A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5 ]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

Surbella, III, Robert G.; Ducati, Lucas C.; Pellegrini, Kristi L.; McNamara, Bruce K.; Autschbach, Jochen; Schwantes, Jon M.; Cahill, Christopher L.

doi:10.1039/c7cc05988d

Title: A new Pu(iii) coordination geometry in (C₅H₅NBr)₂[PuCl₃(H₂O)₅ ]·2Cl·2H₂O as obtained via supramolecular assembly in aqueous, high chloride media

Journal Article · 12 September 2017 · ChemComm

DOI: https://doi.org/10.1039/c7cc05988d · OSTI ID:1406758

^[1];

^[2]; Pellegrini, Kristi L. ^[3]; McNamara, Bruce K. ^[3];

^[4]; Schwantes, Jon M. ^[2];

^[1]

George Washington Univ., Washington, DC (United States)
Univ. of São Paulo (Brazil)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Univ. at Buffalo, State Univ. of New York, Buffalo, NY (United States)

Here, a novel hydrated Pu(iii) chloride, (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·Cl·2H₂O, is prepared from aqueous media and the non-covalent interaction pairings are rationalized using electrostatic potentials.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1406758

Report Number(s):: PNNL-SA-128010; CHCOFS; 45304036L

Journal Information:: ChemComm, Vol. 53, Issue 78; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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