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Title: An Aqueous Ca-Ion Battery

Abstract

Multivalent-ion batteries are emerging as low-cost, high energy density, and safe alternatives to Li-ion batteries but are challenged by slow cation diffusion in electrode materials due to the high polarization strength of Mg- and Al-ions. In contrast, Ca-ion has a low polarization strength similar to that of Li-ion, therefore a Ca-ion battery will share the advantages while avoiding the kinetics issues related to multivalent batteries. However, there is no battery known that utilizes the Ca-ion chemistry due to the limited success in Ca-ion storage materials. Here, a safe and low-cost aqueous Ca-ion battery based on a highly reversible polyimide anode and a high-potential open framework copper hexacyanoferrate cathode is demonstrated. The prototype cell shows a stable capacity and high efficiency at both high and low current rates, with an 88% capacity retention and an average 99% coloumbic efficiency after cycling at 10C for 1000 cycles. The Ca-ion storage mechanism for both electrodes as well as the origin of the fast kinetics have been investigated. Finally, additional comparison with a Mg-ion cell with identical electrodes reveals clear kinetics advantages for the Ca-ion system, which is explained by the smaller ionic radii and more facile desolvation of hydrated Ca-ions.

Authors:
ORCiD logo [1];  [1];  [2];  [1];  [1];  [3];  [1];  [2]; ORCiD logo [4]
  1. Department of Electrical and Computer Engineering and Materials Science and Engineering Program, University of Houston, Houston TX 77204 USA
  2. Department of Materials Science, Fudan University, Shanghai 200433 China
  3. Department of Chemical and Biomolecular Engineering, University of Houston, Houston TX 77204 USA
  4. Department of Electrical and Computer Engineering and Materials Science and Engineering Program, University of Houston, Houston TX 77204 USA, Texas Center for Superconductivity at the University of Houston, Houston TX 77204 USA
Publication Date:
Research Org.:
Univ. of Houston, Houston, TX (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1405039
Alternate Identifier(s):
OSTI ID: 1405040; OSTI ID: 1417014
Grant/Contract Number:  
AR0000380; AC02-06CH11357
Resource Type:
Published Article
Journal Name:
Advanced Science
Additional Journal Information:
Journal Name: Advanced Science Journal Volume: 4 Journal Issue: 12; Journal ID: ISSN 2198-3844
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Gheytani, Saman, Liang, Yanliang, Wu, Feilong, Jing, Yan, Dong, Hui, Rao, Karun K., Chi, Xiaowei, Fang, Fang, and Yao, Yan. An Aqueous Ca-Ion Battery. Germany: N. p., 2017. Web. doi:10.1002/advs.201700465.
Gheytani, Saman, Liang, Yanliang, Wu, Feilong, Jing, Yan, Dong, Hui, Rao, Karun K., Chi, Xiaowei, Fang, Fang, & Yao, Yan. An Aqueous Ca-Ion Battery. Germany. doi:10.1002/advs.201700465.
Gheytani, Saman, Liang, Yanliang, Wu, Feilong, Jing, Yan, Dong, Hui, Rao, Karun K., Chi, Xiaowei, Fang, Fang, and Yao, Yan. Thu . "An Aqueous Ca-Ion Battery". Germany. doi:10.1002/advs.201700465.
@article{osti_1405039,
title = {An Aqueous Ca-Ion Battery},
author = {Gheytani, Saman and Liang, Yanliang and Wu, Feilong and Jing, Yan and Dong, Hui and Rao, Karun K. and Chi, Xiaowei and Fang, Fang and Yao, Yan},
abstractNote = {Multivalent-ion batteries are emerging as low-cost, high energy density, and safe alternatives to Li-ion batteries but are challenged by slow cation diffusion in electrode materials due to the high polarization strength of Mg- and Al-ions. In contrast, Ca-ion has a low polarization strength similar to that of Li-ion, therefore a Ca-ion battery will share the advantages while avoiding the kinetics issues related to multivalent batteries. However, there is no battery known that utilizes the Ca-ion chemistry due to the limited success in Ca-ion storage materials. Here, a safe and low-cost aqueous Ca-ion battery based on a highly reversible polyimide anode and a high-potential open framework copper hexacyanoferrate cathode is demonstrated. The prototype cell shows a stable capacity and high efficiency at both high and low current rates, with an 88% capacity retention and an average 99% coloumbic efficiency after cycling at 10C for 1000 cycles. The Ca-ion storage mechanism for both electrodes as well as the origin of the fast kinetics have been investigated. Finally, additional comparison with a Mg-ion cell with identical electrodes reveals clear kinetics advantages for the Ca-ion system, which is explained by the smaller ionic radii and more facile desolvation of hydrated Ca-ions.},
doi = {10.1002/advs.201700465},
journal = {Advanced Science},
number = 12,
volume = 4,
place = {Germany},
year = {2017},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
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DOI: 10.1002/advs.201700465

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Cited by: 9 works
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