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Title: Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

Metal–organic layers stabilize Fe II or Co II -terpyridine diradical complexes to catalyze alkylazide C sp3 –H amination and benzylic C–H borylation, respectively.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [2] ;  [3] ; ORCiD logo [2] ; ORCiD logo [4]
  1. Department of Chemistry, University of Chicago, Chicago, USA
  2. Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
  3. Research Computing Center, University of North Carolina, USA
  4. Department of Chemistry, University of Chicago, Chicago, USA, Collaborative Innovation Center of Chemistry for Energy Materials
Publication Date:
Grant/Contract Number:
AC02-06CH11357
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 1; Related Information: CHORUS Timestamp: 2017-12-20 07:17:00; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1408785