Bulk assembly of organic metal halide nanotubes
Abstract
The organic metal halide hybrids welcome a new member with a one-dimensional (1D) tubular structure. Herein we report the synthesis and characterization of a single crystalline bulk assembly of organic metal halide nanotubes, (C6H13N4)3Pb2Br7. In a metal halide nanotube, six face-sharing metal halide dimers (Pb2Br95–) connect at the corners to form rings that extend in one dimension, of which the inside and outside surfaces are coated with protonated hexamethylenetetramine (HMTA) cations (C6H13N4+). This unique 1D tubular structure possesses highly localized electronic states with strong quantum confinement, resulting in the formation of self-trapped excitons that give strongly Stokes shifted broadband yellowish-white emission with a photoluminescence quantum efficiency (PLQE) of ~7%. Finally, having realized single crystalline bulk assemblies of two-dimensional (2D) wells, 1D wires, and now 1D tubes using organic metal halide hybrids, our work significantly advances the research on bulk assemblies of quantum-confined materials.
- Authors:
-
[2];
[4];
[5];
[5];
[3]
- FAMU-FSU College of Engineering, Tallahassee, FL (United States)
- Florida State Univ., Tallahassee, FL (United States)
- FAMU-FSU College of Engineering, Tallahassee, FL (United States); Florida State Univ., Tallahassee, FL (United States)
- Univ. of Florida, Gainesville, FL (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1410201
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 12; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Lin, Haoran, Zhou, Chenkun, Tian, Yu, Besara, Tiglet, Neu, Jennifer, Siegrist, Theo, Zhou, Yan, Bullock, James, Schanze, Kirk S., Ming, Wenmei, Du, Mao -Hua, and Ma, Biwu. Bulk assembly of organic metal halide nanotubes. United States: N. p., 2017.
Web. doi:10.1039/c7sc03675b.
Lin, Haoran, Zhou, Chenkun, Tian, Yu, Besara, Tiglet, Neu, Jennifer, Siegrist, Theo, Zhou, Yan, Bullock, James, Schanze, Kirk S., Ming, Wenmei, Du, Mao -Hua, & Ma, Biwu. Bulk assembly of organic metal halide nanotubes. United States. https://doi.org/10.1039/c7sc03675b
Lin, Haoran, Zhou, Chenkun, Tian, Yu, Besara, Tiglet, Neu, Jennifer, Siegrist, Theo, Zhou, Yan, Bullock, James, Schanze, Kirk S., Ming, Wenmei, Du, Mao -Hua, and Ma, Biwu. Mon .
"Bulk assembly of organic metal halide nanotubes". United States. https://doi.org/10.1039/c7sc03675b. https://www.osti.gov/servlets/purl/1410201.
@article{osti_1410201,
title = {Bulk assembly of organic metal halide nanotubes},
author = {Lin, Haoran and Zhou, Chenkun and Tian, Yu and Besara, Tiglet and Neu, Jennifer and Siegrist, Theo and Zhou, Yan and Bullock, James and Schanze, Kirk S. and Ming, Wenmei and Du, Mao -Hua and Ma, Biwu},
abstractNote = {The organic metal halide hybrids welcome a new member with a one-dimensional (1D) tubular structure. Herein we report the synthesis and characterization of a single crystalline bulk assembly of organic metal halide nanotubes, (C6H13N4)3Pb2Br7. In a metal halide nanotube, six face-sharing metal halide dimers (Pb2Br95–) connect at the corners to form rings that extend in one dimension, of which the inside and outside surfaces are coated with protonated hexamethylenetetramine (HMTA) cations (C6H13N4+). This unique 1D tubular structure possesses highly localized electronic states with strong quantum confinement, resulting in the formation of self-trapped excitons that give strongly Stokes shifted broadband yellowish-white emission with a photoluminescence quantum efficiency (PLQE) of ~7%. Finally, having realized single crystalline bulk assemblies of two-dimensional (2D) wells, 1D wires, and now 1D tubes using organic metal halide hybrids, our work significantly advances the research on bulk assemblies of quantum-confined materials.},
doi = {10.1039/c7sc03675b},
journal = {Chemical Science},
number = 12,
volume = 8,
place = {United States},
year = {2017},
month = {10}
}
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Figures / Tables:
Fig. 1: (a) View of the structure of (HMTA)3Pb2Br7 (red: lead atoms; green: bromine atoms; blue: nitrogen atoms; gray: carbon atoms; purple polyhedra: PbBr6 octahedra and Pb2Br9 dimers; hydrogen atoms are hidden for clarity). (b) Side view of an individual lead bromide nanotube. (c) Side view of an individual leadmore »
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