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Title: Composition-dependent surface chemistry of colloidal Ba xSr 1-xTiO 3 perovskite nanocrystals

Ba xSr 1-xTiO 3 perovskite nanocrystals, prepared by the vapor diffusion sol-gel method and characterized by state of the art surface techniques, display significantly different O-H stretching frequencies and adsorption properties towards CO 2 as a function of the alkaline earth composition (Ba vs. Sr). Lastly, the difference of properties can be associated with the more basic nature of BaO-rich than SrO-rich surfaces.
Authors:
 [1] ;  [2] ;  [1] ;  [3] ;  [2] ;  [1]
  1. Federal Inst. of Technology, Zurich (Switzerland). Dept. of Chemistry and Applied Biosciences
  2. Univ. of Southern California, Los Angeles, CA (United States). Dept. of Chemistry
  3. Iowa State Univ., Ames, IA (United States). Dept. of Chemistry
Publication Date:
Grant/Contract Number:
SC0006812; FG02-11ER46826
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 52; Journal Issue: 95; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Univ. of Southern California, Los Angeles, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1406132

Margossian, Tigran, Culver, Sean P., Larmier, Kim, Zhu, Feng, Brutchey, Richard L., and Copéret, Christophe. Composition-dependent surface chemistry of colloidal BaxSr1-xTiO 3 perovskite nanocrystals. United States: N. p., Web. doi:10.1039/c6cc07298d.
Margossian, Tigran, Culver, Sean P., Larmier, Kim, Zhu, Feng, Brutchey, Richard L., & Copéret, Christophe. Composition-dependent surface chemistry of colloidal BaxSr1-xTiO 3 perovskite nanocrystals. United States. doi:10.1039/c6cc07298d.
Margossian, Tigran, Culver, Sean P., Larmier, Kim, Zhu, Feng, Brutchey, Richard L., and Copéret, Christophe. 2016. "Composition-dependent surface chemistry of colloidal BaxSr1-xTiO 3 perovskite nanocrystals". United States. doi:10.1039/c6cc07298d. https://www.osti.gov/servlets/purl/1406132.
@article{osti_1406132,
title = {Composition-dependent surface chemistry of colloidal BaxSr1-xTiO 3 perovskite nanocrystals},
author = {Margossian, Tigran and Culver, Sean P. and Larmier, Kim and Zhu, Feng and Brutchey, Richard L. and Copéret, Christophe},
abstractNote = {BaxSr1-xTiO3 perovskite nanocrystals, prepared by the vapor diffusion sol-gel method and characterized by state of the art surface techniques, display significantly different O-H stretching frequencies and adsorption properties towards CO2 as a function of the alkaline earth composition (Ba vs. Sr). Lastly, the difference of properties can be associated with the more basic nature of BaO-rich than SrO-rich surfaces.},
doi = {10.1039/c6cc07298d},
journal = {ChemComm},
number = 95,
volume = 52,
place = {United States},
year = {2016},
month = {11}
}

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