Pseudocapacitive Charge Storage in Thick Composite MoS2 Nanocrystal-Based Electrodes
Abstract
A synthesis methodology is demonstrated to produce MoS2 nanoparticles with an expanded atomic lamellar structure that are ideal for Faradaic–based capacitive charge storage. While much of the work on MoS2 focuses on the high capacity conversion reaction, that process is prone to poor reversibility. The pseudocapacitive intercalation–based charge storage reaction of MoS2 is investigated, which is extremely fast and highly reversible. A major challenge in the field of pseudocapacitive–based energy storage is the development of thick electrodes from nanostructured materials that can sustain the fast inherent kinetics of the active nanocrystalline material. Here a composite electrode comprised of a poly(acrylic acid) binder, carbon fibers, and carbon black additives is utilized. Here, these electrodes deliver a specific capacity of 90 mAh g–1 in less than 20 s and can be cycled 3000 times while retaining over 80% of the original capacity. Quantitative kinetic analysis indicates that over 80% of the charge storage in these MoS2 nanocrystals is pseudocapacitive. Asymmetric full cell devices utilizing a MoS2 nanocrystal–based electrode and an activated carbon electrode achieve a maximum power density of 5.3 kW kg–1 (with 6 Wh kg–1 energy density) and a maximum energy density of 37 Wh kg–1 (with 74 W kg–1 powermore »
- Authors:
-
- UCLA, Los Angeles, CA (United States)
- Publication Date:
- Research Org.:
- Univ. of California, Los Angeles, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1533064
- Alternate Identifier(s):
- OSTI ID: 1401883
- Grant/Contract Number:
- SC0014213
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 2; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Chemistry; Energy & Fuels; Materials Science; Physics; MoS2; Nanocrystals; Li‐ion batteries; Intercalation‐pseudocapacitance; Pseudocapacitance
Citation Formats
Cook, John B., Kim, Hyung-Seok, Lin, Terri C., Lai, Chun-Han, Dunn, Bruce, and Tolbert, Sarah H. Pseudocapacitive Charge Storage in Thick Composite MoS2 Nanocrystal-Based Electrodes. United States: N. p., 2016.
Web. doi:10.1002/aenm.201601283.
Cook, John B., Kim, Hyung-Seok, Lin, Terri C., Lai, Chun-Han, Dunn, Bruce, & Tolbert, Sarah H. Pseudocapacitive Charge Storage in Thick Composite MoS2 Nanocrystal-Based Electrodes. United States. https://doi.org/10.1002/aenm.201601283
Cook, John B., Kim, Hyung-Seok, Lin, Terri C., Lai, Chun-Han, Dunn, Bruce, and Tolbert, Sarah H. Fri .
"Pseudocapacitive Charge Storage in Thick Composite MoS2 Nanocrystal-Based Electrodes". United States. https://doi.org/10.1002/aenm.201601283. https://www.osti.gov/servlets/purl/1533064.
@article{osti_1533064,
title = {Pseudocapacitive Charge Storage in Thick Composite MoS2 Nanocrystal-Based Electrodes},
author = {Cook, John B. and Kim, Hyung-Seok and Lin, Terri C. and Lai, Chun-Han and Dunn, Bruce and Tolbert, Sarah H.},
abstractNote = {A synthesis methodology is demonstrated to produce MoS2 nanoparticles with an expanded atomic lamellar structure that are ideal for Faradaic–based capacitive charge storage. While much of the work on MoS2 focuses on the high capacity conversion reaction, that process is prone to poor reversibility. The pseudocapacitive intercalation–based charge storage reaction of MoS2 is investigated, which is extremely fast and highly reversible. A major challenge in the field of pseudocapacitive–based energy storage is the development of thick electrodes from nanostructured materials that can sustain the fast inherent kinetics of the active nanocrystalline material. Here a composite electrode comprised of a poly(acrylic acid) binder, carbon fibers, and carbon black additives is utilized. Here, these electrodes deliver a specific capacity of 90 mAh g–1 in less than 20 s and can be cycled 3000 times while retaining over 80% of the original capacity. Quantitative kinetic analysis indicates that over 80% of the charge storage in these MoS2 nanocrystals is pseudocapacitive. Asymmetric full cell devices utilizing a MoS2 nanocrystal–based electrode and an activated carbon electrode achieve a maximum power density of 5.3 kW kg–1 (with 6 Wh kg–1 energy density) and a maximum energy density of 37 Wh kg–1 (with 74 W kg–1 power density).},
doi = {10.1002/aenm.201601283},
journal = {Advanced Energy Materials},
number = 2,
volume = 7,
place = {United States},
year = {Fri Oct 07 00:00:00 EDT 2016},
month = {Fri Oct 07 00:00:00 EDT 2016}
}
Web of Science
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- Small, Vol. 14, Issue 48
A Flexible Film toward High‐Performance Lithium Storage: Designing Nanosheet‐Assembled Hollow Single‐Hole Ni–Co–Mn–O Spheres with Oxygen Vacancy Embedded in 3D Carbon Nanotube/Graphene Network
journal, April 2019
- Li, Sesi; Zhao, Xuebing; Feng, Yuzhang
- Small, Vol. 15, Issue 27
Advanced Materials for Sodium‐Ion Capacitors with Superior Energy–Power Properties: Progress and Perspectives
journal, September 2019
- Zhang, Hongwei; Hu, Mingxiang; Lv, Qian
- Small, Vol. 16, Issue 15
Metal Chalcogenides: Paving the Way for High‐Performance Sodium/Potassium‐Ion Batteries
journal, October 2019
- Tan, Huiteng; Feng, Yuezhan; Rui, Xianhong
- Small Methods, Vol. 4, Issue 1
Holey graphene-wrapped porous TiNb24O62 microparticles as high-performance intercalation pseudocapacitive anode materials for lithium-ion capacitors
journal, May 2018
- Li, Shaohui; Chen, Jingwei; Gong, Xuefei
- NPG Asia Materials, Vol. 10, Issue 5
Achieving high energy density and high power density with pseudocapacitive materials
journal, October 2019
- Choi, Christopher; Ashby, David S.; Butts, Danielle M.
- Nature Reviews Materials, Vol. 5, Issue 1
Insights into the intrinsic capacity of interlayer-expanded MoS 2 as a Li-ion intercalation host
journal, January 2019
- Gong, Shan; Zhao, Guangyu; Lyu, Pengbo
- Journal of Materials Chemistry A, Vol. 7, Issue 3
Heterostructures of Ni–Co–Al layered double hydroxide assembled on V 4 C 3 MXene for high-energy hybrid supercapacitors
journal, January 2019
- Wang, Xin; Li, Hui; Li, Han
- Journal of Materials Chemistry A, Vol. 7, Issue 5
Improved electrochemical performance of 2D accordion-like MnV 2 O 6 nanosheets as anode materials for Li-ion batteries
journal, January 2020
- Zhang, Xiaoyu; Li, Xinjian; Jiang, Fuyi
- Dalton Transactions, Vol. 49, Issue 6
An amorphous Zn–P/graphite composite with chemical bonding for ultra-reversible lithium storage
journal, January 2019
- Li, Wenwu; Yu, Jiale; Wen, Jiajun
- Journal of Materials Chemistry A, Vol. 7, Issue 28
Sulfur covalently bonded to porous graphitic carbon as an anode material for lithium-ion capacitors with high energy storage performance
journal, January 2020
- Sun, Yue; Ma, Junpeng; Yang, Xinyue
- Journal of Materials Chemistry A, Vol. 8, Issue 1
A Facile Synthesis of MoS2/g-C3N4 Composite as an Anode Material with Improved Lithium Storage Capacity
journal, May 2019
- Tran Huu, Ha; Nguyen Thi, Xuan Dieu; Nguyen Van, Kim
- Materials, Vol. 12, Issue 11
In-Plane Assembled Orthorhombic Nb 2 O 5 Nanorod Films with High-Rate Li + Intercalation for High-Performance Flexible Li-Ion Capacitors
journal, November 2017
- Deng, Bohua; Lei, Tianyu; Zhu, Weihua
- Advanced Functional Materials, Vol. 28, Issue 1
Controllable Design of MoS 2 Nanosheets Anchored on Nitrogen-Doped Graphene: Toward Fast Sodium Storage by Tunable Pseudocapacitance
journal, May 2018
- Xu, Xin; Zhao, Ruisheng; Ai, Wei
- Advanced Materials, Vol. 30, Issue 27
Rational Design of Nickel Hydroxide-Based Nanocrystals on Graphene for Ultrafast Energy Storage
journal, December 2017
- Zhao, Bote; Zhang, Lei; Zhang, Qiaobao
- Advanced Energy Materials, Vol. 8, Issue 9
Size‐Independent Fast Ion Intercalation in Two‐Dimensional Titania Nanosheets for Alkali‐Metal‐Ion Batteries
journal, June 2019
- Yang, Jinlin; Xiao, Xu; Gong, Wenbin
- Angewandte Chemie International Edition, Vol. 58, Issue 26
Chemical Mass Production of MoS 2 /Graphene van der Waals Heterostructure as a High‐Performance Li‐ion Intercalation Host
journal, July 2019
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- ChemElectroChem, Vol. 6, Issue 13
Two‐Dimensional Germanium Sulfide Nanosheets as an Ultra‐Stable and High Capacity Anode for Lithium Ion Batteries
journal, November 2019
- Wang, Bo; Du, Wencheng; Yang, Yang
- Chemistry – A European Journal, Vol. 26, Issue 29
High-performance sodium-ion hybrid capacitors based on an interlayer-expanded MoS2/rGO composite: surpassing the performance of lithium-ion capacitors in a uniform system
journal, August 2018
- Zhan, Changzhen; Liu, Wei; Hu, Mingxiang
- NPG Asia Materials, Vol. 10, Issue 8
Cellular carbon-wrapped FeSe 2 nanocavities with ultrathin walls and multiple rooms for ion diffusion-confined ultrafast sodium storage
journal, January 2019
- Tang, Yongchao; Zhao, Zongbin; Hao, Xiaojuan
- Journal of Materials Chemistry A, Vol. 7, Issue 9
Towards fast-charging technologies in Li + /Na + storage: from the perspectives of pseudocapacitive materials and non-aqueous hybrid capacitors
journal, January 2019
- Huang, Haijian; Niederberger, Markus
- Nanoscale, Vol. 11, Issue 41
Tunable pseudocapacitive contribution by dimension control in nanocrystalline-constructed (Mg 0.2 Co 0.2 Ni 0.2 Cu 0.2 Zn 0.2 )O solid solutions to achieve superior lithium-storage properties
journal, January 2019
- Chen, Hong; Qiu, Nan; Wu, Baozhen
- RSC Advances, Vol. 9, Issue 50
Approaching the Lithiation Limit of MoS 2 While Maintaining Its Layered Crystalline Structure to Improve Lithium Storage
journal, February 2019
- Zhu, Zhiqiang; Tang, Yuxin; Leow, Wan Ru
- Angewandte Chemie, Vol. 131, Issue 11
Scalable Epitaxial Growth of WSe2 Thin Films on SiO2/Si via a Self-Assembled PtSe2 Buffer Layer
journal, May 2019
- Wu, Pei-Chen; Yang, Chun-Liang; Du, Yuanmin
- Scientific Reports, Vol. 9, Issue 1
Design of Carbon/Metal Oxide Hybrids for Electrochemical Energy Storage
collection, January 2018
- Fleischmann, Simon; Tolosa, Aura; Presser, Volker
- Universität des Saarlandes
Noncovalent Approach to Liquid-Crystalline Ion Conductors: High-Rate Performances and Room-Temperature Operation for Li-Ion Batteries
journal, January 2018
- Onuma, Taira; Hosono, Eiji; Takenouchi, Motokuni
- ACS Omega, Vol. 3, Issue 1