Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates

Cary, Samantha K.; Ferrier, Maryline G.; Baumbach, Ryan E.; Silver, Mark A.; Lezama Pacheco, Juan; Kozimor, Stosh A.; La Pierre, Henry S.; Stein, Benjamin W.; Arico, Alexandra A.; Gray, Danielle L.; Albrecht-Schmitt, Thomas E.

doi:10.1021/acs.inorgchem.6b00077

Title: Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates

Authors:

Cary, Samantha K. ^[1]; Ferrier, Maryline G. ^[2]; Baumbach, Ryan E. ^[3]; Silver, Mark A. ^[1]; Lezama Pacheco, Juan ^[4]; Kozimor, Stosh A. ^[2]; La Pierre, Henry S. ^[2]; Stein, Benjamin W. ^[2]; Arico, Alexandra A. ^[1]; Gray, Danielle L. ^[5]; Albrecht-Schmitt, Thomas E. ^[1]

Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, Florida 32306, United States
Chemistry Divisions, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States
National High Magnetic Field Laboratory, Tallahassee, Florida 32310, United States
School of Earth, Energy, and Environmental Science, Stanford University, Stanford, California 94305, United States
Department of Chemistry, George L. Clark X-ray Facility & 3M Materials Laboratory, University of Illinois, 505 South Mathews Avenue, Urbana, Illinois 61801, United States

Publication Date:: Tue Apr 12 00:00:00 EDT 2016

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1404757

Grant/Contract Number:: FG02-13ER16414; SC0010677

Resource Type:: Published Article

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Name: Inorganic Chemistry Journal Volume: 55 Journal Issue: 9; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Cary, Samantha K., Ferrier, Maryline G., Baumbach, Ryan E., Silver, Mark A., Lezama Pacheco, Juan, Kozimor, Stosh A., La Pierre, Henry S., Stein, Benjamin W., Arico, Alexandra A., Gray, Danielle L., and Albrecht-Schmitt, Thomas E. Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates.  United States: N. p., 2016. 
Web.  doi:10.1021/acs.inorgchem.6b00077.

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                    Cary, Samantha K., Ferrier, Maryline G., Baumbach, Ryan E., Silver, Mark A., Lezama Pacheco, Juan, Kozimor, Stosh A., La Pierre, Henry S., Stein, Benjamin W., Arico, Alexandra A., Gray, Danielle L., & Albrecht-Schmitt, Thomas E. Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates.  United States.  https://doi.org/10.1021/acs.inorgchem.6b00077

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                    Cary, Samantha K., Ferrier, Maryline G., Baumbach, Ryan E., Silver, Mark A., Lezama Pacheco, Juan, Kozimor, Stosh A., La Pierre, Henry S., Stein, Benjamin W., Arico, Alexandra A., Gray, Danielle L., and Albrecht-Schmitt, Thomas E. Tue .  
"Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates".  United States.  https://doi.org/10.1021/acs.inorgchem.6b00077.

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@article{osti_1404757,

  title        = {Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates},

  author       = {Cary, Samantha K. and Ferrier, Maryline G. and Baumbach, Ryan E. and Silver, Mark A. and Lezama Pacheco, Juan and Kozimor, Stosh A. and La Pierre, Henry S. and Stein, Benjamin W. and Arico, Alexandra A. and Gray, Danielle L. and Albrecht-Schmitt, Thomas E.},

  abstractNote = {},

  doi          = {10.1021/acs.inorgchem.6b00077},

  journal      = {Inorganic Chemistry},

  number       = 9,

  volume       = 55,

  place        = {United States},

  year         = {Tue Apr 12 00:00:00 EDT 2016},

  month        = {Tue Apr 12 00:00:00 EDT 2016}

}

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https://doi.org/10.1021/acs.inorgchem.6b00077

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Title: Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates

Citation Formats

The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis journal, February 2014

Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M 2 Te 4 O 11 ]X 2 (M = Pu, Ce, Zr; X = Cl, Br) journal, October 2012

Complexation of Am(III) and Nd(III) by 1,10-Phenanthroline-2,9-Dicarboxylic Acid journal, December 2012

Complexation of Np V Ions with 1,10-Phenanthroline-2,9-dicarboxylic Acid: Spectrophotometric and Microcalorimetric Studies: Complexation of Np V Ions journal, October 2014

Isolation of Intermediate-Valent Ce(III)/Ce(IV) Hydrolysis Products in the Preparation of Cerium Iodates: Electronic and Structural Aspects of Ce 2 (IO 3 ) 6 (OH x ) ( x ≈ 0 and 0.44) journal, April 2004

Sequestered Plutonium: [PuIV{5LIO(Me-3,2-HOPO)}2]?The First Structurally Characterized Plutonium Hydroxypyridonate Complex journal, April 2005

From Yellow to Black: Dramatic Changes between Cerium(IV) and Plutonium(IV) Molybdates journal, February 2013

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

Metal-Mediated One-Step In Situ Oxidation of 2,9-Dimethyl-1,10-phenanthroline and Formation of Transition-Metal and Lanthanoid Complexes journal, September 2008

Periodic Trends in Lanthanide and Actinide Phosphonates: Discontinuity between Plutonium and Americium journal, June 2012

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Rational Design of Sequestering Agents for Plutonium and Other Actinides journal, November 2003

Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes1 journal, September 2000

Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium Systems journal, May 2009

Acid–base crystalline complexes and the pKa rule journal, January 2012

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Comparison of the Cation Valence and Coordination in Ce 2 UO 6 and Ce 2 MoO 6 journal, January 1996

Structural Periodicity in Plutonium(IV) Sulfates journal, June 2011

Complexation behavior of trivalent actinides and lanthanides with 1,10-phenanthroline-2,9-dicarboxylic acid based ligands: insight from density functional theory journal, January 2012

Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates journal, November 2010

A Miniaturized Linear pH Sensor Based on a Highly Photoluminescent Self-Assembled Europium(III) Metal-Organic Framework journal, August 2009

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Analysis of the crystal‐field spectra of the actinide tetrafluorides. I. UF 4 , NpF 4 , and PuF 4 journal, November 1991

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Surprising Coordination Geometry Differences in CeIV- and PuIV-Maltol Complexes journal, May 2008

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Sequestered Plutonium: [PuIV{5LIO(Me-3,2-HOPO)}2]?The First Structurally Characterized Plutonium Hydroxypyridonate Complex
journal, April 2005

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journal, February 2013

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

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journal, September 2008

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journal, June 2012

Specific sequestering agents for the actinides. 11. Complexation of plutonium and americium by catecholate ligands
journal, February 1985

Critical Role of Water Content in the Formation and Reactivity of Uranium, Neptunium, and Plutonium Iodates under Hydrothermal Conditions: Implications for the Oxidative Dissolution of Spent Nuclear Fuel
journal, April 2007

Rational Design of Sequestering Agents for Plutonium and Other Actinides
journal, November 2003

Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes¹
journal, September 2000

Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium Systems
journal, May 2009

Acid–base crystalline complexes and the pKa rule
journal, January 2012

Bond Valence Sums in Coordination Chemistry. The Calculation of the Oxidation State of Cerium in Complexes Containing Cerium Bonded Only to Oxygen
journal, January 2003

Specific Chiral Sensing of Amino Acids Using Induced Circularly Polarized Luminescence of Bis(diimine)dicarboxylic Acid Europium(III) Complexes
journal, May 2014

Comparison of the Cation Valence and Coordination in Ce ₂ UO ₆ and Ce ₂ MoO ₆
journal, January 1996

Structural Periodicity in Plutonium(IV) Sulfates
journal, June 2011

Complexation behavior of trivalent actinides and lanthanides with 1,10-phenanthroline-2,9-dicarboxylic acid based ligands: insight from density functional theory
journal, January 2012

Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates
journal, November 2010

A Miniaturized Linear pH Sensor Based on a Highly Photoluminescent Self-Assembled Europium(III) Metal-Organic Framework
journal, August 2009

Low-Valent Molecular Plutonium Halide Complexes
journal, September 2008

Single-crystal structure validation with the program PLATON
journal, January 2003

Supramolecular Interactions in PuO ₂ Cl ₄ ^2– and PuCl ₆ ^2– Complexes with Protonated Pyridines: Synthesis, Crystal Structures, and Raman Spectroscopy
journal, December 2013

Analysis of the crystal‐field spectra of the actinide tetrafluorides. I. UF ₄ , NpF ₄ , and PuF ₄
journal, November 1991

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journal, January 2008

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journal, May 2008

Affinity of the Highly Preorganized Ligand PDA (1,10-Phenanthroline-2,9-dicarboxylic acid) for Large Metal Ions of Higher Charge. A Crystallographic and Thermodynamic Study of PDA Complexes of Thorium(IV) and the Uranyl(VI) ion
journal, March 2008

Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl ₆ ^{x –} ( x = 3, 2)
journal, February 2015