Pressure‐induced polyamorphism in lanthanide‐solute metallic glasses
Abstract
The electronic structure inheritance of lanthanide‐solvent atoms in lanthanide‐based metallic glasses has been proposed. Is a polyamorphism possible in lanthanide‐solute metallic glasses? So far, polyamorphic phase transitions in metallic glass containing lanthanide have been observed only in lanthanide‐solvent metallic glasses. Here, a pressure‐induced transition between two distinct amorphous states, accompanied by a 7% volume collapse at ambient pressure, was observed in La 43.4 Pr 18.6 Al 14 Cu 24 metallic glass, with low lanthanide content, by using in situ X‐ray total scattering method. The transformation also indicated by changes in short range and medium range order. Thus, it is proposed that the lanthanide‐solute metallic glasses also inherit 4 f electronic transition from pure lanthanide element in polyamorphic transition. This discovery offers a supplement to research on lanthanide‐based metallic glasses, which further provides a new perspective of the polyamorphic transformation in metallic glasses containing lanthanide element.
- Authors:
-
- Harbin Institute of Technology Harbin 150080 P.R. China, Center for High Pressure Science Technology Advanced Research Changchun 130015 P.R. China
- Harbin Institute of Technology Harbin 150080 P.R. China
- School of Mechanical and Mining Engineering The University of Queensland Brisbane Queensland 4072 Australia
- X‐ray Science Division, Advanced Photon Source Argonne National Laboratory Argonne Illinois 60439 USA, Center for Advanced Energy Studies University of Idaho Idaho Falls Idaho 83406 USA
- X‐ray Science Division, Advanced Photon Source Argonne National Laboratory Argonne Illinois 60439 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401901
- Grant/Contract Number:
- DE‐AC02‐06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Physica Status Solidi. Rapid Research Letters
- Additional Journal Information:
- Journal Name: Physica Status Solidi. Rapid Research Letters Journal Volume: 11 Journal Issue: 6; Journal ID: ISSN 1862-6254
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Li, Liangliang, Wang, Luhong, Li, Renfeng, Qu, Dongdong, Zhao, Haiyan, Chapman, Karena W., Chupas, Peter J., and Liu, Haozhe. Pressure‐induced polyamorphism in lanthanide‐solute metallic glasses. Germany: N. p., 2017.
Web. doi:10.1002/pssr.201700078.
Li, Liangliang, Wang, Luhong, Li, Renfeng, Qu, Dongdong, Zhao, Haiyan, Chapman, Karena W., Chupas, Peter J., & Liu, Haozhe. Pressure‐induced polyamorphism in lanthanide‐solute metallic glasses. Germany. https://doi.org/10.1002/pssr.201700078
Li, Liangliang, Wang, Luhong, Li, Renfeng, Qu, Dongdong, Zhao, Haiyan, Chapman, Karena W., Chupas, Peter J., and Liu, Haozhe. Thu .
"Pressure‐induced polyamorphism in lanthanide‐solute metallic glasses". Germany. https://doi.org/10.1002/pssr.201700078.
@article{osti_1401901,
title = {Pressure‐induced polyamorphism in lanthanide‐solute metallic glasses},
author = {Li, Liangliang and Wang, Luhong and Li, Renfeng and Qu, Dongdong and Zhao, Haiyan and Chapman, Karena W. and Chupas, Peter J. and Liu, Haozhe},
abstractNote = {The electronic structure inheritance of lanthanide‐solvent atoms in lanthanide‐based metallic glasses has been proposed. Is a polyamorphism possible in lanthanide‐solute metallic glasses? So far, polyamorphic phase transitions in metallic glass containing lanthanide have been observed only in lanthanide‐solvent metallic glasses. Here, a pressure‐induced transition between two distinct amorphous states, accompanied by a 7% volume collapse at ambient pressure, was observed in La 43.4 Pr 18.6 Al 14 Cu 24 metallic glass, with low lanthanide content, by using in situ X‐ray total scattering method. The transformation also indicated by changes in short range and medium range order. Thus, it is proposed that the lanthanide‐solute metallic glasses also inherit 4 f electronic transition from pure lanthanide element in polyamorphic transition. This discovery offers a supplement to research on lanthanide‐based metallic glasses, which further provides a new perspective of the polyamorphic transformation in metallic glasses containing lanthanide element.},
doi = {10.1002/pssr.201700078},
journal = {Physica Status Solidi. Rapid Research Letters},
number = 6,
volume = 11,
place = {Germany},
year = {Thu Apr 27 00:00:00 EDT 2017},
month = {Thu Apr 27 00:00:00 EDT 2017}
}
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