Bulk assembly of organic metal halide nanotubes

Lin, Haoran; Zhou, Chenkun; Tian, Yu; Besara, Tiglet; Neu, Jennifer; Siegrist, Theo; Zhou, Yan; Bullock, James; Schanze, Kirk S.; Ming, Wenmei; Du, Mao -Hua; Ma, Biwu

doi:10.1039/c7sc03675b

Title: Bulk assembly of organic metal halide nanotubes

Journal Article · 16 October 2017 · Chemical Science

DOI: https://doi.org/10.1039/c7sc03675b · OSTI ID:1410201

Lin, Haoran ^[1]; Zhou, Chenkun ^[1]; Tian, Yu ^[2];

^[2]; Neu, Jennifer ^[2]; Siegrist, Theo ^[3]; Zhou, Yan ^[2]; Bullock, James ^[4];

^[4];

^[5];

^[3]

FAMU-FSU College of Engineering, Tallahassee, FL (United States)
Florida State Univ., Tallahassee, FL (United States)
FAMU-FSU College of Engineering, Tallahassee, FL (United States); Florida State Univ., Tallahassee, FL (United States)
Univ. of Florida, Gainesville, FL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The organic metal halide hybrids welcome a new member with a one-dimensional (1D) tubular structure. Herein we report the synthesis and characterization of a single crystalline bulk assembly of organic metal halide nanotubes, (C₆H₁₃N₄)₃Pb₂Br₇. In a metal halide nanotube, six face-sharing metal halide dimers (Pb₂Br₉^5–) connect at the corners to form rings that extend in one dimension, of which the inside and outside surfaces are coated with protonated hexamethylenetetramine (HMTA) cations (C₆H₁₃N₄⁺). This unique 1D tubular structure possesses highly localized electronic states with strong quantum confinement, resulting in the formation of self-trapped excitons that give strongly Stokes shifted broadband yellowish-white emission with a photoluminescence quantum efficiency (PLQE) of ~7%. Finally, having realized single crystalline bulk assemblies of two-dimensional (2D) wells, 1D wires, and now 1D tubes using organic metal halide hybrids, our work significantly advances the research on bulk assemblies of quantum-confined materials.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1410201

Journal Information:: Chemical Science, Vol. 8, Issue 12; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 69 works

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References (39)

A Metal−Organic Nanotube Exhibiting Reversible Adsorption of (H ₂ O) ₁₂ Cluster Dai, Fangna; He, Haiyan; Sun, Daofeng Journal of the American Chemical Society, Vol. 130, Issue 43 https://doi.org/10.1021/ja805920t	journal	October 2008
Intriguing Optoelectronic Properties of Metal Halide Perovskites Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V. Chemical Reviews, Vol. 116, Issue 21 https://doi.org/10.1021/acs.chemrev.6b00136	journal	June 2016
One-dimensional organic lead halide perovskites with efficient bluish white-light emission Yuan, Zhao; Zhou, Chenkun; Tian, Yu Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14051	journal	January 2017
Energy transport and scintillation of cerium-doped elpasolite Cs 2 LiYCl 6 : Hybrid density functional calculations Biswas, Koushik; Du, Mao-Hua Physical Review B, Vol. 86, Issue 1 https://doi.org/10.1103/PhysRevB.86.014102	journal	July 2012
Low-temperature solution-processed wavelength-tunable perovskites for lasing Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien Nature Materials, Vol. 13, Issue 5 https://doi.org/10.1038/nmat3911	journal	March 2014
Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites Hu, Te; Smith, Matthew D.; Dohner, Emma R. The Journal of Physical Chemistry Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acs.jpclett.6b00793	journal	May 2016
Helical microtubules of graphitic carbon Iijima, Sumio Nature, Vol. 354, Issue 6348 https://doi.org/10.1038/354056a0	journal	November 1991
Excitonic and Polaronic Properties of 2D Hybrid Organic–Inorganic Perovskites Yin, Jun; Li, Hong; Cortecchia, Daniele ACS Energy Letters, Vol. 2, Issue 2 https://doi.org/10.1021/acsenergylett.6b00659	journal	January 2017
Alkali halide crystals containing impurity ions with the ns2 ground-state electronic configuration† Jacobs, P. W. M. Journal of Physics and Chemistry of Solids, Vol. 52, Issue 1 https://doi.org/10.1016/0022-3697(91)90059-9	journal	January 1991
Low-Dimensional Organic Tin Bromide Perovskites and Their Photoinduced Structural Transformation Zhou, Chenkun; Tian, Yu; Wang, Mingchao Angewandte Chemie International Edition, Vol. 56, Issue 31 https://doi.org/10.1002/anie.201702825	journal	July 2017
Polaron self-localization in white-light emitting hybrid perovskites Cortecchia, Daniele; Yin, Jun; Bruno, Annalisa Journal of Materials Chemistry C, Vol. 5, Issue 11 https://doi.org/10.1039/C7TC00366H	journal	January 2017
Synthesis and Characterization of [NH2C(I):NH2]3MI5 (M = Sn, Pb): Stereochemical Activity in Divalent Tin and Lead Halides Containing Single .ltbbrac.110.rtbbrac. Perovskite Sheets Wang, Shumin; Mitzi, David B.; Feild, Chris A. Journal of the American Chemical Society, Vol. 117, Issue 19 https://doi.org/10.1021/ja00124a012	journal	May 1995
A Microscale Perovskite as Single Component Broadband Phosphor for Downconversion White-Light-Emitting Devices Yuan, Zhao; Zhou, Chenkun; Messier, Joshua Advanced Optical Materials, Vol. 4, Issue 12 https://doi.org/10.1002/adom.201600667	journal	September 2016
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Intrinsic White-Light Emission from Layered Hybrid Perovskites Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R. Journal of the American Chemical Society, Vol. 136, Issue 38 https://doi.org/10.1021/ja507086b	journal	September 2014
A Prototypical Zeolitic Lanthanide−Organic Framework with Nanotubular Structure Huang, You-Gui; Jiang, Fei-Long; Yuan, Da-Qiang Crystal Growth & Design, Vol. 8, Issue 1 https://doi.org/10.1021/cg700927s	journal	January 2008
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design Saparov, Bayrammurad; Mitzi, David B. Chemical Reviews, Vol. 116, Issue 7 https://doi.org/10.1021/acs.chemrev.5b00715	journal	March 2016
High-Performance Flexible Broadband Photodetector Based on Organolead Halide Perovskite Hu, Xin; Zhang, Xiaodong; Liang, Lin Advanced Functional Materials, Vol. 24, Issue 46 https://doi.org/10.1002/adfm.201402020	journal	September 2014
Connecting Thermoelectric Performance and Topological-Insulator Behavior: Bi 2 Te 3 and Bi 2 Te 2 Se from First Principles Shi, Hongliang; Parker, David; Du, Mao-Hua Physical Review Applied, Vol. 3, Issue 1 https://doi.org/10.1103/PhysRevApplied.3.014004	journal	January 2015
Self-Assembly of Broadband White-Light Emitters Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja411045r	journal	January 2014
Atomically thin two-dimensional organic-inorganic hybrid perovskites Dou, L.; Wong, A. B.; Yu, Y. Science, Vol. 349, Issue 6255 https://doi.org/10.1126/science.aac7660	journal	September 2015
Using DFT Methods to Study Activators in Optical Materials Du, Mao-Hua ECS Journal of Solid State Science and Technology, Vol. 5, Issue 1 https://doi.org/10.1149/2.0011601jss	journal	August 2015
Self-assembled arrays of polyoxometalate-based metal–organic nanotubes for proton conduction and magnetism Jiao, Yan-Qing; Zang, Hong-Ying; Wang, Xin-Long Chemical Communications, Vol. 51, Issue 56 https://doi.org/10.1039/C5CC03357H	journal	January 2015
Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets Mitzi, D. B.; Wang, S.; Feild, C. A. Science, Vol. 267, Issue 5203, p. 1473-1476 https://doi.org/10.1126/science.267.5203.1473	journal	March 1995
Bright light-emitting diodes based on organometal halide perovskite Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.149	journal	August 2014
Two-Dimensional Metal Halide Perovskites: Theory, Synthesis, and Optoelectronics Huo, Chengxue; Cai, Bo; Yuan, Zhao Small Methods, Vol. 1, Issue 3 https://doi.org/10.1002/smtd.201600018	journal	January 2017
Self-Assembled Arrays of Single-Walled Metal-Organic Nanotubes Luo, Tzuoo-Tsair; Wu, Huang-Chun; Jao, Yu-Chen Angewandte Chemie International Edition, Vol. 48, Issue 50 https://doi.org/10.1002/anie.200904501	journal	November 2009
Carrier Self-trapping and Luminescence in Intrinsically Activated Scintillator: Cesium Hafnium Chloride (Cs ₂ HfCl ₆ ) Kang, By.; Biswas, Koushik The Journal of Physical Chemistry C, Vol. 120, Issue 22 https://doi.org/10.1021/acs.jpcc.6b02496	journal	May 2016
Crystal structure and mechanism of a calcium-gated potassium channel Jiang, Youxing; Lee, Alice; Chen, Jiayun Nature, Vol. 417, Issue 6888 https://doi.org/10.1038/417515a	journal	May 2002
Recent developments in single-crystal inorganic nanotubes synthesised from removable templates Shen, Guozhen; Bando, Yoshio; Golberg, Dmitri International Journal of Nanotechnology, Vol. 4, Issue 6 https://doi.org/10.1504/IJNT.2007.015467	journal	January 2007
Templating and structural engineering in organic–inorganic perovskites Mitzi, David B. Journal of the Chemical Society, Dalton Transactions, Issue 1 https://doi.org/10.1039/b007070j	journal	January 2001
White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C. Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.7b01312	journal	March 2017
A journey in search of single-walled metal–organic nanotubes Thanasekaran, Pounraj; Luo, Tzuoo-Tsair; Lee, Cheng-Hua Journal of Materials Chemistry, Vol. 21, Issue 35 https://doi.org/10.1039/c1jm11153a	journal	January 2011
Broadband Emission in Two-Dimensional Hybrid Perovskites: The Role of Structural Deformation Cortecchia, Daniele; Neutzner, Stefanie; Srimath Kandada, Ajay Ram Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b10390	journal	December 2016
Alkylammonium lead halides. Part 1. Isolated PbI ₆ ⁴⁻ ions in (CH ₃ NH ₃ ) ₄ PbI ₆ •2H ₂ O Vincent, Beverly R.; Robertson, Katherine N.; Cameron, T. Stanley Canadian Journal of Chemistry, Vol. 65, Issue 5 https://doi.org/10.1139/v87-176	journal	May 1987
Optical Investigation of Broadband White-Light Emission in Self-Assembled Organic–Inorganic Perovskite (C ₆ H ₁₁ NH ₃ ) ₂ PbBr ₄ Yangui, A.; Garrot, D.; Lauret, J. S. The Journal of Physical Chemistry C, Vol. 119, Issue 41 https://doi.org/10.1021/acs.jpcc.5b06211	journal	October 2015
Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges Berry, Joseph; Buonassisi, Tonio; Egger, David A. Advanced Materials, Vol. 27, Issue 35 https://doi.org/10.1002/adma.201502294	journal	July 2015
Self-Assembled Arrays of Single-Walled Metal-Organic Nanotubes Luo, Tzuoo-Tsair; Wu, Huang-Chun; Jao, Yu-Chen Angewandte Chemie, Vol. 121, Issue 50 https://doi.org/10.1002/ange.200904501	journal	November 2009
Low-Dimensional Organic Tin Bromide Perovskites and Their Photoinduced Structural Transformation Zhou, Chenkun; Tian, Yu; Wang, Mingchao Angewandte Chemie, Vol. 129, Issue 31 https://doi.org/10.1002/ange.201702825	journal	July 2017

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