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Title: A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Journal Article · · ChemComm
DOI: https://doi.org/10.1039/c7cc05988d · OSTI ID:1406758
ORCiD logo [1]; ORCiD logo [2];  [3];  [3]; ORCiD logo [4];  [2]; ORCiD logo [1]
  1. George Washington Univ., Washington, DC (United States)
  2. Univ. of São Paulo (Brazil)
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  4. Univ. at Buffalo, State Univ. of New York, Buffalo, NY (United States)
+ Show Author Affiliations

Here, a novel hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·Cl·2H2O, is prepared from aqueous media and the non-covalent interaction pairings are rationalized using electrostatic potentials.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC05-76RL01830
OSTI ID:
1406758
Report Number(s):
PNNL-SA--128010; 45304036L
Journal Information:
ChemComm, Journal Name: ChemComm Journal Issue: 78 Vol. 53; ISSN CHCOFS; ISSN 1359-7345
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

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