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Title: Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U)

In addition to improved syntheses, the solid-state structures, voltammetric data and UV-visible–NIR spectra of (C 5Me 5) 2An(NMe 2) 2(An = Th, U) complexes are presented for the first time.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ;  [1] ;  [1] ; ORCiD logo [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Vermont, Burlington, VT (United States)
Publication Date:
Report Number(s):
LA-UR-17-23836
Journal ID: ISSN 1477-9226; ICHBD9
Grant/Contract Number:
AC52-06NA25396
Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 46; Journal Issue: 34; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Research Org:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1402633