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Title: Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification

We report a simple route to engineer ultrathin polymer brush surfaces with wrinkled morphologies using postpolymerization modification (PPM), where the length scale of the buckled features can be tuned using PPM reaction time. Here, we show that partial crosslinking of the outer layer of the polymer brush under poor solvent conditions is critical to obtain wrinkled morphologies upon swelling.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [2] ; ORCiD logo [3] ; ORCiD logo [3] ;  [3] ; ORCiD logo [1]
  1. Univ. of Southern Mississippi, Hattiesburg, MS (United States)
  2. National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
Macromolecules
Additional Journal Information:
Journal Volume: 50; Journal Issue: 21; Journal ID: ISSN 0024-9297
Publisher:
American Chemical Society
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; polymer brush; postpolymerization modification; wrinkling; creasing; ultrathin
OSTI Identifier:
1407766

Guo, Wei, Reese, Cassandra M., Xiong, Li, Logan, Phillip K., Thompson, Brittany J., Stafford, Christopher M., Ievlev, Anton V., Lokitz, Bradley S., Ovchinnikova, Olga S., and Patton, Derek L.. Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification. United States: N. p., Web. doi:10.1021/acs.macromol.7b01888.
Guo, Wei, Reese, Cassandra M., Xiong, Li, Logan, Phillip K., Thompson, Brittany J., Stafford, Christopher M., Ievlev, Anton V., Lokitz, Bradley S., Ovchinnikova, Olga S., & Patton, Derek L.. Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification. United States. doi:10.1021/acs.macromol.7b01888.
Guo, Wei, Reese, Cassandra M., Xiong, Li, Logan, Phillip K., Thompson, Brittany J., Stafford, Christopher M., Ievlev, Anton V., Lokitz, Bradley S., Ovchinnikova, Olga S., and Patton, Derek L.. 2017. "Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification". United States. doi:10.1021/acs.macromol.7b01888. https://www.osti.gov/servlets/purl/1407766.
@article{osti_1407766,
title = {Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification},
author = {Guo, Wei and Reese, Cassandra M. and Xiong, Li and Logan, Phillip K. and Thompson, Brittany J. and Stafford, Christopher M. and Ievlev, Anton V. and Lokitz, Bradley S. and Ovchinnikova, Olga S. and Patton, Derek L.},
abstractNote = {We report a simple route to engineer ultrathin polymer brush surfaces with wrinkled morphologies using postpolymerization modification (PPM), where the length scale of the buckled features can be tuned using PPM reaction time. Here, we show that partial crosslinking of the outer layer of the polymer brush under poor solvent conditions is critical to obtain wrinkled morphologies upon swelling.},
doi = {10.1021/acs.macromol.7b01888},
journal = {Macromolecules},
number = 21,
volume = 50,
place = {United States},
year = {2017},
month = {10}
}