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Title: Aluminum-induced dreierketten chain cross-links increase the mechanical properties of nanocrystalline calcium aluminosilicate hydrate

The incorporation of Al and increased curing temperature promotes the crystallization and cross-linking of calcium (alumino)silicate hydrate (C-(A-)S-H), which is the primary binding phase in most contemporary concrete materials. However, the influence of Al-induced structural changes on the mechanical properties at atomistic scale is not well understood. Herein, synchrotron radiation-based high-pressure X-ray diffraction is used to quantify the influence of dreierketten chain cross-linking on the anisotropic mechanical behavior of C-(A-)S-H. We show that the ab-planar stiffness is independent of dreierketten chain defects, e.g. vacancies in bridging tetrahedra sites and Al for Si substitution. The c-axis of non-cross-linked C-(A-)S-H is more deformable due to the softer interlayer opening but stiffens with decreased spacing and/or increased zeolitic water and Ca 2+ of the interlayer. Dreierketten chain cross-links act as ‘columns’ to resist compression, thus increasing the bulk modulus of C-(A-)S-H. We provide the first experimental evidence on the influence of the Al-induced atomistic configurational change on the mechanical properties of C-(A-)S-H. Our work advances the fundamental knowledge of C-(A-)S-H on the lowest level of its hierarchical structure, and thus can impact the way that innovative C-(A-)S-H-based cementitious materials are developed using a ‘bottom-up’ approach.
Authors:
 [1] ;  [2] ;  [1] ;  [3] ;  [3] ;  [4] ;  [5]
  1. Univ. of California, Berkeley, CA (United States). Dept. of Civil and Environmental Engineering
  2. Univ. of California, Berkeley, CA (United States). Dept. of Civil and Environmental Engineering; Yale Univ., New Haven, CT (United States). School of Forestry & Environmental Studies
  3. Univ. of California, Berkeley, CA (United States). Dept. of Chemical & Biomolecular Engineering
  4. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
  5. Univ. of California, Berkeley, CA (United States). Dept. of Civil and Environmental Engineering; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Publication Date:
Grant/Contract Number:
AC02-05CH11231; DMR-1410557; 201206090127
Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Research Org:
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF); National Research Foundation (Singapore); Chinese Scholarship Council
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; civil engineering; mechanical properties; mineralogy
OSTI Identifier:
1408423

Geng, Guoqing, Myers, Rupert J., Li, Jiaqi, Maboudian, Roya, Carraro, Carlo, Shapiro, David A., and Monteiro, Paulo J. M.. Aluminum-induced dreierketten chain cross-links increase the mechanical properties of nanocrystalline calcium aluminosilicate hydrate. United States: N. p., Web. doi:10.1038/srep44032.
Geng, Guoqing, Myers, Rupert J., Li, Jiaqi, Maboudian, Roya, Carraro, Carlo, Shapiro, David A., & Monteiro, Paulo J. M.. Aluminum-induced dreierketten chain cross-links increase the mechanical properties of nanocrystalline calcium aluminosilicate hydrate. United States. doi:10.1038/srep44032.
Geng, Guoqing, Myers, Rupert J., Li, Jiaqi, Maboudian, Roya, Carraro, Carlo, Shapiro, David A., and Monteiro, Paulo J. M.. 2017. "Aluminum-induced dreierketten chain cross-links increase the mechanical properties of nanocrystalline calcium aluminosilicate hydrate". United States. doi:10.1038/srep44032. https://www.osti.gov/servlets/purl/1408423.
@article{osti_1408423,
title = {Aluminum-induced dreierketten chain cross-links increase the mechanical properties of nanocrystalline calcium aluminosilicate hydrate},
author = {Geng, Guoqing and Myers, Rupert J. and Li, Jiaqi and Maboudian, Roya and Carraro, Carlo and Shapiro, David A. and Monteiro, Paulo J. M.},
abstractNote = {The incorporation of Al and increased curing temperature promotes the crystallization and cross-linking of calcium (alumino)silicate hydrate (C-(A-)S-H), which is the primary binding phase in most contemporary concrete materials. However, the influence of Al-induced structural changes on the mechanical properties at atomistic scale is not well understood. Herein, synchrotron radiation-based high-pressure X-ray diffraction is used to quantify the influence of dreierketten chain cross-linking on the anisotropic mechanical behavior of C-(A-)S-H. We show that the ab-planar stiffness is independent of dreierketten chain defects, e.g. vacancies in bridging tetrahedra sites and Al for Si substitution. The c-axis of non-cross-linked C-(A-)S-H is more deformable due to the softer interlayer opening but stiffens with decreased spacing and/or increased zeolitic water and Ca2+ of the interlayer. Dreierketten chain cross-links act as ‘columns’ to resist compression, thus increasing the bulk modulus of C-(A-)S-H. We provide the first experimental evidence on the influence of the Al-induced atomistic configurational change on the mechanical properties of C-(A-)S-H. Our work advances the fundamental knowledge of C-(A-)S-H on the lowest level of its hierarchical structure, and thus can impact the way that innovative C-(A-)S-H-based cementitious materials are developed using a ‘bottom-up’ approach.},
doi = {10.1038/srep44032},
journal = {Scientific Reports},
number = ,
volume = 7,
place = {United States},
year = {2017},
month = {3}
}

Works referenced in this record:

Model structures for C-(A)-S-H(I)
journal, November 2014
  • Richardson, Ian G.
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  • DOI: 10.1107/S2052520614021982

X-ray diffraction: a powerful tool to probe and understand the structure of nanocrystalline calcium silicate hydrates
journal, September 2013
  • Grangeon, Sylvain; Claret, Francis; Linard, Yannick
  • Acta Crystallographica Section B Structural Science Crystal Engineering and Materials, Vol. 69, Issue 5, p. 465-473
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