Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes

doi:10.1002/chem.201704782

Title: Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes

Authors:

Vilanova, Sean P. ^[1]; Alayoglu, Pinar ^[2]; Heidarian, Mohammad ^[2]; Huang, Patrick ^[2];

^[1]

Department of Chemistry, University of Missouri, Columbia MO 65211 USA
Department of Chemistry, California State University East Bay, Hayward CA 94542 USA

Publication Date:: 2017-11-07

Sponsoring Org.:: USDOE

OSTI Identifier:: 1407832

Grant/Contract Number:: SC-0014174

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Chemistry - A European Journal

Additional Journal Information:: Journal Name: Chemistry - A European Journal Journal Volume: 23 Journal Issue: 66; Journal ID: ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Vilanova, Sean P., Alayoglu, Pinar, Heidarian, Mohammad, Huang, Patrick, and Walensky, Justin R. Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes.  Germany: N. p., 2017. 
        Web.  doi:10.1002/chem.201704782.

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                    Vilanova, Sean P., Alayoglu, Pinar, Heidarian, Mohammad, Huang, Patrick, & Walensky, Justin R. Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes.  Germany.  doi:10.1002/chem.201704782.

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                    Vilanova, Sean P., Alayoglu, Pinar, Heidarian, Mohammad, Huang, Patrick, and Walensky, Justin R. Tue .  
        "Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes".  Germany.  doi:10.1002/chem.201704782.

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@article{osti_1407832,

  title        = {Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes},

  author       = {Vilanova, Sean P. and Alayoglu, Pinar and Heidarian, Mohammad and Huang, Patrick and Walensky, Justin R.},

  abstractNote = {},

  doi          = {10.1002/chem.201704782},

  journal      = {Chemistry - A European Journal},

  number       = 66,

  volume       = 23,

  place        = {Germany},

  year         = {2017},

  month        = {11}

}

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DOI: 10.1002/chem.201704782

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Works referenced in this record:

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Title: Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes

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N-Heterocyclic Carbene Functionalized Group 7−9 Transition Metal Phosphinidene Complexes journal, September 2009

Remarkably Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene, and Imide Functionalities journal, March 2005

Arsinidene, Phosphinidene, and Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E = N, P, As): Structures of (silox)3Ta:EPh (E = P, As) journal, November 1994

A Lanthanide Phosphinidene Complex: Synthesis, Structure, and Phospha-Wittig Reactivity journal, February 2008

Triamidoamine uranium(IV)–arsenic complexes containing one-, two- and threefold U–As bonding interactions journal, June 2015

Nucleophile Phosphinidenkomplexe: Synthese und Anwendungen journal, March 2010

Synthesis and Reactions of Terminal Osmium and Ruthenium Complexed Phosphinidenes [(6-Ar)(L)MPMes*] journal, May 2003

Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions journal, September 2016

Preparation of Actinide Phosphinidene Complexes: Steric Control of Reactivity journal, January 1996

Reactivity of Terminal, Electrophilic Phosphinidene Complexes of Molybdenum and Tungsten. Nucleophilic Addition at Phosphorus and P−P Bond Forming Reactions with Phosphines and Diphosphines journal, February 2007

Formation and reactivity of the early metal phosphides and phosphinidenes Cp*2Zr:PR, Cp*2Zr(PR)2, and Cp*2Zr(PR)3 journal, August 1993

Crystalline Diuranium Phosphinidiide and μ-Phosphido Complexes with Symmetric and Asymmetric UPU Cores journal, July 2017

Synthesis and Structural Characterization of the First Thermally Stable, Neutral, and Electrophilic Phosphinidene Complexes of Vanadium journal, March 2011

Terminal Aminophosphinidene Complexes of Iron, Ruthenium, and Osmium journal, September 2003

Monomeric Phosphido and Phosphinidene Complexes of Nickel journal, April 2002

Influencing the properties of dysprosium single-molecule magnets with phosphorus donor ligands journal, July 2015

Terminal and Four-Coordinate Vanadium(IV) Phosphinidene Complexes. A Pseudo Jahn−Teller Effect of Second Order Stabilizing the V−P Multiple Bond
journal, February 2004

Covalency in AnCp4 (An = Th–Cm): a comparison of molecular orbital, natural population and atoms-in-molecules analyses
journal, January 2010

Ruthenium-Stabilized Low-Coordinate Phosphorus Atoms. p -Cymene Ligand as Reactivity Switch
journal, September 2007

Terminal Phosphinidene Complexes Cp ^R (L)MPAr of the Group 9 Transition Metals Cobalt, Rhodium, and Iridium. Synthesis, Structures, and Properties
journal, April 2003

N-Heterocyclic Carbene-Functionalized Ruthenium Phosphinidenes: What a Difference a Twist Makes
journal, May 2009

Neutral and Zwitterionic Low-Coordinate Titanium Complexes Bearing the Terminal Phosphinidene Functionality. Structural, Spectroscopic, Theoretical, and Catalytic Studies Addressing the Ti−P Multiple Bond
journal, October 2006

Terminal hafnium phosphinidene complexes and phosphinidene ligand exchange
journal, January 2011

Electrophilic “Fischer Type” Phosphinidene Complexes of Molybdenum, Tungsten, and Ruthenium
journal, June 2001

Formation of a Bridging Phosphinidene Thorium Complex
journal, November 2015

N-Heterocyclic Carbene Functionalized Iridium Phosphinidene Complex [Cp(NHC)IrPMes]: Comparison of Phosphinidene, Imido, and Carbene Complexes
journal, August 2003

Insertion of ^t BuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry
journal, January 2016

Phosphinidenetantalum(V) Complexes of the Type[(N3N)TaPR] as Phospha-Wittig Reagents
journal, May 1993

The first stable transition metal (molybdenum or tungsten) complexes having a metal–phosphorus( III ) double bond: the phosphorus analogues of metal aryl- and alkyl-imides; X-ray structure of [Mo(η-C ₅ H ₅ ) ₂ (PAr)](Ar = C ₆ H ₂ Bu ^t ₃ -2,4,6)
journal, January 1987

Phospha- and Arsaalkenes RE=C(NMe2)2 (E = P, As) as Novel Phosphinidene- and Arsinidene-Transfer Reagents
journal, September 2007

Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning
journal, June 2012

A Thermally Stable and Sterically Unprotected Terminal Electrophilic Phosphinidene Complex of Cobalt and Its Conversion to an η ¹ -Phosphirene
journal, March 2003

Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes
journal, March 2014

Reactivity of Electrophilic Terminal Phosphinidene Complexes: P−P Bond Forming Reactions with Phosphines and Diphosphines
journal, October 2001

Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
journal, March 2017

Anionic and Mononuclear Phosphinidene and Imide Complexes of Niobium
journal, August 2015

Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV)
journal, May 2017

Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling
journal, January 2017

Organoactinide phosphine/phosphite coordination chemistry. Facile hydride-induced dealkoxylation and the formation of actinide phosphinidene complexes
journal, May 1984

Magneto-structural correlations in arsenic- and selenium-ligated dysprosium single-molecule magnets
journal, January 2016

Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds
journal, January 2009

Nucleophilic Phosphinidene Complexes: Access and Applicability
journal, March 2010

Terminal Phosphinidene and Heavier Congeneric Complexes. The Quest Is Over
journal, November 1997

Four-Coordinate Phosphinidene Complexes of Titanium Prepared by α-H-Migration: Phospha-Staudinger and Phosphaalkene-Insertion Reactions
journal, August 2003

Synthesis of Novel Terminal Iridium Phosphinidene Complexes
journal, July 2002

Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes
journal, March 2014

Metal-phosphido and -phosphinidene complexes in P–E bond-forming reactions
journal, January 2009

Phosphinidentantal(v)-Komplexe des Typs [(N3N)TaPR] als Phospha-Wittig-Reagentien (R = Ph, Cy,tBu; N3N = (Me3SiNCH2CH2)3N)
journal, May 1993

Matrix Infrared Spectra and Quantum Chemical Calculations of Ti, Zr, and Hf Dihydride Phosphinidene and Arsinidene Molecules
journal, August 2016

Terminal phosphinidene formation via tantalaziridine complexes
journal, January 2012

Nucleophilic or Electrophilic Phosphinidene Complexes ML _n PH; What Makes the Difference?
journal, March 2002

Crystalline Diuranium Phosphinidiide and μ-Phosphido Complexes with Symmetric and Asymmetric UPU Cores
journal, July 2017

N-Heterocyclic Carbene Functionalized Group 7−9 Transition Metal Phosphinidene Complexes
journal, September 2009

Remarkably Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene, and Imide Functionalities
journal, March 2005

Arsinidene, Phosphinidene, and Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E = N, P, As): Structures of (silox)3Ta:EPh (E = P, As)
journal, November 1994

A Lanthanide Phosphinidene Complex: Synthesis, Structure, and Phospha-Wittig Reactivity
journal, February 2008

Triamidoamine uranium(IV)–arsenic complexes containing one-, two- and threefold U–As bonding interactions
journal, June 2015

Nucleophile Phosphinidenkomplexe: Synthese und Anwendungen
journal, March 2010

Synthesis and Reactions of Terminal Osmium and Ruthenium Complexed Phosphinidenes [(6-Ar)(L)MPMes*]
journal, May 2003

Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
journal, September 2016

Preparation of Actinide Phosphinidene Complexes: Steric Control of Reactivity
journal, January 1996

Reactivity of Terminal, Electrophilic Phosphinidene Complexes of Molybdenum and Tungsten. Nucleophilic Addition at Phosphorus and P−P Bond Forming Reactions with Phosphines and Diphosphines
journal, February 2007

Formation and reactivity of the early metal phosphides and phosphinidenes Cp2Zr:PR, Cp2Zr(PR)2, and Cp*2Zr(PR)3
journal, August 1993

Crystalline Diuranium Phosphinidiide and μ-Phosphido Complexes with Symmetric and Asymmetric UPU Cores
journal, July 2017

Synthesis and Structural Characterization of the First Thermally Stable, Neutral, and Electrophilic Phosphinidene Complexes of Vanadium
journal, March 2011

Terminal Aminophosphinidene Complexes of Iron, Ruthenium, and Osmium
journal, September 2003

Monomeric Phosphido and Phosphinidene Complexes of Nickel
journal, April 2002

Influencing the properties of dysprosium single-molecule magnets with phosphorus donor ligands
journal, July 2015