REE Incorporation into Calcite Individual Crystals as One Time Spike Addition

Gabitov, Rinat; Sadekov, Aleksey; Migdisov, Artas

doi:10.3390/min7110204

Title: REE Incorporation into Calcite Individual Crystals as One Time Spike Addition

Abstract

Experiments on the incorporation of trace elements into calcite were performed, and rare earth elements (REE) were used to mark the growth zones of individual crystals. Experiments were conducted at different pH (7.7 to 8.8) and temperatures (2 °C to 24.6 °C) in NH₄Cl + CaCl₂ solutions, where REE were rapidly consumed by growing calcite. LA-ICP-MS line-scans yielded the distribution of (REE/Ca)_calcite within individual crystals in a manner consistent with the addition of REE into fluid. A sharp decrease of (REE/Ca)_calcite toward the crystal edge suggests the fast depletion of (REE/Ca)_fluid due to strong REE consumption by growing calcite. An attempt was made to estimate the lower limit of the partition coefficients between calcite and fluid using selected REE/Ca data within individual calcite crystals and the amount of REE added into fluid.

Authors:

Gabitov, Rinat ^[1]; Sadekov, Aleksey ^[2];

^[3]

Mississippi State Univ., Mississippi State, MS (United States). Department of Geosciences
The University of Western Australia, Crawley, WA (Australia). ARC Centre of Excellence for Coral Reef Studies
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Publication Date:: 2017-10-26

Research Org.:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1409791

Report Number(s):: LA-UR-17-28574
Journal ID: ISSN 2075-163X

Grant/Contract Number:: AC52-06NA25396

Resource Type:: Accepted Manuscript

Journal Name:: Minerals

Additional Journal Information:: Journal Volume: 7; Journal Issue: 11; Journal ID: ISSN 2075-163X

Publisher:: MDPI

Country of Publication:: United States

Language:: English

Subject:: 58 GEOSCIENCES; 36 MATERIALS SCIENCE; Earth Sciences; Calcite, rare earth, partitioning, LA-ICP-MS

Citation Formats


                    Gabitov, Rinat, Sadekov, Aleksey, and Migdisov, Artas. REE Incorporation into Calcite Individual Crystals as One Time Spike Addition.  United States: N. p., 2017. 
Web.  doi:10.3390/min7110204.

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                    Gabitov, Rinat, Sadekov, Aleksey, & Migdisov, Artas. REE Incorporation into Calcite Individual Crystals as One Time Spike Addition.  United States.  https://doi.org/10.3390/min7110204

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                    Gabitov, Rinat, Sadekov, Aleksey, and Migdisov, Artas. Thu .  
"REE Incorporation into Calcite Individual Crystals as One Time Spike Addition".  United States.  https://doi.org/10.3390/min7110204.  https://www.osti.gov/servlets/purl/1409791.

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@article{osti_1409791,

  title        = {REE Incorporation into Calcite Individual Crystals as One Time Spike Addition},

  author       = {Gabitov, Rinat and Sadekov, Aleksey and Migdisov, Artas},

  abstractNote = {Experiments on the incorporation of trace elements into calcite were performed, and rare earth elements (REE) were used to mark the growth zones of individual crystals. Experiments were conducted at different pH (7.7 to 8.8) and temperatures (2 °C to 24.6 °C) in NH4Cl + CaCl2 solutions, where REE were rapidly consumed by growing calcite. LA-ICP-MS line-scans yielded the distribution of (REE/Ca)calcite within individual crystals in a manner consistent with the addition of REE into fluid. A sharp decrease of (REE/Ca)calcite toward the crystal edge suggests the fast depletion of (REE/Ca)fluid due to strong REE consumption by growing calcite. An attempt was made to estimate the lower limit of the partition coefficients between calcite and fluid using selected REE/Ca data within individual calcite crystals and the amount of REE added into fluid.},

  doi          = {10.3390/min7110204},

  journal      = {Minerals},

  number       = 11,

  volume       = 7,

  place        = {United States},

  year         = {2017},

  month        = {10}

}

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Therapeutic Applications of Phytoplankton, with an Emphasis on Diatoms and Coccolithophores
journal, October 2018

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Advanced Therapeutics, Vol. 2, Issue 2
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Title: REE Incorporation into Calcite Individual Crystals as One Time Spike Addition

Abstract

Citation Formats

The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of ocean waters journal, April 1990

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A simple model for sector zoning in slowly grown crystals; implications for growth rate and lattice diffusion, with emphasis on accessory minerals in crustal rocks journal, December 1995

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Experimental determination of growth rate effect on U6+ and Mg2+ partitioning between aragonite and fluid at elevated U6+ concentration journal, August 2008

Crystal growth rate effect on Mg/Ca and Sr/Ca partitioning between calcite and fluid: An in situ approach journal, February 2014

Relative precipitation rates of aragonite and Mg calcite from seawater: Temperature or carbonate ion control? journal, January 1987

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Non-equilibrium isotopic and elemental fractionation during diffusion-controlled crystal growth under static and dynamic conditions journal, September 2009

Diffusion of ions in sea water and in deep-sea sediments journal, May 1974

An experimental study of hydroxylbastnasite solubility in aqueous solutions at 25 °C journal, July 2016

Preparation of Artificial Seawater1 journal, April 1967

Effect of mineralogy, salinity, and temperature on Li/Ca and Li isotope composition of calcium carbonate journal, November 2004

Uptake of sodium and potassium by calcite journal, January 1984

Therapeutic Applications of Phytoplankton, with an Emphasis on Diatoms and Coccolithophores journal, October 2018

The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of ocean waters
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Incorporation of Eu(III) into Calcite under Recrystallization conditions
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Experimental study of europium (III) coprecipitation with calcite
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REE diffusion in calcite
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Study of the radiotoxicity of actinides recycling in boiling water reactors fuel
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The coprecipitation of rare-earth elements with calcite and aragonite
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