skip to main content

DOE PAGESDOE PAGES

Title: In-situ neutron imaging of hydrogenous fuels in combustion generated porous carbons under dynamic and steady state pressure conditions

Here, we report results from experiments where we characterize the surface properties of soot particles interacting with high-pressure methane. We also found considerable differences in behavior of the soot material between static and dynamic pressure conditions that can be explained by multiscale correlations in the dynamics, from the micro to macro of the porous fractal-like carbon matrix. The measurements were possible utilizing cold neutron imaging of methane mixed with combustion generated carbon (soot) inside steel cells. The studies were performed under static and dynamic pressure conditions in the range 10-90 bar, and are of interest for applications of energy storage of hydrogenous fuels. The very high cross sections for neutrons compared to hard X-ray photons, enabled us to find considerable amounts of native hydrogen in the soot and to see and quantify the presence of hydrogen atoms in the carbon soot matrix under different pressure conditions. Our work lays the base for more detailed in-situ investigations on the interaction of porous carbon materials with hydrogen in practical environments for hydrogen and methane storage.
Authors:
 [1] ; ORCiD logo [2] ; ORCiD logo [2]
  1. Lund Univ. (Sweden). Combustion Physics
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
Carbon
Additional Journal Information:
Journal Volume: 116; Journal Issue: C; Journal ID: ISSN 0008-6223
Publisher:
Elsevier
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; in-situ measurements; high pressure; soot; adsorption; methane; neutron radiography; pressure
OSTI Identifier:
1407995
Alternate Identifier(s):
OSTI ID: 1396889

Ossler, Frederik, Santodonato, Louis J., and Bilheux, Hassina Z.. In-situ neutron imaging of hydrogenous fuels in combustion generated porous carbons under dynamic and steady state pressure conditions. United States: N. p., Web. doi:10.1016/j.carbon.2017.02.025.
Ossler, Frederik, Santodonato, Louis J., & Bilheux, Hassina Z.. In-situ neutron imaging of hydrogenous fuels in combustion generated porous carbons under dynamic and steady state pressure conditions. United States. doi:10.1016/j.carbon.2017.02.025.
Ossler, Frederik, Santodonato, Louis J., and Bilheux, Hassina Z.. 2017. "In-situ neutron imaging of hydrogenous fuels in combustion generated porous carbons under dynamic and steady state pressure conditions". United States. doi:10.1016/j.carbon.2017.02.025. https://www.osti.gov/servlets/purl/1407995.
@article{osti_1407995,
title = {In-situ neutron imaging of hydrogenous fuels in combustion generated porous carbons under dynamic and steady state pressure conditions},
author = {Ossler, Frederik and Santodonato, Louis J. and Bilheux, Hassina Z.},
abstractNote = {Here, we report results from experiments where we characterize the surface properties of soot particles interacting with high-pressure methane. We also found considerable differences in behavior of the soot material between static and dynamic pressure conditions that can be explained by multiscale correlations in the dynamics, from the micro to macro of the porous fractal-like carbon matrix. The measurements were possible utilizing cold neutron imaging of methane mixed with combustion generated carbon (soot) inside steel cells. The studies were performed under static and dynamic pressure conditions in the range 10-90 bar, and are of interest for applications of energy storage of hydrogenous fuels. The very high cross sections for neutrons compared to hard X-ray photons, enabled us to find considerable amounts of native hydrogen in the soot and to see and quantify the presence of hydrogen atoms in the carbon soot matrix under different pressure conditions. Our work lays the base for more detailed in-situ investigations on the interaction of porous carbon materials with hydrogen in practical environments for hydrogen and methane storage.},
doi = {10.1016/j.carbon.2017.02.025},
journal = {Carbon},
number = C,
volume = 116,
place = {United States},
year = {2017},
month = {2}
}