Platinum Nanoparticle Loading of Boron Nitride Aerogel and Its Use as a Novel Material for Low-Power Catalytic Gas Sensing
Abstract
A high-surface-area, highly crystalline boron nitride aerogel synthesized with nonhazardous reactants has been loaded with crystalline platinum nanoparticles to form a novel nanomaterial that exhibits many advantages for use in a catalytic gas sensing application. The platinum nanoparticle-loaded boron nitride aerogel integrated onto a microheater platform allows for calorimetric propane detection. The boron nitride aerogel exhibits thermal stability up to 900°C and supports disperse platinum nanoparticles, with no sintering observed after 24 h of high-temperature testing. The high thermal conductivity and low density of the boron nitride aerogel result in an order of magnitude faster response and recovery times ( < 2 s) than reported on alumina support and allow for 10% duty cycling of the microheater with no loss in sensitivity. The resulting 1.5 mW sensor power consumption is two orders of magnitude less than commercially available catalytic gas sensors and unlocks the potential for wireless, battery-powered catalytic gas sensing.
- Authors:
-
- Univ. of California, Berkeley, CA (United States). Department of Chemical and Biomolecular Engineering
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States). Department of Physics, Materials Sciences Division and Kavli Energy NanoSciences Institute
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Physical and Life Science Directorate
- Publication Date:
- Research Org.:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1409980
- Alternate Identifier(s):
- OSTI ID: 1440917
- Report Number(s):
- LLNL-JRNL-691677
Journal ID: ISSN 1616-301X
- Grant/Contract Number:
- AC52-07NA27344; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 26; Journal Issue: 3; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; gas sensors; boron nitride aerogel; platinum nanoparticles; microheater; combustible gas
Citation Formats
Harley-Trochimczyk, Anna, Pham, Thang, Chang, Jiyoung, Chen, Ernest, Worsley, Marcus A., Zettl, Alex, Mickelson, William, and Maboudian, Roya. Platinum Nanoparticle Loading of Boron Nitride Aerogel and Its Use as a Novel Material for Low-Power Catalytic Gas Sensing. United States: N. p., 2015.
Web. doi:10.1002/adfm.201503605.
Harley-Trochimczyk, Anna, Pham, Thang, Chang, Jiyoung, Chen, Ernest, Worsley, Marcus A., Zettl, Alex, Mickelson, William, & Maboudian, Roya. Platinum Nanoparticle Loading of Boron Nitride Aerogel and Its Use as a Novel Material for Low-Power Catalytic Gas Sensing. United States. doi:https://doi.org/10.1002/adfm.201503605
Harley-Trochimczyk, Anna, Pham, Thang, Chang, Jiyoung, Chen, Ernest, Worsley, Marcus A., Zettl, Alex, Mickelson, William, and Maboudian, Roya. Wed .
"Platinum Nanoparticle Loading of Boron Nitride Aerogel and Its Use as a Novel Material for Low-Power Catalytic Gas Sensing". United States. doi:https://doi.org/10.1002/adfm.201503605. https://www.osti.gov/servlets/purl/1409980.
@article{osti_1409980,
title = {Platinum Nanoparticle Loading of Boron Nitride Aerogel and Its Use as a Novel Material for Low-Power Catalytic Gas Sensing},
author = {Harley-Trochimczyk, Anna and Pham, Thang and Chang, Jiyoung and Chen, Ernest and Worsley, Marcus A. and Zettl, Alex and Mickelson, William and Maboudian, Roya},
abstractNote = {A high-surface-area, highly crystalline boron nitride aerogel synthesized with nonhazardous reactants has been loaded with crystalline platinum nanoparticles to form a novel nanomaterial that exhibits many advantages for use in a catalytic gas sensing application. The platinum nanoparticle-loaded boron nitride aerogel integrated onto a microheater platform allows for calorimetric propane detection. The boron nitride aerogel exhibits thermal stability up to 900°C and supports disperse platinum nanoparticles, with no sintering observed after 24 h of high-temperature testing. The high thermal conductivity and low density of the boron nitride aerogel result in an order of magnitude faster response and recovery times ( < 2 s) than reported on alumina support and allow for 10% duty cycling of the microheater with no loss in sensitivity. The resulting 1.5 mW sensor power consumption is two orders of magnitude less than commercially available catalytic gas sensors and unlocks the potential for wireless, battery-powered catalytic gas sensing.},
doi = {10.1002/adfm.201503605},
journal = {Advanced Functional Materials},
number = 3,
volume = 26,
place = {United States},
year = {2015},
month = {12}
}
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Works referenced in this record:
One-Step Template-Free Synthesis of Highly Porous Boron Nitride Microsponges for Hydrogen Storage
journal, December 2013
- Weng, Qunhong; Wang, Xuebin; Bando, Yoshio
- Advanced Energy Materials, Vol. 4, Issue 7
Complete oxidation of methane at low temperature over noble metal based catalysts: a review
journal, November 2002
- Gélin, Patrick; Primet, Michel
- Applied Catalysis B: Environmental, Vol. 39, Issue 1, p. 1-37
A novel boron nitride supported Pt catalyst for VOC incineration
journal, October 2001
- Wu, Jeffrey C. -S; Lin, Zhi-An; Pan, Jen-Wei
- Applied Catalysis A: General, Vol. 219, Issue 1-2
Thermal effects by the sensitive coating of calorimetric gas sensors
journal, November 2005
- Fürjes, P.; Ádám, M.; Dücső, Cs.
- Sensors and Actuators B: Chemical, Vol. 111-112
Easily-Controlled Chemoselective Hydrogenation by using Palladium on Boron Nitride
journal, June 2013
- Yabe, Yuki; Sawama, Yoshinari; Yamada, Tsuyoshi
- ChemCatChem, Vol. 5, Issue 8
Ultralight boron nitride aerogels via template-assisted chemical vapor deposition
journal, May 2015
- Song, Yangxi; Li, Bin; Yang, Siwei
- Scientific Reports, Vol. 5, Issue 1
Boron Nitride Supported Metal Catalysts: Influence of the Metal and Preparation Method
journal, July 2006
- Postole, G.; Gervasini, A.; Auroux, A.
- Materials Science Forum, Vol. 518
Synthesis and Characterization of Highly Crystalline Graphene Aerogels
journal, October 2014
- Worsley, Marcus A.; Pham, Thang T.; Yan, Aiming
- ACS Nano, Vol. 8, Issue 10, p. 11013-11022
Oxidative and hydrolytic stability of boron nitride — A new approach to improving the oxidation resistance of carbonaceous structures
journal, January 1995
- Cofer, Cameron G.; Economy, James
- Carbon, Vol. 33, Issue 4
Measurement of reaction heats using a polysilicon-based microcalorimetric sensor
journal, October 2011
- Vereshchagina, E.; Wolters, R. A. M.; Gardeniers, J. G. E.
- Sensors and Actuators A: Physical, Vol. 169, Issue 2
Fast response integrated MEMS microheaters for ultra low power gas detection
journal, March 2015
- Zhou, Qin; Sussman, Allen; Chang, Jiyoung
- Sensors and Actuators A: Physical, Vol. 223
Facile Preparation of Superelastic and Ultralow Dielectric Boron Nitride Nanosheet Aerogels via Freeze-Casting Process
journal, August 2015
- Zeng, Xiaoliang; Ye, Lei; Yu, Shuhui
- Chemistry of Materials, Vol. 27, Issue 17
Boron nitride as an alternative support of Pd catalysts for the selective oxidation of lactose
journal, December 2012
- Meyer, Nathalie; Bekaert, Kevin; Pirson, Damien
- Catalysis Communications, Vol. 29
Porous boron nitride nanosheets for effective water cleaning
journal, April 2013
- Lei, Weiwei; Portehault, David; Liu, Dan
- Nature Communications, Vol. 4, Article No. 1777
Boron Nitride Nanotubes
journal, August 1995
- Chopra, N. G.; Luyken, R. J.; Cherrey, K.
- Science, Vol. 269, Issue 5226
The application of propane/butane mixture for domestic refrigerators
journal, September 1998
- Alsaad, M. A.; Hammad, M. A.
- Applied Thermal Engineering, Vol. 18, Issue 9-10
Strong Oxidation Resistance of Atomically Thin Boron Nitride Nanosheets
journal, January 2014
- Li, Lu Hua; Cervenka, Jiri; Watanabe, Kenji
- ACS Nano, Vol. 8, Issue 2
Boron Nitride Nanotubes
journal, September 2007
- Golberg, D.; Bando, Y.; Tang, C. C.
- Advanced Materials, Vol. 19, Issue 18, p. 2413-2432
Design, Fabrication, and Characterization of a High-Heating-Efficiency 3-D Microheater for Catalytic Gas Sensors
journal, December 2012
- Xu, Lei; Wang, Yuchen; Zhou, Hong
- Journal of Microelectromechanical Systems, Vol. 21, Issue 6
Boron nitride nanotubes: Pronounced resistance to oxidation
journal, March 2004
- Chen, Ying; Zou, Jin; Campbell, Stewart J.
- Applied Physics Letters, Vol. 84, Issue 13, p. 2430-2432
The use of propane in domestic refrigerators
journal, January 1992
- James, R. W.; Missenden, J. F.
- International Journal of Refrigeration, Vol. 15, Issue 2
Explosion-proof monitoring of hydrocarbons by mechanically stabilised, integrable calorimetric microsensors
journal, October 2003
- Dücso, C.; Ádám, M.; Fürjes, P.
- Sensors and Actuators B: Chemical, Vol. 95, Issue 1-3, p. 189-194
Thermal Conductivity and Phonon Transport in Suspended Few-Layer Hexagonal Boron Nitride
journal, January 2013
- Jo, Insun; Pettes, Michael Thompson; Kim, Jaehyun
- Nano Letters, Vol. 13, Issue 2, p. 550-554
Catalytic hydrogen sensing using microheated platinum nanoparticle-loaded graphene aerogel
journal, January 2015
- Harley-Trochimczyk, Anna; Chang, Jiyoung; Zhou, Qin
- Sensors and Actuators B: Chemical, Vol. 206
Synthesis of Highly Crystalline sp2-Bonded Boron Nitride Aerogels
journal, September 2013
- Rousseas, Michael; Goldstein, Anna P.; Mickelson, William
- ACS Nano, Vol. 7, Issue 10, p. 8540-8546
Characterization of Boron-Nitride-Supported Pt Catalysts for the Deep Oxidation of Benzene
journal, August 2002
- Lin, C.
- Journal of Catalysis, Vol. 210, Issue 1
Porous boron nitride with a high surface area: hydrogen storage and water treatment
journal, March 2013
- Li, Jie; Lin, Jing; Xu, Xuewen
- Nanotechnology, Vol. 24, Issue 15, Article No. 155603
Boron nitride supported Pt catalyst for selective hydrogenation
journal, August 2005
- Wu, Jeffrey C. S.; Chen, Chao-Yu; Lin, Shawn D.
- Catalysis Letters, Vol. 102, Issue 3-4
High-surface area ceramic-derived boron-nitride and its hydrogen uptake properties
journal, January 2013
- Kim, Jinhong; Han, Jisun; Seo, Moonsu
- Journal of Materials Chemistry A, Vol. 1, Issue 4, p. 1014-1017
Boron Nitride Nanotubes and Nanosheets
journal, May 2010
- Golberg, Dmitri; Bando, Yoshio; Huang, Yang
- ACS Nano, Vol. 4, Issue 6
Fabrication and properties of a Si-based high-sensitivity microcalorimetric gas sensor
journal, May 1995
- Zanini, M.; Visser, J. H.; Rimai, L.
- Sensors and Actuators A: Physical, Vol. 48, Issue 3, p. 187-192
The physics of boron nitride nanotubes
journal, November 2010
- Cohen, Marvin L.; Zettl, Alex
- Physics Today, Vol. 63, Issue 11, p. 34-38
Efficient catalytic combustion in integrated micropellistors
journal, October 2009
- Bársony, I.; Ádám, M.; Fürjes, P.
- Measurement Science and Technology, Vol. 20, Issue 12
Energy efficient planar catalytic sensor for methane measurement
journal, May 2013
- Karpov, Evgeny Е.; Karpov, Еvgeny F.; Suchkov, Аlexey
- Sensors and Actuators A: Physical, Vol. 194
Nanostructured and architectured boron nitride from boron, nitrogen and hydrogen-containing molecular and polymeric precursors
journal, November 2014
- Bernard, S.; Miele, P.
- Materials Today, Vol. 17, Issue 9
Large-scale synthesis and functionalization of hexagonal boron nitride nanosheets
journal, January 2014
- Bhimanapati, Ganesh R.; Kozuch, Daniel; Robinson, Joshua A.
- Nanoscale, Vol. 6, Issue 20
Highly microporous boron nitride for gas adsorption
journal, November 1991
- Borek, Theodore T.; Ackerman, William.; Hua, D. W.
- Langmuir, Vol. 7, Issue 11, p. 2844-2846
Nanosheet-Structured Boron Nitride Spheres with a Versatile Adsorption Capacity for Water Cleaning
journal, January 2015
- Liu, Fei; Yu, Jie; Ji, Xixi
- ACS Applied Materials & Interfaces, Vol. 7, Issue 3
Controllable synthesis, property investigation of hexagonal boron nitride micromesh and its functionalization by Ag nanoparticles
journal, January 2013
- Zhang, Yuxu; Xu, Liqiang; Tang, Bin
- Catal. Sci. Technol., Vol. 3, Issue 1
Hydrogen adsorption on boron nitride nanotubes: A path to room-temperature hydrogen storage
journal, June 2004
- Jhi, Seung-Hoon; Kwon, Young-Kyun
- Physical Review B, Vol. 69, Issue 24, Article No. 245407
Nanoscale structure and superhydrophobicity of sp 2 -bonded boron nitride aerogels
journal, January 2015
- Pham, Thang; Goldstein, Anna P.; Lewicki, James P.
- Nanoscale, Vol. 7, Issue 23
Micro-differential scanning calorimeter for combustible gas sensing
journal, January 2004
- Cavicchi, R. E.; Poirier, G. E.; Tea, N. H.
- Sensors and Actuators B: Chemical, Vol. 97, Issue 1, p. 22-30
25th Anniversary Article: Hybrid Nanostructures Based on Two-Dimensional Nanomaterials
journal, March 2014
- Huang, Xiao; Tan, Chaoliang; Yin, Zongyou
- Advanced Materials, Vol. 26, Issue 14
A facile route for 3D aerogels from nanostructured 1D and 2D materials
journal, November 2012
- Jung, Sung Mi; Jung, Hyun Young; Dresselhaus, Mildred S.
- Scientific Reports, Vol. 2, Issue 1, Article No. 849
Works referencing / citing this record:
Carbon aerogel evolution: Allotrope, graphene-inspired, and 3D-printed aerogels
journal, October 2017
- Chandrasekaran, Swetha; Campbell, Patrick G.; Baumann, Theodore F.
- Journal of Materials Research, Vol. 32, Issue 22
Two-Dimensional Nanostructured Materials for Gas Sensing
journal, August 2017
- Liu, Xianghong; Ma, Tiantian; Pinna, Nicola
- Advanced Functional Materials, Vol. 27, Issue 37
Understanding the noble metal modifying effect on In 2 O 3 nanowires: highly sensitive and selective gas sensors for potential early screening of multiple diseases
journal, January 2019
- Liu, Wei; Sun, Jiao; Xu, Lin
- Nanoscale Horizons, Vol. 4, Issue 6
On-chip assembly of 3D graphene-based aerogels for chemiresistive gas sensing
journal, January 2020
- Shao, Gaofeng; Ovsianytskyi, Oleksandr; Bekheet, Maged F.
- Chemical Communications, Vol. 56, Issue 3
Ultrathin Pd-based nanosheets: syntheses, properties and applications
journal, January 2020
- Nosheen, Farhat; Wasfi, Nimra; Aslam, Sehrish
- Nanoscale, Vol. 12, Issue 7
Monolithic aerogel photocatalysts: a review
journal, January 2018
- Wan, Wenchao; Zhang, Ruiyang; Ma, Minzhi
- Journal of Materials Chemistry A, Vol. 6, Issue 3
Versatile Aerogels for Sensors
journal, September 2019
- Yang, Jing; Li, Yi; Zheng, Yuanyuan
- Small, Vol. 15, Issue 41
“Naked” Magnetically Recyclable Mesoporous Au-γ-Fe 2 O 3 Nanocrystal Clusters: A Highly Integrated Catalyst System
journal, January 2017
- Shang, Lu; Liang, Yunhui; Li, Mengzhu
- Advanced Functional Materials, Vol. 27, Issue 9
High Surface Area MoS 2 /Graphene Hybrid Aerogel for Ultrasensitive NO 2 Detection
journal, May 2016
- Long, Hu; Harley-Trochimczyk, Anna; Pham, Thang
- Advanced Functional Materials, Vol. 26, Issue 28
Resistive gas sensors based on metal-oxide nanowires
journal, December 2019
- Mirzaei, Ali; Lee, Jae-Hyoung; Majhi, Sanjit Manohar
- Journal of Applied Physics, Vol. 126, Issue 24
Extremely sensitive and accurate H 2 S sensor at room temperature fabricated with In-doped Co 3 O 4 porous nanosheets
journal, January 2019
- Wu, Jie; Yang, Ying; Zhang, Chengxin
- Dalton Transactions, Vol. 48, Issue 22
Functionalized hexagonal boron nitride nanomaterials: emerging properties and applications
journal, January 2016
- Weng, Qunhong; Wang, Xuebin; Wang, Xi
- Chemical Society Reviews, Vol. 45, Issue 14
Fabrication and application of BN nanoparticles, nanosheets and their nanohybrids
journal, January 2018
- Shtansky, Dmitry V.; Firestein, Konstantin L.; Golberg, Dmitri V.
- Nanoscale, Vol. 10, Issue 37
Improved control on the morphology and LSPR properties of plasmonic Pt NPs through enhanced solid state dewetting by using a sacrificial indium layer
journal, January 2019
- Kunwar, Sundar; Sui, Mao; Pandey, Puran
- RSC Advances, Vol. 9, Issue 4
Surface modification of hexagonal boron nitride nanomaterials: a review
journal, August 2017
- Zheng, Zhuoyuan; Cox, McCord; Li, Bin
- Journal of Materials Science, Vol. 53, Issue 1
Synthesis of aerogels: from molecular routes to 3-dimensional nanoparticle assembly
journal, January 2017
- Rechberger, Felix; Niederberger, Markus
- Nanoscale Horizons, Vol. 2, Issue 1