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Title: Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U)

In addition to improved syntheses, the solid-state structures, voltammetric data and UV-visible–NIR spectra of (C 5Me 5) 2An(NMe 2) 2(An = Th, U) complexes are presented for the first time.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ;  [1] ;  [1] ; ORCiD logo [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Vermont, Burlington, VT (United States)
Publication Date:
Report Number(s):
LA-UR-17-23836
Journal ID: ISSN 1477-9226; ICHBD9
Grant/Contract Number:
AC52-06NA25396
Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 46; Journal Issue: 34; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Research Org:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1402633

Erickson, K. A., Kagan, B. D., Scott, B. L., Morris, D. E., and Kiplinger, J. L.. Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U). United States: N. p., Web. doi:10.1039/C7DT02373A.
Erickson, K. A., Kagan, B. D., Scott, B. L., Morris, D. E., & Kiplinger, J. L.. Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U). United States. doi:10.1039/C7DT02373A.
Erickson, K. A., Kagan, B. D., Scott, B. L., Morris, D. E., and Kiplinger, J. L.. 2017. "Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U)". United States. doi:10.1039/C7DT02373A. https://www.osti.gov/servlets/purl/1402633.
@article{osti_1402633,
title = {Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C 5 Me 5 ) 2 An(NMe 2 ) 2 (An = Th, U)},
author = {Erickson, K. A. and Kagan, B. D. and Scott, B. L. and Morris, D. E. and Kiplinger, J. L.},
abstractNote = {In addition to improved syntheses, the solid-state structures, voltammetric data and UV-visible–NIR spectra of (C5Me5)2An(NMe2)2(An = Th, U) complexes are presented for the first time.},
doi = {10.1039/C7DT02373A},
journal = {Dalton Transactions},
number = 34,
volume = 46,
place = {United States},
year = {2017},
month = {8}
}