Efficacy of passive sampler collection for atmospheric NO 2 isotopes under simulated environmental conditions

Coughlin, Justin G.; Yu, Zhongjie; Elliott, Emily M.

doi:10.1002/rcm.7885

Title: Efficacy of passive sampler collection for atmospheric NO ₂ isotopes under simulated environmental conditions

Abstract

Rationale Nitrogen oxides or NO _x (NO _x = NO + NO ₂ ) play an important role in air quality, atmospheric chemistry, and climate. The isotopic compositions of anthropogenic and natural NO ₂ sources are wide‐ranging, and they can be used to constrain sources of ambient NO ₂ and associated atmospheric deposition of nitrogen compounds. While passive sample collection of NO ₂ isotopes has been used in field studies to determine NO _x source influences on atmospheric deposition, this approach has not been evaluated for accuracy or precision under different environmental conditions. Methods The efficacy of NO ₂ passive sampler collection for NO ₂ isotopes was evaluated under varied temperature and relative humidity (RH) conditions in a dynamic flux chamber. The precision and accuracy of the filter NO ₂ collection as nitrite (NO ₂ ^– ) for isotopic analysis were determined using a reference NO ₂ gas tank and through inter‐calibration with a modified EPA Method 7. The bacterial denitrifer method was used to convert 20 μM of collected NO ₂ ^– or nitrate (NO ₃ ^– ) into N ₂ O and was carried out on an Isoprime continuous flow isotope ratio mass spectrometer. Results δ ¹⁵ N‐NOmore »« less

Authors:

^[1]; Yu, Zhongjie ^[1]; Elliott, Emily M. ^[1]

Department of Geology and Environmental Science University of Pittsburgh Pittsburgh PA 15260 USA

Publication Date:: Sun Jun 18 00:00:00 EDT 2017

Sponsoring Org.:: USDOE

OSTI Identifier:: 1401899

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Rapid Communications in Mass Spectrometry

Additional Journal Information:: Journal Name: Rapid Communications in Mass Spectrometry Journal Volume: 31 Journal Issue: 14; Journal ID: ISSN 0951-4198

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Coughlin, Justin G., Yu, Zhongjie, and Elliott, Emily M. Efficacy of passive sampler collection for atmospheric NO 2 isotopes under simulated environmental conditions.  United Kingdom: N. p., 2017. 
Web.  doi:10.1002/rcm.7885.

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                    Coughlin, Justin G., Yu, Zhongjie, & Elliott, Emily M. Efficacy of passive sampler collection for atmospheric NO 2 isotopes under simulated environmental conditions.  United Kingdom.  https://doi.org/10.1002/rcm.7885

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                    Coughlin, Justin G., Yu, Zhongjie, and Elliott, Emily M. Sun .  
"Efficacy of passive sampler collection for atmospheric NO 2 isotopes under simulated environmental conditions".  United Kingdom.  https://doi.org/10.1002/rcm.7885.

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@article{osti_1401899,

  title        = {Efficacy of passive sampler collection for atmospheric NO 2 isotopes under simulated environmental conditions},

  author       = {Coughlin, Justin G. and Yu, Zhongjie and Elliott, Emily M.},

  abstractNote = {Rationale Nitrogen oxides or NO x (NO x = NO + NO 2 ) play an important role in air quality, atmospheric chemistry, and climate. The isotopic compositions of anthropogenic and natural NO 2 sources are wide‐ranging, and they can be used to constrain sources of ambient NO 2 and associated atmospheric deposition of nitrogen compounds. While passive sample collection of NO 2 isotopes has been used in field studies to determine NO x source influences on atmospheric deposition, this approach has not been evaluated for accuracy or precision under different environmental conditions. Methods The efficacy of NO 2 passive sampler collection for NO 2 isotopes was evaluated under varied temperature and relative humidity (RH) conditions in a dynamic flux chamber. The precision and accuracy of the filter NO 2 collection as nitrite (NO 2 – ) for isotopic analysis were determined using a reference NO 2 gas tank and through inter‐calibration with a modified EPA Method 7. The bacterial denitrifer method was used to convert 20 μM of collected NO 2 – or nitrate (NO 3 – ) into N 2 O and was carried out on an Isoprime continuous flow isotope ratio mass spectrometer. Results δ 15 N‐NO 2 values determined from passive NO 2 collection, in conditions of 11–34 °C, 1–78% RH, have an overall accuracy and precision of ±2.1 ‰, and individual run precision of ±0.6 ‰. δ 18 O‐NO 2 values obtained from passive NO 2 sampler collection, under the same conditions, have an overall precision of ± 1.3 ‰. Conclusions Suitable conditions for passive sampler collection of NO 2 isotopes are in environments ranging from 11 to 34 °C and 1 to 78% RH. The passive NO 2 isotope measurement technique provides an accurate method to determine variations in atmospheric δ 15 N‐NO 2 values and a precise method for determining atmospheric δ 18 O‐NO 2 values. The ability to measure NO 2 isotopes over spatial gradients at the same temporal resolution provides a unique perspective on the extent and seasonality of fluctuations in atmospheric NO 2 isotopic compositions. Copyright © 2017 John Wiley & Sons, Ltd.},

  doi          = {10.1002/rcm.7885},

  journal      = {Rapid Communications in Mass Spectrometry},

  number       = 14,

  volume       = 31,

  place        = {United Kingdom},

  year         = {Sun Jun 18 00:00:00 EDT 2017},

  month        = {Sun Jun 18 00:00:00 EDT 2017}

}

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https://doi.org/10.1002/rcm.7885

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Works referenced in this record:

Theoretical calculation of nitrogen isotope equilibrium exchange fractionation factors for various NO y molecules
journal, September 2015

Walters, Wendell W.; Michalski, Greg
Geochimica et Cosmochimica Acta, Vol. 164
DOI: 10.1016/j.gca.2015.05.029

Reactive nitrogen in atmospheric emission inventories
journal, January 2009

Reis, S.; Pinder, R. W.; Zhang, M.
Atmospheric Chemistry and Physics, Vol. 9, Issue 19
DOI: 10.5194/acp-9-7657-2009

Aridity and plant uptake interact to make dryland soils hotspots for nitric oxide (NO) emissions
journal, April 2016

Homyak, Peter M.; Blankinship, Joseph C.; Marchus, Kenneth
Proceedings of the National Academy of Sciences, Vol. 113, Issue 19
DOI: 10.1073/pnas.1520496113

The Use of Passive Diffusion Tubes for Measuring Concentrations of Nitrogen Dioxide in Air
journal, October 2009

Cape, J. N.
Critical Reviews in Analytical Chemistry, Vol. 39, Issue 4
DOI: 10.1080/10408340903001375

Oxygen Isotopes in Nitrite: Analysis, Calibration, and Equilibration
journal, March 2007

Casciotti, Karen L.; Böhlke, John Karl; McIlvin, Matthew R.
Analytical Chemistry, Vol. 79, Issue 6
DOI: 10.1021/ac061598h

Nitrogen isotope exchange between NO and NO ₂ and its implications for δ ¹⁵ N variations in tropospheric NO _x and atmospheric nitrate
journal, January 2016

Walters, Wendell W.; Simonini, Damian S.; Michalski, Greg
Geophysical Research Letters, Vol. 43, Issue 1
DOI: 10.1002/2015GL066438

Influence of NOx emissions from ships on tropospheric photochemistry and climate
journal, November 1999

Lawrence, Mark G.; Crutzen, Paul J.
Nature, Vol. 402, Issue 6758
DOI: 10.1038/46013

Highway contributions to reactive nitrogen deposition: tracing the fate of vehicular NOx using stable isotopes and plant biomonitors
journal, May 2013

Redling, Katherine; Elliott, Emily; Bain, Daniel
Biogeochemistry, Vol. 116, Issue 1-3
DOI: 10.1007/s10533-013-9857-x

A new all-season passive sampling system for monitoring NO2 in air
journal, January 1999

Tang, Hongmao; Lau, Thomas; Brassard, Bernie
Field Analytical Chemistry & Technology, Vol. 3, Issue 6
DOI: 10.1002/(SICI)1520-6521(1999)3:6<338::AID-FACT3>3.0.CO;2-U

Traffic exposure increases natural 15N and heavy metal concentrations in mosses: RESEARCH Mosses and N pollution
journal, August 2000

Pearson, J.; Wells, D. M.; Seller, K. J.
New Phytologist, Vol. 147, Issue 2
DOI: 10.1046/j.1469-8137.2000.00702.x

The effects of wind speed and turbulence on the performance of diffusion tube samplers
journal, September 1995

Gair, A. J.; Penkett, S. A.
Atmospheric Environment, Vol. 29, Issue 18
DOI: 10.1016/1352-2310(95)91998-8

On the interaction of isotopic exchange processes with photochemical reactions in atmospheric oxides of nitrogen
journal, January 1993

Freyer, H. D.; Kley, D.; Volz-Thomas, A.
Journal of Geophysical Research, Vol. 98, Issue D8
DOI: 10.1029/93JD00874

Theoretical calculation of oxygen equilibrium isotope fractionation factors involving various NO molecules, OH, and H2O and its implications for isotope variations in atmospheric nitrate
journal, October 2016

Walters, Wendell W.; Michalski, Greg
Geochimica et Cosmochimica Acta, Vol. 191
DOI: 10.1016/j.gca.2016.06.039

Health effects of short-term inhalation of nitrogen dioxide and ozone mixtures
journal, October 1977

Ehrlich, Richard; Findlay, J. C.; Fenters, J. D.
Environmental Research, Vol. 14, Issue 2
DOI: 10.1016/0013-9351(77)90034-2

Nitrogen Cycles: Past, Present, and Future
journal, September 2004

Galloway, J. N.; Dentener, F. J.; Capone, D. G.
Biogeochemistry, Vol. 70, Issue 2
DOI: 10.1007/s10533-004-0370-0

Estimating the uptake of traffic-derived NO 2 from 15 N abundance in Norway spruce needles
journal, February 1999

Ammann, M.; Siegwolf, R.; Pichlmayer, F.
Oecologia, Vol. 118, Issue 2
DOI: 10.1007/s004420050710

Measurement of nitrogen dioxide diffusive sampling rates for Palmes diffusion tubes using a controlled atmosphere test facility (CATFAC)
journal, September 2014

Martin, Nicholas A.; Helmore, Jonathan J.; White, Samual
Atmospheric Environment, Vol. 94
DOI: 10.1016/j.atmosenv.2014.05.064

Seasonal trends of NH⁺₄and NO⁻₃nitrogen isotope composition in rain collected at Jülich, Germany
journal, February 1978

Freyer, H. D.
Tellus, Vol. 30, Issue 1
DOI: 10.1111/j.2153-3490.1978.tb00820.x

Anthropogenic Impacts on Nitrogen Isotopes of Ice-Core Nitrate
journal, June 2009

Hastings, M. G.; Jarvis, J. C.; Steig, E. J.
Science, Vol. 324, Issue 5932
DOI: 10.1126/science.1170510

Characterizing the isotopic composition of atmospheric ammonia emission sources using passive samplers and a combined oxidation-bacterial denitrifier approach: Improved method for isotope characterization of ammonia in air
journal, September 2013

David Felix, J.; Elliott, Emily M.; Gish, Timothy J.
Rapid Communications in Mass Spectrometry, Vol. 27, Issue 20
DOI: 10.1002/rcm.6679

Nitrogen isotopic signature of soil-released nitric oxide (NO) after fertilizer application
journal, June 2008

Li, Dejun; Wang, Xinming
Atmospheric Environment, Vol. 42, Issue 19
DOI: 10.1016/j.atmosenv.2008.01.042

The isotopic composition of ammonia, nitrogen dioxide and nitrate in the atmosphere
journal, January 1977

Moore, Howard
Atmospheric Environment (1967), Vol. 11, Issue 12
DOI: 10.1016/0004-6981(77)90102-0

Human health effects of air pollution
journal, January 2008

Kampa, Marilena; Castanas, Elias
Environmental Pollution, Vol. 151, Issue 2
DOI: 10.1016/j.envpol.2007.06.012

A laboratory evaluation of a nitrogen dioxide personal sampling device
journal, January 1990

Moschandreas, D. J.; Relwani, S. M.; Taylor, K. C.
Atmospheric Environment. Part A. General Topics, Vol. 24, Issue 11
DOI: 10.1016/0960-1686(90)90167-L

Influence of meteorological factors on the NO2 measurements by passive diffusion tube
journal, February 2004

Plaisance, H.; Piechocki-Minguy, A.; Garcia-Fouque, S.
Atmospheric Environment, Vol. 38, Issue 4
DOI: 10.1016/j.atmosenv.2003.09.073

Recent ecological and biogeochemical changes in alpine lakes of Rocky Mountain National Park (Colorado, USA): a response to anthropogenic nitrogen deposition
journal, October 2003

Wolfe, Alexander P.; Van Gorp, Alison C.; Baron, Jill S.
Geobiology, Vol. 1, Issue 2
DOI: 10.1046/j.1472-4669.2003.00012.x

Development and Types of Passive Samplers for Monitoring Atmospheric NO2 and NH3 Concentrations
journal, January 2001

Tang, Y. S.; Cape, J. N.; Sutton, M. A.
The Scientific World JOURNAL, Vol. 1
DOI: 10.1100/tsw.2001.82

Measurements of nitrogen dioxide in Greenland using Palmes diffusion tubes
journal, January 2001

Hansen, T. Stroyer; Kruse, Mikkel; Nissen, Hanne
Journal of Environmental Monitoring, Vol. 3, Issue 1
DOI: 10.1039/b008325i

Technical considerations for the use of passive samplers to quantify the isotopic composition of NOx and NO2 using the denitrifier method
journal, October 2016

Dahal, Bigyan; Hastings, Meredith G.
Atmospheric Environment, Vol. 143
DOI: 10.1016/j.atmosenv.2016.08.006

A Bacterial Method for the Nitrogen Isotopic Analysis of Nitrate in Seawater and Freshwater
journal, September 2001

Sigman, D. M.; Casciotti, K. L.; Andreani, M.
Analytical Chemistry, Vol. 73, Issue 17
DOI: 10.1021/ac010088e

Nitrogen Isotopic Composition of Coal-Fired Power Plant NO _x : Influence of Emission Controls and Implications for Global Emission Inventories
journal, February 2012

Felix, J. David; Elliott, Emily M.; Shaw, Stephanie L.
Environmental Science & Technology, Vol. 46, Issue 6
DOI: 10.1021/es203355v

Dual nitrate isotopes in dry deposition: Utility for partitioning NO _x source contributions to landscape nitrogen deposition
journal, January 2009

Elliott, E. M.; Kendall, C.; Boyer, E. W.
Journal of Geophysical Research, Vol. 114, Issue G4
DOI: 10.1029/2008JG000889

Nitrogen Stable Isotope Composition (δ ¹⁵ N) of Vehicle-Emitted NO _x
journal, February 2015

Walters, Wendell W.; Goodwin, Stanford R.; Michalski, Greg
Environmental Science & Technology, Vol. 49, Issue 4
DOI: 10.1021/es505580v

The changing photochemistry of the troposphere
journal, August 1991

Crutzen, Paul J.; Zimmermann, Peter H.
Tellus A, Vol. 43, Issue 4
DOI: 10.1034/j.1600-0870.1991.00012.x

¹⁵N/¹⁴N ratios of NO_x from vehicle engines and coal-fired power stations
journal, January 1990

Heaton, T. H. E.
Tellus B: Chemical and Physical Meteorology, Vol. 42, Issue 3
DOI: 10.3402/tellusb.v42i3.15223

Collection of NO and NO ₂ for Isotopic Analysis of NO _x Emissions
journal, November 2014

Fibiger, Dorothy L.; Hastings, Meredith G.; Lew, Audrey F.
Analytical Chemistry, Vol. 86, Issue 24
DOI: 10.1021/ac502968e

The Role of NO and NO2 in the Chemistry of the Troposphere and Stratosphere
journal, May 1979

Crutzen, P. J.
Annual Review of Earth and Planetary Sciences, Vol. 7, Issue 1
DOI: 10.1146/annurev.ea.07.050179.002303

Nitrogen Isotopes as Indicators of NO _x Source Contributions to Atmospheric Nitrate Deposition Across the Midwestern and Northeastern United States
journal, November 2007

Elliott, E. M.; Kendall, C.; Wankel, S. D.
Environmental Science & Technology, Vol. 41, Issue 22
DOI: 10.1021/es070898t

First detection of nitrogen from NOx in tree rings: a 15N/14N study near a motorway
journal, June 2004

Saurer, M.; Cherubini, P.; Ammann, M.
Atmospheric Environment, Vol. 38, Issue 18
DOI: 10.1016/j.atmosenv.2004.02.037

Isotopic evidence for source changes of nitrate in rain at Bermuda: NITRATE N AND O ISOTOPES IN BERMUDA RAIN
journal, December 2003

Hastings, Meredith Galanter; Sigman, Daniel M.; Lipschultz, Fred
Journal of Geophysical Research: Atmospheres, Vol. 108, Issue D24
DOI: 10.1029/2003JD003789

Simple approaches for measuring dry atmospheric nitrogen deposition to watersheds: MEASURING DRY ATMOSPHERIC NITROGEN DEPOSITION
journal, April 2008

Golden, Heather E.; Boyer, Elizabeth W.; Brown, Michael G.
Water Resources Research, Vol. 44, Issue 4
DOI: 10.1029/2008WR006952

Overestimation of urban nitrogen dioxide by passive diffusion tubes: a comparative exposure and model study
journal, February 1999

Heal, M. R.; O’Donoghue, M. A.; Cape, J. N.
Atmospheric Environment, Vol. 33, Issue 4
DOI: 10.1016/S1352-2310(98)00290-8

Isotopic composition of passively collected nitrogen dioxide emissions: Vehicle, soil and livestock source signatures
journal, August 2014

Felix, J. David; Elliott, Emily M.
Atmospheric Environment, Vol. 92
DOI: 10.1016/j.atmosenv.2014.04.005

Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and soil emissions
journal, January 2005

Jaeglé, Lyatt; Steinberger, Linda; Martin, Randall V.
Faraday Discussions, Vol. 130
DOI: 10.1039/b502128f

The isotopic composition of the ammonia and the nitrate ion in rain
journal, January 1957

Hoering, Thomas
Geochimica et Cosmochimica Acta, Vol. 12, Issue 1-2
DOI: 10.1016/0016-7037(57)90021-2

Nitrogen deposition to the United States: distribution, sources, and processes
journal, January 2012

Zhang, L.; Jacob, D. J.; Knipping, E. M.
Atmospheric Chemistry and Physics, Vol. 12, Issue 10
DOI: 10.5194/acp-12-4539-2012

Nitrogen Isotope Composition of Thermally Produced NO _x from Various Fossil-Fuel Combustion Sources
journal, September 2015

Walters, Wendell W.; Tharp, Bruce D.; Fang, Huan
Environmental Science & Technology, Vol. 49, Issue 19
DOI: 10.1021/acs.est.5b02769

Seasonal variation of 15N/14N ratios in atmospheric nitrate species
journal, February 1991

Freyer, H. D.
Tellus B, Vol. 43, Issue 1
DOI: 10.1034/j.1600-0889.1991.00003.x

Passive ammonia monitoring in the United States: Comparing three different sampling devices
journal, January 2011

Puchalski, Melissa A.; Sather, Mark E.; Walker, John T.
Journal of Environmental Monitoring, Vol. 13, Issue 11
DOI: 10.1039/c1em10553a

Measurement of the Oxygen Isotopic Composition of Nitrate in Seawater and Freshwater Using the Denitrifier Method
journal, October 2002

Casciotti, K. L.; Sigman, D. M.; Hastings, M. Galanter
Analytical Chemistry, Vol. 74, Issue 19
DOI: 10.1021/ac020113w

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Title: Efficacy of passive sampler collection for atmospheric NO 2 isotopes under simulated environmental conditions

Abstract

Citation Formats

Theoretical calculation of nitrogen isotope equilibrium exchange fractionation factors for various NO y molecules journal, September 2015

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Aridity and plant uptake interact to make dryland soils hotspots for nitric oxide (NO) emissions journal, April 2016

The Use of Passive Diffusion Tubes for Measuring Concentrations of Nitrogen Dioxide in Air journal, October 2009

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Health effects of short-term inhalation of nitrogen dioxide and ozone mixtures journal, October 1977

Nitrogen Cycles: Past, Present, and Future journal, September 2004

Estimating the uptake of traffic-derived NO 2 from 15 N abundance in Norway spruce needles journal, February 1999

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A laboratory evaluation of a nitrogen dioxide personal sampling device journal, January 1990

Influence of meteorological factors on the NO2 measurements by passive diffusion tube journal, February 2004

Recent ecological and biogeochemical changes in alpine lakes of Rocky Mountain National Park (Colorado, USA): a response to anthropogenic nitrogen deposition journal, October 2003

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Technical considerations for the use of passive samplers to quantify the isotopic composition of NOx and NO2 using the denitrifier method journal, October 2016

A Bacterial Method for the Nitrogen Isotopic Analysis of Nitrate in Seawater and Freshwater journal, September 2001

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Dual nitrate isotopes in dry deposition: Utility for partitioning NO x source contributions to landscape nitrogen deposition journal, January 2009

Nitrogen Stable Isotope Composition (δ 15 N) of Vehicle-Emitted NO x journal, February 2015

The changing photochemistry of the troposphere journal, August 1991

15N/14N ratios of NOx from vehicle engines and coal-fired power stations journal, January 1990

Collection of NO and NO 2 for Isotopic Analysis of NO x Emissions journal, November 2014

The Role of NO and NO2 in the Chemistry of the Troposphere and Stratosphere journal, May 1979

Nitrogen Isotopes as Indicators of NO x Source Contributions to Atmospheric Nitrate Deposition Across the Midwestern and Northeastern United States journal, November 2007

First detection of nitrogen from NOx in tree rings: a 15N/14N study near a motorway journal, June 2004

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Overestimation of urban nitrogen dioxide by passive diffusion tubes: a comparative exposure and model study journal, February 1999

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Nitrogen Isotope Composition of Thermally Produced NO x from Various Fossil-Fuel Combustion Sources journal, September 2015

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Title: Efficacy of passive sampler collection for atmospheric NO ₂ isotopes under simulated environmental conditions

Theoretical calculation of nitrogen isotope equilibrium exchange fractionation factors for various NO y molecules
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journal, May 2013

A new all-season passive sampling system for monitoring NO2 in air
journal, January 1999

Traffic exposure increases natural 15N and heavy metal concentrations in mosses: RESEARCH Mosses and N pollution
journal, August 2000

The effects of wind speed and turbulence on the performance of diffusion tube samplers
journal, September 1995

On the interaction of isotopic exchange processes with photochemical reactions in atmospheric oxides of nitrogen
journal, January 1993

Theoretical calculation of oxygen equilibrium isotope fractionation factors involving various NO molecules, OH, and H2O and its implications for isotope variations in atmospheric nitrate
journal, October 2016

Health effects of short-term inhalation of nitrogen dioxide and ozone mixtures
journal, October 1977

Nitrogen Cycles: Past, Present, and Future
journal, September 2004

Estimating the uptake of traffic-derived NO 2 from 15 N abundance in Norway spruce needles
journal, February 1999

Measurement of nitrogen dioxide diffusive sampling rates for Palmes diffusion tubes using a controlled atmosphere test facility (CATFAC)
journal, September 2014

Seasonal trends of NH⁺₄and NO⁻₃nitrogen isotope composition in rain collected at Jülich, Germany
journal, February 1978

Anthropogenic Impacts on Nitrogen Isotopes of Ice-Core Nitrate
journal, June 2009

Characterizing the isotopic composition of atmospheric ammonia emission sources using passive samplers and a combined oxidation-bacterial denitrifier approach: Improved method for isotope characterization of ammonia in air
journal, September 2013

Nitrogen isotopic signature of soil-released nitric oxide (NO) after fertilizer application
journal, June 2008

The isotopic composition of ammonia, nitrogen dioxide and nitrate in the atmosphere
journal, January 1977

Human health effects of air pollution
journal, January 2008

A laboratory evaluation of a nitrogen dioxide personal sampling device
journal, January 1990

Influence of meteorological factors on the NO2 measurements by passive diffusion tube
journal, February 2004

Recent ecological and biogeochemical changes in alpine lakes of Rocky Mountain National Park (Colorado, USA): a response to anthropogenic nitrogen deposition
journal, October 2003

Development and Types of Passive Samplers for Monitoring Atmospheric NO2 and NH3 Concentrations
journal, January 2001

Measurements of nitrogen dioxide in Greenland using Palmes diffusion tubes
journal, January 2001

Technical considerations for the use of passive samplers to quantify the isotopic composition of NOx and NO2 using the denitrifier method
journal, October 2016

A Bacterial Method for the Nitrogen Isotopic Analysis of Nitrate in Seawater and Freshwater
journal, September 2001

Nitrogen Isotopic Composition of Coal-Fired Power Plant NO _x : Influence of Emission Controls and Implications for Global Emission Inventories
journal, February 2012

Dual nitrate isotopes in dry deposition: Utility for partitioning NO _x source contributions to landscape nitrogen deposition
journal, January 2009

Nitrogen Stable Isotope Composition (δ ¹⁵ N) of Vehicle-Emitted NO _x
journal, February 2015

The changing photochemistry of the troposphere
journal, August 1991

¹⁵N/¹⁴N ratios of NO_x from vehicle engines and coal-fired power stations
journal, January 1990

Collection of NO and NO ₂ for Isotopic Analysis of NO _x Emissions
journal, November 2014

The Role of NO and NO2 in the Chemistry of the Troposphere and Stratosphere
journal, May 1979

Nitrogen Isotopes as Indicators of NO _x Source Contributions to Atmospheric Nitrate Deposition Across the Midwestern and Northeastern United States
journal, November 2007

First detection of nitrogen from NOx in tree rings: a 15N/14N study near a motorway
journal, June 2004

Isotopic evidence for source changes of nitrate in rain at Bermuda: NITRATE N AND O ISOTOPES IN BERMUDA RAIN
journal, December 2003

Simple approaches for measuring dry atmospheric nitrogen deposition to watersheds: MEASURING DRY ATMOSPHERIC NITROGEN DEPOSITION
journal, April 2008

Overestimation of urban nitrogen dioxide by passive diffusion tubes: a comparative exposure and model study
journal, February 1999

Isotopic composition of passively collected nitrogen dioxide emissions: Vehicle, soil and livestock source signatures
journal, August 2014

Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and soil emissions
journal, January 2005

The isotopic composition of the ammonia and the nitrate ion in rain
journal, January 1957

Nitrogen deposition to the United States: distribution, sources, and processes
journal, January 2012

Nitrogen Isotope Composition of Thermally Produced NO _x from Various Fossil-Fuel Combustion Sources
journal, September 2015

Seasonal variation of 15N/14N ratios in atmospheric nitrate species
journal, February 1991

Passive ammonia monitoring in the United States: Comparing three different sampling devices
journal, January 2011

Measurement of the Oxygen Isotopic Composition of Nitrate in Seawater and Freshwater Using the Denitrifier Method
journal, October 2002