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Title: Air‐Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3

Abstract

Abstract The first stable copper borohydride complex [(CAAC)CuBH 4 ] [CAAC=cyclic(alkyl)(amino)carbene] bearing a single monodentate ligand was prepared by addition of NaBH 4 or BH 3 NH 3 to the corresponding [(CAAC)CuCl] complex. Both complexes are air‐stable and promote the catalytic hydrolytic dehydrogenation of ammonia borane. The amount of hydrogen released reaches 2.8 H 2 /BH 3 NH 3 with a turnover frequency of 8400 mol  mol cat −1  h −1 at 25 °C. In a fifteen‐cycle experiment, the catalyst was reused without any loss of efficiency.

Authors:
; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401841
Grant/Contract Number:  
DE‐FG02‐13ER16370
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition) Journal Volume: 54 Journal Issue: 20; Journal ID: ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Hu, Xingbang, Soleilhavoup, Michèle, Melaimi, Mohand, Chu, Jiaxiang, and Bertrand, Guy. Air‐Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3. Germany: N. p., 2015. Web. doi:10.1002/anie.201500224.
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Hu, Xingbang, Soleilhavoup, Michèle, Melaimi, Mohand, Chu, Jiaxiang, & Bertrand, Guy. Air‐Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3. Germany. https://doi.org/10.1002/anie.201500224
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Hu, Xingbang, Soleilhavoup, Michèle, Melaimi, Mohand, Chu, Jiaxiang, and Bertrand, Guy. Fri . "Air‐Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3". Germany. https://doi.org/10.1002/anie.201500224.
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@article{osti_1401841,
title = {Air‐Stable (CAAC)CuCl and (CAAC)CuBH 4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH 3 NH 3},
author = {Hu, Xingbang and Soleilhavoup, Michèle and Melaimi, Mohand and Chu, Jiaxiang and Bertrand, Guy},
abstractNote = {Abstract The first stable copper borohydride complex [(CAAC)CuBH 4 ] [CAAC=cyclic(alkyl)(amino)carbene] bearing a single monodentate ligand was prepared by addition of NaBH 4 or BH 3 NH 3 to the corresponding [(CAAC)CuCl] complex. Both complexes are air‐stable and promote the catalytic hydrolytic dehydrogenation of ammonia borane. The amount of hydrogen released reaches 2.8 H 2 /BH 3 NH 3 with a turnover frequency of 8400 mol  mol cat −1  h −1 at 25 °C. In a fifteen‐cycle experiment, the catalyst was reused without any loss of efficiency.},
doi = {10.1002/anie.201500224},
journal = {Angewandte Chemie (International Edition)},
number = 20,
volume = 54,
place = {Germany},
year = {Fri Mar 20 00:00:00 EDT 2015},
month = {Fri Mar 20 00:00:00 EDT 2015}
}
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https://doi.org/10.1002/anie.201500224
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