Li + -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances

Li, Qiuyan; Lu, Dongping; Zheng, Jianming; Jiao, Shuhong; Luo, Langli; Wang, Chong-Min; Xu, Kang; Zhang, Ji-Guang; Xu, Wu

doi:10.1021/acsami.7b13887

Title: Li ⁺ -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances

Abstract

Lithium (Li) ion battery (LIB) has penetrated almost every aspects of human life, from portable electronics, vehicles to grids, and its operation stability in extreme environments becomes increasingly important. Among these, sub-zero temperature presents a kinetic challenge to the electrochemical reactions required to deliver the stored energy. Here, in this work, we attempted to identify the rate-determining process for Li⁺ migration under such low temperatures, so that an optimum electrolyte formulation could be designed to maximize the energy output. Substantial increase in available capacities from graphite||LiNi_0.80Co_0.15Al_0.05O₂ chemistry down to -40°C is achieved by reducing the solvent molecule that more tightly binds to Li⁺ and thus constitutes high desolvation energy barrier. Lastly, the fundamental understanding is applicable universally to a wide spectrum of electrochemical devices that have to operate in similar environments.

Authors:

Li, Qiuyan ^[1];

^[1]; Zheng, Jianming ^[1]; Jiao, Shuhong ^[1];

^[2];

^[2]; Xu, Kang ^[1];

^[1];

^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environmental Directorate
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)

Publication Date:: 2017-11-17

Research Org.:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Contributing Org.:: PNNL Laboratory Directed Research and Development (LDRD) Project under Technology Investment Program

OSTI Identifier:: 1409313

Grant/Contract Number:: AC05-76RL01830; AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: ACS Applied Materials and Interfaces

Additional Journal Information:: Journal Volume: 9; Journal Issue: 49; Journal ID: ISSN 1944-8244

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; low temperature; desolvation; ion transfer; electrolyte; lithium ion battery; cesium cation

Citation Formats


                    Li, Qiuyan, Lu, Dongping, Zheng, Jianming, Jiao, Shuhong, Luo, Langli, Wang, Chong-Min, Xu, Kang, Zhang, Ji-Guang, and Xu, Wu. Li + -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances.  United States: N. p., 2017. 
Web.  doi:10.1021/acsami.7b13887.

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                    Li, Qiuyan, Lu, Dongping, Zheng, Jianming, Jiao, Shuhong, Luo, Langli, Wang, Chong-Min, Xu, Kang, Zhang, Ji-Guang, & Xu, Wu. Li + -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances.  United States.  https://doi.org/10.1021/acsami.7b13887

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                    Li, Qiuyan, Lu, Dongping, Zheng, Jianming, Jiao, Shuhong, Luo, Langli, Wang, Chong-Min, Xu, Kang, Zhang, Ji-Guang, and Xu, Wu. Fri .  
"Li + -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances".  United States.  https://doi.org/10.1021/acsami.7b13887.  https://www.osti.gov/servlets/purl/1409313.

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@article{osti_1409313,

  title        = {Li + -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances},

  author       = {Li, Qiuyan and Lu, Dongping and Zheng, Jianming and Jiao, Shuhong and Luo, Langli and Wang, Chong-Min and Xu, Kang and Zhang, Ji-Guang and Xu, Wu},

  abstractNote = {Lithium (Li) ion battery (LIB) has penetrated almost every aspects of human life, from portable electronics, vehicles to grids, and its operation stability in extreme environments becomes increasingly important. Among these, sub-zero temperature presents a kinetic challenge to the electrochemical reactions required to deliver the stored energy. Here, in this work, we attempted to identify the rate-determining process for Li+ migration under such low temperatures, so that an optimum electrolyte formulation could be designed to maximize the energy output. Substantial increase in available capacities from graphite||LiNi0.80Co0.15Al0.05O2 chemistry down to -40°C is achieved by reducing the solvent molecule that more tightly binds to Li+ and thus constitutes high desolvation energy barrier. Lastly, the fundamental understanding is applicable universally to a wide spectrum of electrochemical devices that have to operate in similar environments.},

  doi          = {10.1021/acsami.7b13887},

  journal      = {ACS Applied Materials and Interfaces},

  number       = 49,

  volume       = 9,

  place        = {United States},

  year         = {2017},

  month        = {11}

}

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Works referencing / citing this record:

Exploiting Mechanistic Solvation Kinetics for Dual‐Graphite Batteries with High Power Output at Extremely Low Temperature
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Title: Li + -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances

Abstract

Citation Formats

Improved low-temperature performance of lithium-ion cells with quaternary carbonate-based electrolytes journal, June 2003

Development of low temperature Li-ion electrolytes for NASA and DoD applications journal, March 2001

Electrochemical performance and kinetics of Li1+x(Co1/3Ni1/3Mn1/3)1−xO2 cathodes and graphite anodes in low-temperature electrolytes journal, June 2007

Limiting factors for low-temperature performance of electrolytes in LiFePO4/Li and graphite/Li half cells journal, January 2012

A low-temperature electrolyte for lithium and lithium-ion batteries journal, June 2000

Optimization of EC-based multi-solvent electrolytes for low temperature applications of lithium-ion batteries journal, October 2004

A new approach toward improved low temperature performance of Li-ion battery journal, November 2002

A new co-solvent for wide temperature lithium ion battery electrolytes: 2,2,2-Trifluoroethyl n-caproate journal, January 2015

Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance journal, January 2010

A low-temperature electrolyte for lithium-ion batteries journal, October 2014

Effect of sulfolane on the performance of lithium bis(oxalato)borate-based electrolytes for advanced lithium ion batteries journal, March 2012

Low-temperature performance of Li-ion cells with a LiBF4-based electrolyte journal, March 2003

Nonaqueous electrolytes for wide-temperature-range operation of Li-ion cells journal, June 2003

Improvement of low-temperature performance by adopting polydimethylsiloxane- g -polyacrylate and lithium-modified silica nanosalt as electrolyte additives in lithium-ion batteries journal, May 2016

Lithium-silica nanosalt as a low-temperature electrolyte additive for lithium-ion batteries journal, June 2016

On the discharge capability and its limiting factors of commercial 18650 Li-ion cell at low temperatures journal, May 2003

Low temperature performance of graphite electrode in Li-ion cells journal, December 2002

The low temperature performance of Li-ion batteries journal, March 2003

Li + -solvation/desolvation dictates interphasial processes on graphitic anode in Li ion cells journal, August 2012

Differentiating Contributions to “Ion Transfer” Barrier from Interphasial Resistance and Li + Desolvation at Electrolyte/Graphite Interface journal, July 2010

Solvated Li-Ion Transfer at Interface Between Graphite and Electrolyte journal, January 2004

Distinguishing Li + Charge Transfer Kinetics at NCA/Electrolyte and Graphite/Electrolyte Interfaces, and NCA/Electrolyte and LFP/Electrolyte Interfaces in Li-Ion Cells journal, January 2012

Electrolytes for Low Temperature Operations of Li-Ion Batteries conference, January 2007

The Role of Cesium Cation in Controlling Interphasial Chemistry on Graphite Anode in Propylene Carbonate-Rich Electrolytes journal, September 2015

Effects of Propylene Carbonate Content in CsPF 6 -Containing Electrolytes on the Enhanced Performances of Graphite Electrode for Lithium-Ion Batteries journal, February 2016

Wide-Temperature Electrolytes for Lithium-Ion Batteries journal, May 2017

Exploiting Mechanistic Solvation Kinetics for Dual‐Graphite Batteries with High Power Output at Extremely Low Temperature journal, November 2019

Low-temperature performance of electrochemical capacitors using acetonitrile/methyl formate electrolytes and activated carbon fabric electrodes journal, January 2020

Exploiting Mechanistic Solvation Kinetics for Dual‐Graphite Batteries with High Power Output at Extremely Low Temperature journal, December 2019

Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments journal, January 2019

Lithium-Ion Cell Fault Detection by Single-Point Impedance Diagnostic and Degradation Mechanism Validation for Series-Wired Batteries Cycled at 0 °C journal, April 2018

Title: Li ⁺ -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances

Improved low-temperature performance of lithium-ion cells with quaternary carbonate-based electrolytes
journal, June 2003

Development of low temperature Li-ion electrolytes for NASA and DoD applications
journal, March 2001

Electrochemical performance and kinetics of Li1+x(Co1/3Ni1/3Mn1/3)1−xO2 cathodes and graphite anodes in low-temperature electrolytes
journal, June 2007

Limiting factors for low-temperature performance of electrolytes in LiFePO4/Li and graphite/Li half cells
journal, January 2012

A low-temperature electrolyte for lithium and lithium-ion batteries
journal, June 2000

Optimization of EC-based multi-solvent electrolytes for low temperature applications of lithium-ion batteries
journal, October 2004

A new approach toward improved low temperature performance of Li-ion battery
journal, November 2002

A new co-solvent for wide temperature lithium ion battery electrolytes: 2,2,2-Trifluoroethyl n-caproate
journal, January 2015

Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance
journal, January 2010

A low-temperature electrolyte for lithium-ion batteries
journal, October 2014

Effect of sulfolane on the performance of lithium bis(oxalato)borate-based electrolytes for advanced lithium ion batteries
journal, March 2012

Low-temperature performance of Li-ion cells with a LiBF4-based electrolyte
journal, March 2003

Nonaqueous electrolytes for wide-temperature-range operation of Li-ion cells
journal, June 2003

Improvement of low-temperature performance by adopting polydimethylsiloxane- g -polyacrylate and lithium-modified silica nanosalt as electrolyte additives in lithium-ion batteries
journal, May 2016

Lithium-silica nanosalt as a low-temperature electrolyte additive for lithium-ion batteries
journal, June 2016

On the discharge capability and its limiting factors of commercial 18650 Li-ion cell at low temperatures
journal, May 2003

Low temperature performance of graphite electrode in Li-ion cells
journal, December 2002

The low temperature performance of Li-ion batteries
journal, March 2003

Li ⁺ -solvation/desolvation dictates interphasial processes on graphitic anode in Li ion cells
journal, August 2012

Differentiating Contributions to “Ion Transfer” Barrier from Interphasial Resistance and Li ⁺ Desolvation at Electrolyte/Graphite Interface
journal, July 2010

Solvated Li-Ion Transfer at Interface Between Graphite and Electrolyte
journal, January 2004

Distinguishing Li ⁺ Charge Transfer Kinetics at NCA/Electrolyte and Graphite/Electrolyte Interfaces, and NCA/Electrolyte and LFP/Electrolyte Interfaces in Li-Ion Cells
journal, January 2012

Electrolytes for Low Temperature Operations of Li-Ion Batteries
conference, January 2007

The Role of Cesium Cation in Controlling Interphasial Chemistry on Graphite Anode in Propylene Carbonate-Rich Electrolytes
journal, September 2015

Effects of Propylene Carbonate Content in CsPF ₆ -Containing Electrolytes on the Enhanced Performances of Graphite Electrode for Lithium-Ion Batteries
journal, February 2016

Wide-Temperature Electrolytes for Lithium-Ion Batteries
journal, May 2017

Exploiting Mechanistic Solvation Kinetics for Dual‐Graphite Batteries with High Power Output at Extremely Low Temperature
journal, November 2019

Low-temperature performance of electrochemical capacitors using acetonitrile/methyl formate electrolytes and activated carbon fabric electrodes
journal, January 2020

Exploiting Mechanistic Solvation Kinetics for Dual‐Graphite Batteries with High Power Output at Extremely Low Temperature
journal, December 2019

Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments
journal, January 2019

Lithium-Ion Cell Fault Detection by Single-Point Impedance Diagnostic and Degradation Mechanism Validation for Series-Wired Batteries Cycled at 0 °C
journal, April 2018