Synergetic effects of K + and Mg 2+ ion intercalation on the electrochemical and actuation properties of the two-dimensional Ti 3 C 2 MXene
Abstract
Two-dimensional materials, such as MXenes, are attractive candidates for energy storage and electrochemical actuators due to their high volume changes upon ion intercalation. Of special interest for boosting energy storage is the intercalation of multivalent ions such as Mg 2+, which suffers from sluggish intercalation and transport kinetics due to its ion size. By combining traditional electrochemical characterization techniques with electrochemical dilatometry and contact resonance atomic force microscopy, the synergetic effects of the pre-intercalation of K +ions are demonstrated to improve the charge storage of multivalent ions, as well as tune the mechanical and actuation properties of the Ti 3C 2MXene. Our results have important implications for quantitatively understanding the charge storage processes in intercalation compounds and provide a new path for studying the mechanical evolution of energy storage materials.
- Authors:
-
[1];
[1];
[2];
[1];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
- Drexel Univ., Philadelphia, PA (United States). Dept. of Materials Science and Engineering, A.J. Drexel Nanomaterials Inst.
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- OSTI Identifier:
- 1408018
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Faraday Discussions
- Additional Journal Information:
- Journal Volume: 199; Journal Issue: 1; Journal ID: ISSN 1359-6640
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Gao, Qiang, Come, Jeremy, Naguib, Michael, Jesse, Stephen, Gogotsi, Yury, and Balke, Nina. Synergetic effects of K + and Mg 2+ ion intercalation on the electrochemical and actuation properties of the two-dimensional Ti 3 C 2 MXene. United States: N. p., 2017.
Web. doi:10.1039/C6FD00251J.
Gao, Qiang, Come, Jeremy, Naguib, Michael, Jesse, Stephen, Gogotsi, Yury, & Balke, Nina. Synergetic effects of K + and Mg 2+ ion intercalation on the electrochemical and actuation properties of the two-dimensional Ti 3 C 2 MXene. United States. doi:10.1039/C6FD00251J.
Gao, Qiang, Come, Jeremy, Naguib, Michael, Jesse, Stephen, Gogotsi, Yury, and Balke, Nina. Sun .
"Synergetic effects of K + and Mg 2+ ion intercalation on the electrochemical and actuation properties of the two-dimensional Ti 3 C 2 MXene". United States. doi:10.1039/C6FD00251J. https://www.osti.gov/servlets/purl/1408018.
@article{osti_1408018,
title = {Synergetic effects of K + and Mg 2+ ion intercalation on the electrochemical and actuation properties of the two-dimensional Ti 3 C 2 MXene},
author = {Gao, Qiang and Come, Jeremy and Naguib, Michael and Jesse, Stephen and Gogotsi, Yury and Balke, Nina},
abstractNote = {Two-dimensional materials, such as MXenes, are attractive candidates for energy storage and electrochemical actuators due to their high volume changes upon ion intercalation. Of special interest for boosting energy storage is the intercalation of multivalent ions such as Mg2+, which suffers from sluggish intercalation and transport kinetics due to its ion size. By combining traditional electrochemical characterization techniques with electrochemical dilatometry and contact resonance atomic force microscopy, the synergetic effects of the pre-intercalation of K+ions are demonstrated to improve the charge storage of multivalent ions, as well as tune the mechanical and actuation properties of the Ti3C2MXene. Our results have important implications for quantitatively understanding the charge storage processes in intercalation compounds and provide a new path for studying the mechanical evolution of energy storage materials.},
doi = {10.1039/C6FD00251J},
journal = {Faraday Discussions},
number = 1,
volume = 199,
place = {United States},
year = {2017},
month = {1}
}
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 4 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
In Situ Electrochemical Dilatometry of Onion-Like Carbon and Carbon Black
journal, January 2012
- Hantel, M. M.; Presser, V.; McDonough, J. K.
- Journal of The Electrochemical Society, Vol. 159, Issue 11
Electrochemical in Situ Tracking of Volumetric Changes in Two-Dimensional Metal Carbides (MXenes) in Ionic Liquids
journal, November 2016
- Jäckel, Nicolas; Krüner, Benjamin; Van Aken, Katherine L.
- ACS Applied Materials & Interfaces, Vol. 8, Issue 47
The Electrochemical Reaction of Lithium with Tin Studied By In Situ AFM
journal, January 2003
- Beaulieu, L. Y.; Beattie, S. D.; Hatchard, T. D.
- Journal of The Electrochemical Society, Vol. 150, Issue 4
The band excitation method in scanning probe microscopy for rapid mapping of energy dissipation on the nanoscale
journal, September 2007
- Jesse, Stephen; Kalinin, Sergei V.; Proksch, Roger
- Nanotechnology, Vol. 18, Issue 43
Mapping nanoscale elasticity and dissipation using dual frequency contact resonance AFM
journal, August 2011
- Gannepalli, A.; Yablon, D. G.; Tsou, A. H.
- Nanotechnology, Vol. 22, Issue 35
Controlling the actuation properties of MXene paper electrodes upon cation intercalation
journal, October 2015
- Come, Jeremy; Black, Jennifer M.; Lukatskaya, Maria R.
- Nano Energy, Vol. 17
Nanoscale Elastic Changes in 2D Ti 3 C 2 T x (MXene) Pseudocapacitive Electrodes
journal, March 2016
- Come, Jeremy; Xie, Yu; Naguib, Michael
- Advanced Energy Materials, Vol. 6, Issue 9
In situ atomic force microscopy study of dimensional changes during Li+ ion intercalation/de-intercalation in highly oriented pyrolytic graphite
journal, January 2005
- Campana, F. P.; Kötz, R.; Vetter, J.
- Electrochemistry Communications, Vol. 7, Issue 1
In situ electrochemical dilatometry of carbide-derived carbons
journal, November 2011
- Hantel, M. M.; Presser, V.; Kötz, R.
- Electrochemistry Communications, Vol. 13, Issue 11
Anisometric charge dependent swelling of porous carbon in an ionic liquid
journal, September 2013
- Kaasik, F.; Tamm, T.; Hantel, M. M.
- Electrochemistry Communications, Vol. 34
Solving the Capacitive Paradox of 2D MXene using Electrochemical Quartz-Crystal Admittance and In Situ Electronic Conductance Measurements
journal, August 2014
- Levi, Mikhael D.; Lukatskaya, Maria R.; Sigalov, Sergey
- Advanced Energy Materials, Vol. 5, Issue 1
Quartz Crystal Microbalance with Dissipation Monitoring (EQCM-D) for in-situ studies of electrodes for supercapacitors and batteries: A mini-review
journal, June 2016
- Levi, Mikhael D.; Daikhin, Leonid; Aurbach, Doron
- Electrochemistry Communications, Vol. 67
Carbons and Electrolytes for Advanced Supercapacitors
journal, February 2014
- Béguin, François; Presser, Volker; Balducci, Andrea
- Advanced Materials, Vol. 26, Issue 14, p. 2219-2251
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide
journal, September 2013
- Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E.
- Science, Vol. 341, Issue 6153
Quantitative Viscoelastic Mapping of Polyolefin Blends with Contact Resonance Atomic Force Microscopy
journal, May 2012
- Yablon, Dalia G.; Gannepalli, Anil; Proksch, Roger
- Macromolecules, Vol. 45, Issue 10
Where Do Batteries End and Supercapacitors Begin?
journal, March 2014
- Simon, P.; Gogotsi, Y.; Dunn, B.
- Science, Vol. 343, Issue 6176
Strain-Based In Situ Study of Anion and Cation Insertion into Porous Carbon Electrodes with Different Pore Sizes
journal, October 2013
- Black, Jennifer M.; Feng, Guang; Fulvio, Pasquale F.
- Advanced Energy Materials, Vol. 4, Issue 3
In situ tracking of the nanoscale expansion of porous carbon electrodes
journal, January 2013
- Arruda, Thomas M.; Heon, Min; Presser, Volker
- Energy Environ. Sci., Vol. 6, Issue 1
Multidimensional materials and device architectures for future hybrid energy storage
journal, September 2016
- Lukatskaya, Maria R.; Dunn, Bruce; Gogotsi, Yury
- Nature Communications, Vol. 7, Issue 1
Quantification of surface displacements and electromechanical phenomena via dynamic atomic force microscopy
journal, September 2016
- Balke, Nina; Jesse, Stephen; Yu, Pu
- Nanotechnology, Vol. 27, Issue 42
Flexible and conductive MXene films and nanocomposites with high capacitance
journal, November 2014
- Ling, Zheng; Ren, Chang E.; Zhao, Meng-Qiang
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 47
In situ scanning probe microscopy investigations of electroactive films
journal, March 1998
- Häring, P.; Kötz, R.; Repphun, G.
- Applied Physics A: Materials Science & Processing, Vol. 66, Issue 7
Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries
journal, August 2014
- Xie, Yu; Dall’Agnese, Yohan; Naguib, Michael
- ACS Nano, Vol. 8, Issue 9
Ion-Exchange and Cation Solvation Reactions in Ti 3 C 2 MXene
journal, May 2016
- Ghidiu, Michael; Halim, Joseph; Kota, Sankalp
- Chemistry of Materials, Vol. 28, Issue 10
Probing the Mechanism of High Capacitance in 2D Titanium Carbide Using In Situ X-Ray Absorption Spectroscopy
journal, May 2015
- Lukatskaya, Maria R.; Bak, Seong-Min; Yu, Xiqian
- Advanced Energy Materials, Vol. 5, Issue 15
Contact resonance atomic force microscopy imaging in air and water using photothermal excitation
journal, August 2015
- Kocun, Marta; Labuda, Aleksander; Gannepalli, Anil
- Review of Scientific Instruments, Vol. 86, Issue 8
Nanoscale mapping of ion diffusion in a lithium-ion battery cathode
journal, August 2010
- Balke, N.; Jesse, S.; Morozovska, A. N.
- Nature Nanotechnology, Vol. 5, Issue 10
Effect of Metal Ion Intercalation on the Structure of MXene and Water Dynamics on its Internal Surfaces
journal, March 2016
- Osti, Naresh C.; Naguib, Michael; Ostadhossein, Alireza
- ACS Applied Materials & Interfaces, Vol. 8, Issue 14