skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Redox Non-Innocence of Nitrosobenzene at Nickel

Authors:
ORCiD logo [1];  [2];  [3];  [3];  [1]; ORCiD logo [1]
  1. Department of Chemistry, Georgetown University, Box 571227 Washington DC 20057-1227 USA
  2. Inorganic, Isotope and Actinide Chemistry, Los, Alamos National Laboratory, Los Alamos NM 87545 USA, Department of Chemistry and Biochemistry, California State Polytechnic University, Pomona CA 91768 USA
  3. Inorganic, Isotope and Actinide Chemistry, Los, Alamos National Laboratory, Los Alamos NM 87545 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401870
Grant/Contract Number:  
AC52-06NA25396; AC02-76SF00515
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 128 Journal Issue: 35; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Kundu, Subrata, Stieber, S. Chantal E., Ferrier, Maryline G., Kozimor, Stosh A., Bertke, Jeffery A., and Warren, Timothy H. Redox Non-Innocence of Nitrosobenzene at Nickel. Germany: N. p., 2016. Web. doi:10.1002/ange.201605026.
Kundu, Subrata, Stieber, S. Chantal E., Ferrier, Maryline G., Kozimor, Stosh A., Bertke, Jeffery A., & Warren, Timothy H. Redox Non-Innocence of Nitrosobenzene at Nickel. Germany. doi:10.1002/ange.201605026.
Kundu, Subrata, Stieber, S. Chantal E., Ferrier, Maryline G., Kozimor, Stosh A., Bertke, Jeffery A., and Warren, Timothy H. Fri . "Redox Non-Innocence of Nitrosobenzene at Nickel". Germany. doi:10.1002/ange.201605026.
@article{osti_1401870,
title = {Redox Non-Innocence of Nitrosobenzene at Nickel},
author = {Kundu, Subrata and Stieber, S. Chantal E. and Ferrier, Maryline G. and Kozimor, Stosh A. and Bertke, Jeffery A. and Warren, Timothy H.},
abstractNote = {},
doi = {10.1002/ange.201605026},
journal = {Angewandte Chemie},
number = 35,
volume = 128,
place = {Germany},
year = {2016},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/ange.201605026

Save / Share:

Works referenced in this record:

Electronic Structure of Ni 2 E 2 Complexes (E = S, Se, Te) and a Global Analysis of M 2 E 2 Compounds: A Case for Quantized E 2 n Oxidation Levels with n = 2, 3, or 4
journal, April 2015

  • Yao, Shu A.; Martin-Diaconescu, Vlad; Infante, Ivan
  • Journal of the American Chemical Society, Vol. 137, Issue 15
  • DOI: 10.1021/ja511607j

Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal–ligand interactions
journal, January 2015

  • Tomson, Neil C.; Williams, Kamille D.; Dai, Xuliang
  • Chemical Science, Vol. 6, Issue 4
  • DOI: 10.1039/C4SC03294B

Redox Non-Innocence of a N -Heterocyclic Nitrenium Cation Bound to a Nickel–Cyclam Core
journal, December 2013

  • Heims, Florian; Pfaff, Florian Felix; Abram, Sarah-Luise
  • Journal of the American Chemical Society, Vol. 136, Issue 2
  • DOI: 10.1021/ja4099559

Nitric Oxide Oxidatively Nitrosylates Ni(I) and Cu(I) C -Organonitroso Adducts
journal, December 2009

  • Wiese, Stefan; Kapoor, Pooja; Williams, Kamille D.
  • Journal of the American Chemical Society, Vol. 131, Issue 50
  • DOI: 10.1021/ja903550n

Α β-Diketiminato−Nickel(II) Synthon for Nickel(I) Complexes
journal, November 2005

  • Bai, Guangcai; Wei, Pingrong; Stephan, Douglas W.
  • Organometallics, Vol. 24, Issue 24
  • DOI: 10.1021/om050544f

Reactions of HNO with Metal Porphyrins: Underscoring the Biological Relevance of HNO
journal, September 2014

  • Doctorovich, Fabio; Bikiel, Damian E.; Pellegrino, Juan
  • Accounts of Chemical Research, Vol. 47, Issue 10
  • DOI: 10.1021/ar500153c

Dioxygenase-Like Reactivity of an Isolable Superoxo-Nickel(II) Complex
journal, July 2010

  • Company, Anna; Yao, Shenglai; Ray, Kallol
  • Chemistry - A European Journal, Vol. 16, Issue 31
  • DOI: 10.1002/chem.201001138

Redox Noninnocence of Nitrosoarene Ligands in Transition Metal Complexes
journal, June 2011

  • Tomson, Neil C.; Labios, Liezel A.; Weyhermüller, Thomas
  • Inorganic Chemistry, Vol. 50, Issue 12
  • DOI: 10.1021/ic2005979

A T-Shaped Three-Coordinate Nickel(I) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d 9 Complexes
journal, October 2005

  • Eckert, Nathan A.; Dinescu, Adriana; Cundari, Thomas R.
  • Inorganic Chemistry, Vol. 44, Issue 22
  • DOI: 10.1021/ic0510213

Copper C -Nitroso Compounds: Activation of Hydroxylamines and NO Reactivity
journal, July 2013

  • Williams, Kamille D.; Cardenas, Allan Jay P.; Oliva, Jennifer D.
  • European Journal of Inorganic Chemistry, Vol. 2013, Issue 22-23
  • DOI: 10.1002/ejic.201300378

Influence of Ligand Flexibility on the Electronic Structure of Oxidized Ni III -Phenoxide Complexes
journal, September 2014

  • Kawai, Minoru; Yamaguchi, Takahide; Masaoka, Shigeyuki
  • Inorganic Chemistry, Vol. 53, Issue 19
  • DOI: 10.1021/ic501181k

A New Route to Coordination Complexes of Nitroxyl (HNO) via Insertion Reactions of Nitrosonium Triflate with Transition-Metal Hydrides
journal, October 2002

  • Melenkivitz, Rory; Southern, Joel S.; Hillhouse, Gregory L.
  • Journal of the American Chemical Society, Vol. 124, Issue 41
  • DOI: 10.1021/ja0277475

Mechanistic Studies of Copper(I)-Catalyzed Allylic Amination
journal, December 2007

  • Srivastava, Radhey S.; Tarver, Nathan R.; Nicholas, Kenneth M.
  • Journal of the American Chemical Society, Vol. 129, Issue 49
  • DOI: 10.1021/ja0751072

Nitrosyl hydride (HNO) replaces dioxygen in nitroxygenase activity of manganese quercetin dioxygenase
journal, November 2011

  • Kumar, M. R.; Zapata, A.; Ramirez, A. J.
  • Proceedings of the National Academy of Sciences, Vol. 108, Issue 47
  • DOI: 10.1073/pnas.1111488108

[Me 2 NN]Co(η 6 -toluene):  OO, NN, and ON Bond Cleavage Provides β-Diketiminato Cobalt μ-Oxo and Imido Complexes
journal, April 2004

  • Dai, Xuliang; Kapoor, Pooja; Warren, Timothy H.
  • Journal of the American Chemical Society, Vol. 126, Issue 15
  • DOI: 10.1021/ja036308i

An “End-On” Chromium(III)-Superoxo Complex: Crystallographic and Spectroscopic Characterization and Reactivity in C−H Bond Activation of Hydrocarbons
journal, May 2010

  • Cho, Jaeheung; Woo, Jaeyoung; Nam, Wonwoo
  • Journal of the American Chemical Society, Vol. 132, Issue 17
  • DOI: 10.1021/ja1015926

β-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing for H 2 and N 2 Activation
journal, December 2009

  • Pfirrmann, Stefan; Yao, Shenglai; Ziemer, Burkhard
  • Organometallics, Vol. 28, Issue 24
  • DOI: 10.1021/om9007983

The Specificity of Nitroxyl Chemistry Is Unique Among Nitrogen Oxides in Biological Systems
journal, May 2011

  • Flores-Santana, Wilmarie; Salmon, Debra J.; Donzelli, Sonia
  • Antioxidants & Redox Signaling, Vol. 14, Issue 9
  • DOI: 10.1089/ars.2010.3841

The two spin states of an end-on copper(ii)-superoxide mimic
journal, January 2011

  • Askari, Mohammad S.; Girard, Brigitte; Murugesu, Muralee
  • Chemical Communications, Vol. 47, Issue 28
  • DOI: 10.1039/c1cc11381j

Hydride Attack on a Coordinated Ferric Nitrosyl: Experimental and DFT Evidence for the Formation of a Heme Model–HNO Derivative
journal, December 2015

  • Abucayon, Erwin G.; Khade, Rahul L.; Powell, Douglas R.
  • Journal of the American Chemical Society, Vol. 138, Issue 1
  • DOI: 10.1021/jacs.5b12008

A “Side-on” Superoxonickel Complex [LNi(O 2 )] with a Square-Planar Tetracoordinate Nickel(II) Center and Its Conversion into [LNi(μ-OH) 2 NiL]
journal, September 2008

  • Yao, Shenglai; Bill, Eckhard; Milsmann, Carsten
  • Angewandte Chemie International Edition, Vol. 47, Issue 37
  • DOI: 10.1002/anie.200802234

X-ray spectroscopic studies of nickel complexes, with application to the structure of nickel sites in hydrogenases
journal, March 1991

  • Colpas, Gerard J.; Maroney, Michael J.; Bagyinka, Csaba.
  • Inorganic Chemistry, Vol. 30, Issue 5
  • DOI: 10.1021/ic00005a010

Controlled nitrene transfer from a tyrosinase-like arylnitroso–copper complex
journal, January 2015

  • Askari, Mohammad S.; Orio, Maylis; Ottenwaelder, Xavier
  • Chemical Communications, Vol. 51, Issue 56
  • DOI: 10.1039/C5CC02806J

OO Bond Activation in Heterobimetallic Peroxides: Synthesis of the Peroxide [LNi(μ,η 22 -O 2 )K] and its Conversion into a Bis(μ-Hydroxo) Nickel Zinc Complex
journal, October 2009

  • Yao, Shenglai; Xiong, Yun; Vogt, Matthias
  • Angewandte Chemie International Edition, Vol. 48, Issue 43
  • DOI: 10.1002/anie.200903772

Reductive Deprotonation and Dehydrogenation of Phenylhydrazine at a Nickel Center To Give a Nickel Diazenido Complex
journal, September 2012

  • Köthe, Claudia; Metzinger, Ramona; Herwig, Christian
  • Inorganic Chemistry, Vol. 51, Issue 18
  • DOI: 10.1021/ic301066x

Addition, Reduction, and Oxidation Reactions of Nitrosobenzene
journal, September 1994


Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates
journal, July 2015


Aromatic nitroso compounds as .pi. acids in the zerovalent nickel triad metal complexes and the metal-assisted atom-transfer reactions with donor reagents
journal, March 1976

  • Otsuka, Sei.; Aotani, Yoshimasa.; Tatsuno, Yoshitaka.
  • Inorganic Chemistry, Vol. 15, Issue 3
  • DOI: 10.1021/ic50157a032

Nitrosoarene−Cu(I) Complexes Are Intermediates in Copper-Catalyzed Allylic Amination
journal, May 2005

  • Srivastava, Radhey S.; Khan, Masood A.; Nicholas, Kenneth M.
  • Journal of the American Chemical Society, Vol. 127, Issue 20
  • DOI: 10.1021/ja044093m

A Terminal Ni(III)−Imide with Diverse Reactivity Pathways
journal, August 2005

  • Kogut, Elzbieta; Wiencko, Heather L.; Zhang, Libei
  • Journal of the American Chemical Society, Vol. 127, Issue 32
  • DOI: 10.1021/ja0533186

Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions
journal, August 2014

  • Ray, Kallol; Pfaff, Florian Felix; Wang, Bin
  • Journal of the American Chemical Society, Vol. 136, Issue 40
  • DOI: 10.1021/ja507807v

Coordination chemistry of the HNO ligand with hemes and synthetic coordination complexes
journal, January 2005


Characterization of a High-Spin Non-Heme Fe III –OOH Intermediate and Its Quantitative Conversion to an Fe IV ═O Complex
journal, May 2011

  • Li, Feifei; Meier, Katlyn K.; Cranswick, Matthew A.
  • Journal of the American Chemical Society, Vol. 133, Issue 19
  • DOI: 10.1021/ja111742z

Dioxygen Activation by a Non-Heme Iron(II) Complex: Formation of an Iron(IV)−Oxo Complex via C−H Activation by a Putative Iron(III)−Superoxo Species
journal, August 2010

  • Lee, Yong-Min; Hong, Seungwoo; Morimoto, Yuma
  • Journal of the American Chemical Society, Vol. 132, Issue 31
  • DOI: 10.1021/ja103903c

Three-Coordinate β-Diketiminato Nickel Nitrosyl Complexes from Nickel(I)−Lutidine and Nickel(II)−Alkyl Precursors
journal, September 2003

  • Puiu, Simona C.; Warren, Timothy H.
  • Organometallics, Vol. 22, Issue 20
  • DOI: 10.1021/om034041q

Interactions of Organic Nitroso Compounds with Metals
journal, April 2002

  • Lee, Jonghyuk; Chen, Li; West, Ann H.
  • Chemical Reviews, Vol. 102, Issue 4
  • DOI: 10.1021/cr0000731