Tuning the Reactivity of Ultrathin Oxides: NO Adsorption on Monolayer FeO(111)

Merte, Lindsay R.; Heard, Christopher J.; Zhang, Feng; Choi, Juhee; Shipilin, Mikhail; Gustafson, Johan; Weaver, Jason F.; Grönbeck, Henrik; Lundgren, Edvin

doi:10.1002/ange.201601647

Title: Tuning the Reactivity of Ultrathin Oxides: NO Adsorption on Monolayer FeO(111)

Journal Article · 27 June 2016 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.201601647 · OSTI ID:1401859

^[1]; Heard, Christopher J. ^[2]; Zhang, Feng ^[3]; Choi, Juhee ^[3]; Shipilin, Mikhail ^[1]; Gustafson, Johan ^[1]; Weaver, Jason F. ^[3]; Grönbeck, Henrik ^[2];

^[1]

Division of Synchrotron Radiation Research Lund University 22100 Lund Sweden
Department of Physics and Competence Centre for Catalysis Chalmers University of Technology 41296 Göteborg Sweden
Department of Chemical Engineering University of Florida Gainesville FL 32611 USA

Abstract Ultrathin metal oxides exhibit unique chemical properties and show promise for applications in heterogeneous catalysis. Monolayer FeO films supported on metal surfaces show large differences in reactivity depending on the metal substrate, potentially enabling tuning of the catalytic properties of these materials. Nitric oxide (NO) adsorption is facile on silver‐supported FeO, whereas a similar film grown on platinum is inert to NO under similar conditions. Ab initio calculations link this substrate‐dependent behavior to steric hindrance caused by substrate‐induced rumpling of the FeO surface, which is stronger for the platinum‐supported film. Calculations show that the size of the activation barrier to adsorption caused by the rumpling is dictated by the strength of the metal–oxide interaction, offering a straightforward method for tailoring the adsorption properties of ultrathin films.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-03ER15478

OSTI ID:: 1401859

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 32 Vol. 128; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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