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Title: REE Incorporation into Calcite Individual Crystals as One Time Spike Addition

Abstract

Experiments on the incorporation of trace elements into calcite were performed, and rare earth elements (REE) were used to mark the growth zones of individual crystals. Experiments were conducted at different pH (7.7 to 8.8) and temperatures (2 °C to 24.6 °C) in NH4Cl + CaCl2 solutions, where REE were rapidly consumed by growing calcite. LA-ICP-MS line-scans yielded the distribution of (REE/Ca)calcite within individual crystals in a manner consistent with the addition of REE into fluid. A sharp decrease of (REE/Ca)calcite toward the crystal edge suggests the fast depletion of (REE/Ca)fluid due to strong REE consumption by growing calcite. An attempt was made to estimate the lower limit of the partition coefficients between calcite and fluid using selected REE/Ca data within individual calcite crystals and the amount of REE added into fluid.

Authors:
 [1];  [2]; ORCiD logo [3]
  1. Mississippi State Univ., Mississippi State, MS (United States). Department of Geosciences
  2. The University of Western Australia, Crawley, WA (Australia). ARC Centre of Excellence for Coral Reef Studies
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1409791
Report Number(s):
LA-UR-17-28574
Journal ID: ISSN 2075-163X
Grant/Contract Number:  
AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Minerals
Additional Journal Information:
Journal Volume: 7; Journal Issue: 11; Journal ID: ISSN 2075-163X
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
58 GEOSCIENCES; 36 MATERIALS SCIENCE; Earth Sciences; Calcite, rare earth, partitioning, LA-ICP-MS

Citation Formats

Gabitov, Rinat, Sadekov, Aleksey, and Migdisov, Artas. REE Incorporation into Calcite Individual Crystals as One Time Spike Addition. United States: N. p., 2017. Web. doi:10.3390/min7110204.
Gabitov, Rinat, Sadekov, Aleksey, & Migdisov, Artas. REE Incorporation into Calcite Individual Crystals as One Time Spike Addition. United States. doi:https://doi.org/10.3390/min7110204
Gabitov, Rinat, Sadekov, Aleksey, and Migdisov, Artas. Thu . "REE Incorporation into Calcite Individual Crystals as One Time Spike Addition". United States. doi:https://doi.org/10.3390/min7110204. https://www.osti.gov/servlets/purl/1409791.
@article{osti_1409791,
title = {REE Incorporation into Calcite Individual Crystals as One Time Spike Addition},
author = {Gabitov, Rinat and Sadekov, Aleksey and Migdisov, Artas},
abstractNote = {Experiments on the incorporation of trace elements into calcite were performed, and rare earth elements (REE) were used to mark the growth zones of individual crystals. Experiments were conducted at different pH (7.7 to 8.8) and temperatures (2 °C to 24.6 °C) in NH4Cl + CaCl2 solutions, where REE were rapidly consumed by growing calcite. LA-ICP-MS line-scans yielded the distribution of (REE/Ca)calcite within individual crystals in a manner consistent with the addition of REE into fluid. A sharp decrease of (REE/Ca)calcite toward the crystal edge suggests the fast depletion of (REE/Ca)fluid due to strong REE consumption by growing calcite. An attempt was made to estimate the lower limit of the partition coefficients between calcite and fluid using selected REE/Ca data within individual calcite crystals and the amount of REE added into fluid.},
doi = {10.3390/min7110204},
journal = {Minerals},
number = 11,
volume = 7,
place = {United States},
year = {2017},
month = {10}
}

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Works referenced in this record:

The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of ocean waters
journal, April 1990

  • Elderfield, H.; Upstill-Goddard, R.; Sholkovitz, E. R.
  • Geochimica et Cosmochimica Acta, Vol. 54, Issue 4
  • DOI: 10.1016/0016-7037(90)90432-K

Incorporation of Eu(III) into Calcite under Recrystallization conditions
journal, September 2016

  • Hellebrandt, S. E.; Hofmann, S.; Jordan, N.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep33137

Experimental study of europium (III) coprecipitation with calcite
journal, February 2004


Incorporation of Np(V) and U(VI) in carbonate and sulfate minerals crystallized from aqueous solution
journal, February 2015

  • Balboni, Enrica; Morrison, Jessica M.; Wang, Zheming
  • Geochimica et Cosmochimica Acta, Vol. 151
  • DOI: 10.1016/j.gca.2014.10.027

REE diffusion in calcite
journal, August 1998


Study of the radiotoxicity of actinides recycling in boiling water reactors fuel
journal, October 2009


The coprecipitation of rare-earth elements with calcite and aragonite
journal, June 1988


Partitioning of rare earth elements (REEs) between calcite and seawater solutions at 25°C and 1 atm, and high dissolved REE concentrations
journal, February 1995


Experimental study of rare earth element partitioning between calcite and sodium chloride solution at room temperature and pressure
journal, January 2014


The experimental determination of REE partition coefficients in the water-calcite system
journal, June 2017


Charge Compensation in Solid Solutions
journal, July 2008

  • Schmidt, Moritz; Stumpf, Thorsten; Marques Fernandes, Maria
  • Angewandte Chemie International Edition, Vol. 47, Issue 31
  • DOI: 10.1002/anie.200705827

Incorporation of trivalent actinides into calcite: A time resolved laser fluorescence spectroscopy (TRLFS) study
journal, January 2008

  • Fernandes, M. Marques; Stumpf, T.; Rabung, T.
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 2
  • DOI: 10.1016/j.gca.2007.10.015

Relationship between surface structure, growth mechanism, and trace element incorporation in calcite
journal, February 1995


Oxygen isotope fractionation between calcite and fluid as a function of growth rate and temperature: An in situ study
journal, May 2012


An intensity ratio calibration method for the accurate determination of Mg/Ca and Sr/Ca of marine carbonates by ICP-AES: MARINE CARBONATE ANALYSIS
journal, January 2002

  • de Villiers, Stephanie; Greaves, Mervyn; Elderfield, Henry
  • Geochemistry, Geophysics, Geosystems, Vol. 3, Issue 1
  • DOI: 10.1029/2001GC000169

Comparative hydrolysis behavior of the rare earths and yttrium: the influence of temperature and ionic strength
journal, January 2000


Comparative carbonate complexation of yttrium and gadolinium at 25 °C and 0.7 mol dm−3 ionic strength
journal, December 1995


Carbonate complexation of yttrium and the rare earth elements in natural waters
journal, February 2004


Growth-step-selective incorporation of boron on the calcite surface
journal, September 1998


Nanoscale effects of strontium on calcite growth: An in situ AFM study in the absence of vital effects
journal, June 2005

  • Wasylenki, Laura E.; Dove, Patricia M.; Wilson, Darren S.
  • Geochimica et Cosmochimica Acta, Vol. 69, Issue 12
  • DOI: 10.1016/j.gca.2004.12.019

Surface enrichment and trace-element uptake during crystal growth
journal, December 1996


Surface speciation of calcite observed in situ by high-resolution X-ray reflectivity
journal, April 2000


Experimental determination of growth rate effect on U6+ and Mg2+ partitioning between aragonite and fluid at elevated U6+ concentration
journal, August 2008

  • Gabitov, R. I.; Gaetani, G. A.; Watson, E. B.
  • Geochimica et Cosmochimica Acta, Vol. 72, Issue 16
  • DOI: 10.1016/j.gca.2008.05.047

Crystal growth rate effect on Mg/Ca and Sr/Ca partitioning between calcite and fluid: An in situ approach
journal, February 2014


In situ study of boron partitioning between calcite and fluid at different crystal growth rates
journal, July 2014

  • Gabitov, Rinat I.; Rollion-Bard, Claire; Tripati, Aradhna
  • Geochimica et Cosmochimica Acta, Vol. 137
  • DOI: 10.1016/j.gca.2014.04.014

Diffusion of ions in sea water and in deep-sea sediments
journal, May 1974


An experimental study of hydroxylbastnasite solubility in aqueous solutions at 25 °C
journal, July 2016


Preparation of Artificial Seawater1
journal, April 1967

  • Kester, Dana R.; Duedall, Iver W.; Connors, Donald N.
  • Limnology and Oceanography, Vol. 12, Issue 1
  • DOI: 10.4319/lo.1967.12.1.0176

Effect of mineralogy, salinity, and temperature on Li/Ca and Li isotope composition of calcium carbonate
journal, November 2004


Uptake of sodium and potassium by calcite
journal, January 1984


    Works referencing / citing this record:

    Therapeutic Applications of Phytoplankton, with an Emphasis on Diatoms and Coccolithophores
    journal, October 2018

    • Lomora, Mihai; Shumate, David; Rahman, Asrizal Abdul
    • Advanced Therapeutics, Vol. 2, Issue 2
    • DOI: 10.1002/adtp.201800099