Decomposition Reactions of Anode Solid Electrolyte Interphase (SEI) Components with LiPF 6

Parimalam, Bharathy S.; MacIntosh, Alex D.; Kadam, Rahul; Lucht, Brett L.

doi:10.1021/acs.jpcc.7b08433

Title: Decomposition Reactions of Anode Solid Electrolyte Interphase (SEI) Components with LiPF ₆

Journal Article · 02 October 2017 · Journal of Physical Chemistry. C

DOI: https://doi.org/10.1021/acs.jpcc.7b08433 · OSTI ID:1405196

Parimalam, Bharathy S. ^[1]; MacIntosh, Alex D. ^[1]; Kadam, Rahul ^[1];

^[1]

Department of Chemistry, University of Rhode Island, Kingston, Rhode Island 02881, United States

Not Available

View Journal Article

Cite

Export

Save

Research Organization:: Univ. of Rhode Island, Kingston, RI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0007074

OSTI ID:: 1405196

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 41 Vol. 121; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (29)

Lithium Ion Batteries: Fundamentals and Performance Wakihara, M.; Yamamoto, O. https://doi.org/10.1002/9783527612000	book	June 1998
Capacity fade of Sony 18650 cells cycled at elevated temperatures Ramadass, P.; Haran, Bala; White, Ralph Journal of Power Sources, Vol. 112, Issue 2 https://doi.org/10.1016/S0378-7753(02)00473-1	journal	November 2002
Simulation of capacity fade in lithium-ion batteries Spotnitz, R. Journal of Power Sources, Vol. 113, Issue 1 https://doi.org/10.1016/S0378-7753(02)00490-1	journal	January 2003
X-ray photoelectron spectroscopy of negative electrodes from high-power lithium-ion cells showing various levels of power fade Herstedt, M.; Abraham, D. P.; Kerr, J. B. Electrochimica Acta, Vol. 49, Issue 28 https://doi.org/10.1016/j.electacta.2004.06.021	journal	November 2004
Effects of lithium salts on thermal stabilities of lithium alkyl carbonates in SEI layer Ryou, Myung-Hyun; Lee, Je-Nam; Lee, Dong Jin Electrochimica Acta, Vol. 83 https://doi.org/10.1016/j.electacta.2012.08.012	journal	November 2012
Thermal behaviour of the lithiated-graphite/electrolyte interface through GC/MS analysis Gachot, Grégory; Grugeon, Sylvie; Eshetu, Gebrekidan Gebresilassie Electrochimica Acta, Vol. 83 https://doi.org/10.1016/j.electacta.2012.08.016	journal	November 2012
Ageing mechanisms in lithium-ion batteries Vetter, J.; Novák, P.; Wagner, M. R. Journal of Power Sources, Vol. 147, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.01.006	journal	September 2005
Deciphering the multi-step degradation mechanisms of carbonate-based electrolyte in Li batteries Gachot, Gregory; Grugeon, Sylvie; Armand, Michel Journal of Power Sources, Vol. 178, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.11.110	journal	March 2008
Thermal runaway caused fire and explosion of lithium ion battery Wang, Qingsong; Ping, Ping; Zhao, Xuejuan Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.038	journal	June 2012
Computational Exploration of the Li-Electrode\|Electrolyte Interface in the Presence of a Nanometer Thick Solid-Electrolyte Interphase Layer Li, Yunsong; Leung, Kevin; Qi, Yue Accounts of Chemical Research, Vol. 49, Issue 10 https://doi.org/10.1021/acs.accounts.6b00363	journal	September 2016
Stability of Solid Electrolyte Interphase Components on Lithium Metal and Reactive Anode Material Surfaces Leung, Kevin; Soto, Fernando; Hankins, Kie The Journal of Physical Chemistry C, Vol. 120, Issue 12 https://doi.org/10.1021/acs.jpcc.5b11719	journal	March 2016
Li ⁺ Transport and Mechanical Properties of Model Solid Electrolyte Interphases (SEI): Insight from Atomistic Molecular Dynamics Simulations Bedrov, Dmitry; Borodin, Oleg; Hooper, Justin B. The Journal of Physical Chemistry C, Vol. 121, Issue 30 https://doi.org/10.1021/acs.jpcc.7b04247	journal	July 2017
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Direct Calculation of Li-Ion Transport in the Solid Electrolyte Interphase Shi, Siqi; Lu, Peng; Liu, Zhongyi Journal of the American Chemical Society, Vol. 134, Issue 37 https://doi.org/10.1021/ja305366r	journal	September 2012
Syntheses and Characterization of Lithium Alkyl Mono- and Dicarbonates as Components of Surface Films in Li-Ion Batteries Xu, Kang; Zhuang, Guorong V.; Allen, Jan L. The Journal of Physical Chemistry B, Vol. 110, Issue 15 https://doi.org/10.1021/jp0601522	journal	March 2006
Li Ion Diffusion Mechanisms in Bulk Monoclinic Li ₂ CO ₃ Crystals from Density Functional Studies Iddir, H.; Curtiss, L. A. The Journal of Physical Chemistry C, Vol. 114, Issue 48 https://doi.org/10.1021/jp1086569	journal	October 2010
Electronic Structure Modeling of Electrochemical Reactions at Electrode/Electrolyte Interfaces in Lithium Ion Batteries Leung, Kevin The Journal of Physical Chemistry C, Vol. 117, Issue 4 https://doi.org/10.1021/jp308929a	journal	December 2012
Atomistic Modeling of the Electrode–Electrolyte Interface in Li-Ion Energy Storage Systems: Electrolyte Structuring Jorn, Ryan; Kumar, Revati; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 117, Issue 8 https://doi.org/10.1021/jp3102282	journal	February 2013
Defect Thermodynamics and Diffusion Mechanisms in Li ₂ CO ₃ and Implications for the Solid Electrolyte Interphase in Li-Ion Batteries Shi, Siqi; Qi, Yue; Li, Hong The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp310591u	journal	March 2013
Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy Nie, Mengyun; Chalasani, Dinesh; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 117, Issue 3, p. 1257-1267 https://doi.org/10.1021/jp3118055	journal	January 2013
Molecular Dynamics Simulations and Experimental Study of Lithium Ion Transport in Dilithium Ethylene Dicarbonate Borodin, Oleg; Zhuang, Guorong V.; Ross, Philip N. The Journal of Physical Chemistry C, Vol. 117, Issue 15 https://doi.org/10.1021/jp4000494	journal	April 2013
A Comparative Study of Synthetic Graphite and Li Electrodes in Electrolyte Solutions Based on Ethylene Carbonate-Dimethyl Carbonate Mixtures Aurbach, D. Journal of The Electrochemical Society, Vol. 143, Issue 12 https://doi.org/10.1149/1.1837300	journal	January 1996
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Arora, Pankaj; White, Ralph E.; Doyle, Marc Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667 https://doi.org/10.1149/1.1838857	journal	January 1998
The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries Aurbach, Doron Journal of The Electrochemical Society, Vol. 141, Issue 3 https://doi.org/10.1149/1.2054777	journal	January 1994
Electrochemical Intercalation of Lithium into Graphite Shu, Z. X. Journal of The Electrochemical Society, Vol. 140, Issue 4 https://doi.org/10.1149/1.2056228	journal	January 1993
Thermal Decomposition of LiPF[sub 6]-Based Electrolytes for Lithium-Ion Batteries Campion, Christopher L.; Li, Wentao; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 152, Issue 12 https://doi.org/10.1149/1.2083267	journal	January 2005
Identification of the Source of Evolved Gas in Li-Ion Batteries Using [sup 13]C-labeled Solvents Onuki, Masamichi; Kinoshita, Shinichi; Sakata, Yuuichi Journal of The Electrochemical Society, Vol. 155, Issue 11 https://doi.org/10.1149/1.2969947	journal	January 2008
Reduction Reactions of Carbonate Solvents for Lithium Ion Batteries Seo, D. M.; Chalasani, D.; Parimalam, B. S. ECS Electrochemistry Letters, Vol. 3, Issue 9 https://doi.org/10.1149/2.0021409eel	journal	January 2014
Decomposition of LiPF ₆ in High Energy Lithium-Ion Batteries Studied with Online Electrochemical Mass Spectrometry Guéguen, Aurélie; Streich, Daniel; He, Minglong Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.0981606jes	journal	January 2016

Similar Records

Effect of electrolyte on the nanostructure of the solid electrolyte interphase (SEI) and performance of lithium metal anodes

Journal Article · 2018 · Energy & Environmental Science · OSTI ID:1512926

Jurng, Sunhyung; Brown, Zachary L.; Kim, Jiyeon; +1 more

Thermal Decomposition of the Solid Electrolyte Interphase (SEI) on Silicon Electrodes for Lithium Ion Batteries

Journal Article · 2017 · Chemistry of Materials · OSTI ID:1534459

Yoon, Taeho; Milien, Mickdy S.; Parimalam, Bharathy S.; +1 more

Characterizing Solid Electrolyte Interphase on Sn Anode in Lithium Ion Battery

Journal Article · 2015 · Journal of the Electrochemical Society · OSTI ID:1454690

Seo, Daniel M.; Nguyen, Cao Cuong; Young, Benjamin T.; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Decomposition Reactions of Anode Solid Electrolyte Interphase (SEI) Components with LiPF 6

Citation Formats

References (29)

Similar Records

Related Subjects

Title: Decomposition Reactions of Anode Solid Electrolyte Interphase (SEI) Components with LiPF ₆