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Title: Honeycomb-Ordered Na 3Ni 1.5M 0.5BiO 6 (M = Ni, Cu, Mg, Zn) as High-Voltage Layered Cathodes for Sodium-Ion Batteries

Developing high-voltage layered cathodes for sodium-ion batteries (SIBs) has always been a severe challenge. Herein, a new family of honeycomb-layered Na 3Ni 1.5M 0.5BiO 6 (M = Ni, Cu, Mg, Zn) with a monoclinic superstructure has been shown to combine good Na + (de)intercalation activity with a competitive 3.3 V high voltage. By coupling the electrochemical process with ex situ X-ray absorption spectroscopy as well as in situ X-ray diffraction, the charge compensation mechanism and structural evolution of these new cathodes are clearly investigated. Interestingly, both Ni 2+/Ni 3+ and Cu 2+/Cu 3+ participate in the redox reaction upon cycling, and the succession of single-phase, two-phase, or three-phase regions upon Na+ extraction/insertion were identified with rather good accuracy. Furthermore, this research strategy could provide insights into the structure–function–property relationships on a new series of honeycomb-ordered materials with the general formula Na 3Ni 1.5M 0.5BiO 6 and also serve as a bridge to guide future design of high-performance cathodes for SIBs.
Authors:
ORCiD logo [1] ;  [1] ;  [1] ; ORCiD logo [1] ;  [2] ;  [2] ;  [3] ;  [3] ;  [4] ; ORCiD logo [5] ; ORCiD logo [1]
  1. Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Sciences, Beijing (China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Qingdao Univ., Qingdao (China)
  4. Chinese Academy of Sciences (CAS), Beijing (China); Univ. of Chinese Academy of Science, Beijing (China)
  5. Chinese Academy of Sciences (CAS), Beijing (China)
Publication Date:
Report Number(s):
BNL-114520-2017-JA
Journal ID: ISSN 2380-8195; R&D Project: MA453MAEA; VT1201000
Grant/Contract Number:
SC0012704
Type:
Accepted Manuscript
Journal Name:
ACS Energy Letters
Additional Journal Information:
Journal Volume: 2; Journal ID: ISSN 2380-8195
Publisher:
American Chemical Society (ACS)
Research Org:
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; National Synchrotron Light Source
OSTI Identifier:
1409508