Amorphous MoS 3 Infiltrated with Carbon Nanotubes as an Advanced Anode Material of Sodium‐Ion Batteries with Large Gravimetric, Areal, and Volumetric Capacities
Abstract
The search for earth‐abundant and high‐performance electrode materials for sodium‐ion batteries represents an important challenge to current battery research. 2D transition metal dichalcogenides, particularly MoS 2 , have attracted increasing attention recently, but few of them so far have been able to meet expectations. In this study, it is demonstrated that another phase of molybdenum sulfide—amorphous chain‐like MoS 3 —can be a better choice as the anode material of sodium‐ion batteries. Highly compact MoS 3 particles infiltrated with carbon nanotubes are prepared via the facile acid precipitation method in ethylene glycol. Compared to crystalline MoS 2 , the resultant amorphous MoS 3 not only exhibits impressive gravimetric performance—featuring excellent specific capacity (≈615 mA h g −1 ), rate capability (235 mA h g −1 at 20 A g −1 ), and cycling stability but also shows exceptional volumetric capacity of ≈1000 mA h cm −3 and an areal capacity of >6.0 mA h cm −2 at very high areal loadings of active materials (up to 12 mg cm −2 ). The experimental results are supported by density functional theory simulations showing that the 1D chains of MoS 3 can facilitate the adsorption and diffusion of Na + ions. At last,more »
- Authors:
-
- Institute of Functional Nano and Soft Materials (FUNSOM) Jiangsu Key Laboratory for Carbon‐Based Functional Materials and Devices Soochow University Suzhou 215123 China
- Chemical Sciences and Engineering Division Argonne National Laboratory Lemont IL 60439 USA
- Department of Chemistry Dalhousie University Halifax NS B3H 4R2 Canada
- Department of Chemical Engineering University of Waterloo Ontario N2L 3G1 Canada
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401718
- Grant/Contract Number:
- DE‐AC02‐06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Name: Advanced Energy Materials Journal Volume: 7 Journal Issue: 5; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Ye, Hualin, Wang, Lu, Deng, Shuo, Zeng, Xiaoqiao, Nie, Kaiqi, Duchesne, Paul N., Wang, Bo, Liu, Simon, Zhou, Junhua, Zhao, Feipeng, Han, Na, Zhang, Peng, Zhong, Jun, Sun, Xuhui, Li, Youyong, Li, Yanguang, and Lu, Jun. Amorphous MoS 3 Infiltrated with Carbon Nanotubes as an Advanced Anode Material of Sodium‐Ion Batteries with Large Gravimetric, Areal, and Volumetric Capacities. Germany: N. p., 2016.
Web. doi:10.1002/aenm.201601602.
Ye, Hualin, Wang, Lu, Deng, Shuo, Zeng, Xiaoqiao, Nie, Kaiqi, Duchesne, Paul N., Wang, Bo, Liu, Simon, Zhou, Junhua, Zhao, Feipeng, Han, Na, Zhang, Peng, Zhong, Jun, Sun, Xuhui, Li, Youyong, Li, Yanguang, & Lu, Jun. Amorphous MoS 3 Infiltrated with Carbon Nanotubes as an Advanced Anode Material of Sodium‐Ion Batteries with Large Gravimetric, Areal, and Volumetric Capacities. Germany. https://doi.org/10.1002/aenm.201601602
Ye, Hualin, Wang, Lu, Deng, Shuo, Zeng, Xiaoqiao, Nie, Kaiqi, Duchesne, Paul N., Wang, Bo, Liu, Simon, Zhou, Junhua, Zhao, Feipeng, Han, Na, Zhang, Peng, Zhong, Jun, Sun, Xuhui, Li, Youyong, Li, Yanguang, and Lu, Jun. Thu .
"Amorphous MoS 3 Infiltrated with Carbon Nanotubes as an Advanced Anode Material of Sodium‐Ion Batteries with Large Gravimetric, Areal, and Volumetric Capacities". Germany. https://doi.org/10.1002/aenm.201601602.
@article{osti_1401718,
title = {Amorphous MoS 3 Infiltrated with Carbon Nanotubes as an Advanced Anode Material of Sodium‐Ion Batteries with Large Gravimetric, Areal, and Volumetric Capacities},
author = {Ye, Hualin and Wang, Lu and Deng, Shuo and Zeng, Xiaoqiao and Nie, Kaiqi and Duchesne, Paul N. and Wang, Bo and Liu, Simon and Zhou, Junhua and Zhao, Feipeng and Han, Na and Zhang, Peng and Zhong, Jun and Sun, Xuhui and Li, Youyong and Li, Yanguang and Lu, Jun},
abstractNote = {The search for earth‐abundant and high‐performance electrode materials for sodium‐ion batteries represents an important challenge to current battery research. 2D transition metal dichalcogenides, particularly MoS 2 , have attracted increasing attention recently, but few of them so far have been able to meet expectations. In this study, it is demonstrated that another phase of molybdenum sulfide—amorphous chain‐like MoS 3 —can be a better choice as the anode material of sodium‐ion batteries. Highly compact MoS 3 particles infiltrated with carbon nanotubes are prepared via the facile acid precipitation method in ethylene glycol. Compared to crystalline MoS 2 , the resultant amorphous MoS 3 not only exhibits impressive gravimetric performance—featuring excellent specific capacity (≈615 mA h g −1 ), rate capability (235 mA h g −1 at 20 A g −1 ), and cycling stability but also shows exceptional volumetric capacity of ≈1000 mA h cm −3 and an areal capacity of >6.0 mA h cm −2 at very high areal loadings of active materials (up to 12 mg cm −2 ). The experimental results are supported by density functional theory simulations showing that the 1D chains of MoS 3 can facilitate the adsorption and diffusion of Na + ions. At last, it is demonstrated that the MoS 3 anode can be paired with an Na 3 V 2 (PO 4 ) 3 cathode to afford full cells with great capacity and cycling performance.},
doi = {10.1002/aenm.201601602},
journal = {Advanced Energy Materials},
number = 5,
volume = 7,
place = {Germany},
year = {Thu Nov 17 00:00:00 EST 2016},
month = {Thu Nov 17 00:00:00 EST 2016}
}
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Works referenced in this record:
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Mesoporous Amorphous FePO 4 Nanospheres as High-Performance Cathode Material for Sodium-Ion Batteries
journal, May 2014
- Fang, Yongjin; Xiao, Lifen; Qian, Jiangfeng
- Nano Letters, Vol. 14, Issue 6
Carbon-Coated Na 3 V 2 (PO 4 ) 3 Embedded in Porous Carbon Matrix: An Ultrafast Na-Storage Cathode with the Potential of Outperforming Li Cathodes
journal, March 2014
- Zhu, Changbao; Song, Kepeng; van Aken, Peter A.
- Nano Letters, Vol. 14, Issue 4
Synergistic Na-Storage Reactions in Sn 4 P 3 as a High-Capacity, Cycle-stable Anode of Na-Ion Batteries
journal, March 2014
- Qian, Jiangfeng; Xiong, Ya; Cao, Yuliang
- Nano Letters, Vol. 14, Issue 4
Carbon Nanofibers Decorated with Molybdenum Disulfide Nanosheets: Synergistic Lithium Storage and Enhanced Electrochemical Performance
journal, September 2014
- Zhou, Fei; Xin, Sen; Liang, Hai-Wei
- Angewandte Chemie International Edition, Vol. 53, Issue 43
Conversion reactions for sodium-ion batteries
journal, January 2013
- Klein, Franziska; Jache, Birte; Bhide, Amrtha
- Physical Chemistry Chemical Physics, Vol. 15, Issue 38
Ni 3+ -Induced Formation of Active NiOOH on the Spinel Ni-Co Oxide Surface for Efficient Oxygen Evolution Reaction
journal, February 2015
- Wang, Hsin-Yi; Hsu, Ying-Ya; Chen, Rong
- Advanced Energy Materials, Vol. 5, Issue 10
Effective Liquid-Phase Exfoliation and Sodium Ion Battery Application of MoS 2 Nanosheets
journal, May 2014
- Bang, Gyeong Sook; Nam, Kwan Woo; Kim, Jong Yun
- ACS Applied Materials & Interfaces, Vol. 6, Issue 10
Electrical, Mechanical, and Capacity Percolation Leads to High-Performance MoS 2 /Nanotube Composite Lithium Ion Battery Electrodes
journal, May 2016
- Liu, Yuping; He, Xiaoyun; Hanlon, Damien
- ACS Nano, Vol. 10, Issue 6
A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon Nanoparticle-Based Lithium-Ion Battery Negative Electrodes
journal, February 2016
- Higgins, Thomas M.; Park, Sang-Hoon; King, Paul J.
- ACS Nano, Vol. 10, Issue 3
Amorphous molybdenum trisulfide: A new lithium battery cathode
journal, November 1979
- Jacobson, A. J.; Chianelli, R. R.; Rich, S. M.
- Materials Research Bulletin, Vol. 14, Issue 11
MoS 2 Nanoflowers with Expanded Interlayers as High-Performance Anodes for Sodium-Ion Batteries
journal, September 2014
- Hu, Zhe; Wang, Lixiu; Zhang, Kai
- Angewandte Chemie, Vol. 126, Issue 47
Lithium ion battery applications of molybdenum disulfide (MoS 2 ) nanocomposites
journal, January 2014
- Stephenson, Tyler; Li, Zhi; Olsen, Brian
- Energy Environ. Sci., Vol. 7, Issue 1
Self-assembly of hierarchical MoSx/CNT nanocomposites (2<x<3): towards high performance anode materials for lithium ion batteries
journal, July 2013
- Shi, Yumeng; Wang, Ye; Wong, Jen It
- Scientific Reports, Vol. 3, Issue 1
Modeling the Structure of Amorphous MoS 3 : A Neutron Diffraction and Reverse Monte Carlo Study
journal, January 2004
- Hibble, Simon J.; Wood, Glenn B.
- Journal of the American Chemical Society, Vol. 126, Issue 3
Optimizing Areal Capacities through Understanding the Limitations of Lithium-Ion Electrodes
journal, November 2015
- Gallagher, Kevin G.; Trask, Stephen E.; Bauer, Christoph
- Journal of The Electrochemical Society, Vol. 163, Issue 2
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012
- Palomares, Verónica; Serras, Paula; Villaluenga, Irune
- Energy & Environmental Science, Vol. 5, Issue 3
Amorphous Molybdenum Sulfide Electrodes for Nonaqueous Electrochemical Cells
journal, January 1987
- Auborn, J. J.
- Journal of The Electrochemical Society, Vol. 134, Issue 3
Hydrogen evolution catalyzed by MoS3 and MoS2 particles
journal, January 2012
- Vrubel, Heron; Merki, Daniel; Hu, Xile
- Energy & Environmental Science, Vol. 5, Issue 3
Comparative IR and Raman studies of various amorphous MoS3 and LixMoS3 phases
journal, July 1989
- Sourisseau, C.; Gorochov, O.; Schleich, D. M.
- Materials Science and Engineering: B, Vol. 3, Issue 1-2
Thermal decomposition of (NH4)2MoO2S2, (NH4)2MoS4, (NH4)2WO2S2 and (NH4)2WS4
journal, June 1973
- Prasad, T. P.; Diemann, E.; Müller, A.
- Journal of Inorganic and Nuclear Chemistry, Vol. 35, Issue 6
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Water-Soluble MoS 3 Nanoparticles for Photocatalytic H 2 Evolution
journal, March 2015
- Zhang, Wei; Zhou, Tianhua; Zheng, Jianwei
- ChemSusChem, Vol. 8, Issue 8
Engineering the Composition and Crystallinity of Molybdenum Sulfide for High-Performance Electrocatalytic Hydrogen Evolution
journal, November 2014
- Li, Yanpeng; Yu, Yifei; Huang, Yufeng
- ACS Catalysis, Vol. 5, Issue 1
MoS 2 Nanosheets Vertically Aligned on Carbon Paper: A Freestanding Electrode for Highly Reversible Sodium-Ion Batteries
journal, December 2015
- Xie, Xiuqiang; Makaryan, Taron; Zhao, Mengqiang
- Advanced Energy Materials, Vol. 6, Issue 5
Single-Layered Ultrasmall Nanoplates of MoS 2 Embedded in Carbon Nanofibers with Excellent Electrochemical Performance for Lithium and Sodium Storage
journal, January 2014
- Zhu, Changbao; Mu, Xiaoke; van Aken, Peter A.
- Angewandte Chemie International Edition, Vol. 53, Issue 8
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
From Bulk to Monolayer MoS2: Evolution of Raman Scattering
journal, January 2012
- Li, Hong; Zhang, Qing; Yap, Chin Chong Ray
- Advanced Functional Materials, Vol. 22, Issue 7
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Prospects for reducing the processing cost of lithium ion batteries
journal, February 2015
- Wood, David L.; Li, Jianlin; Daniel, Claus
- Journal of Power Sources, Vol. 275
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage
journal, February 2015
- Kundu, Dipan; Talaie, Elahe; Duffort, Victor
- Angewandte Chemie International Edition, Vol. 54, Issue 11
Electrochemical properties of all-solid-state lithium batteries with amorphous MoS 3 electrodes prepared by mechanical milling
journal, January 2015
- Matsuyama, Takuya; Hayashi, Akitoshi; Ozaki, Tomoatsu
- Journal of Materials Chemistry A, Vol. 3, Issue 27
The First Report on Excellent Cycling Stability and Superior Rate Capability of Na 3 V 2 (PO 4 ) 3 for Sodium Ion Batteries
journal, November 2012
- Saravanan, Kuppan; Mason, Chad W.; Rudola, Ashish
- Advanced Energy Materials, Vol. 3, Issue 4
True Performance Metrics in Electrochemical Energy Storage
journal, November 2011
- Gogotsi, Y.; Simon, P.
- Science, Vol. 334, Issue 6058
Ab initio characterization of layered MoS2 as anode for sodium-ion batteries
journal, December 2014
- Mortazavi, Majid; Wang, Chao; Deng, Junkai
- Journal of Power Sources, Vol. 268
An Advanced MoS 2 /Carbon Anode for High-Performance Sodium-Ion Batteries
journal, September 2014
- Wang, Jingjing; Luo, Chao; Gao, Tao
- Small, Vol. 11, Issue 4
Capacitive Energy Storage in Nanostructured Carbon–Electrolyte Systems
journal, June 2012
- Simon, P.; Gogotsi, Y.
- Accounts of Chemical Research, Vol. 46, Issue 5
A Rechargeable All-Solid-State Sodium Cell with Polymer Electrolyte
journal, January 1985
- West, K.
- Journal of The Electrochemical Society, Vol. 132, Issue 12
Growth and Activation of an Amorphous Molybdenum Sulfide Hydrogen Evolving Catalyst
journal, August 2013
- Vrubel, Heron; Hu, Xile
- ACS Catalysis, Vol. 3, Issue 9
Sn 4+ Ion Decorated Highly Conductive Ti 3 C 2 MXene: Promising Lithium-Ion Anodes with Enhanced Volumetric Capacity and Cyclic Performance
journal, January 2016
- Luo, Jianmin; Tao, Xinyong; Zhang, Jun
- ACS Nano, Vol. 10, Issue 2
Hierarchical nanotubes assembled from MoS 2 -carbon monolayer sandwiched superstructure nanosheets for high-performance sodium ion batteries
journal, April 2016
- Shi, Zheng-Tian; Kang, Wenpei; Xu, Jun
- Nano Energy, Vol. 22
Nanostructured CuP 2 /C composites as high-performance anode materials for sodium ion batteries
journal, January 2015
- Zhao, Feipeng; Han, Na; Huang, Wenjing
- Journal of Materials Chemistry A, Vol. 3, Issue 43
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998
- Ankudinov, A. L.; Ravel, B.; Rehr, J. J.
- Physical Review B, Vol. 58, Issue 12
Layered SnS 2 -Reduced Graphene Oxide Composite - A High-Capacity, High-Rate, and Long-Cycle Life Sodium-Ion Battery Anode Material
journal, March 2014
- Qu, Baihua; Ma, Chuze; Ji, Ge
- Advanced Materials, Vol. 26, Issue 23
MoS 2 /Graphene Composite Paper for Sodium-Ion Battery Electrodes
journal, January 2014
- David, Lamuel; Bhandavat, Romil; Singh, Gurpreet
- ACS Nano, Vol. 8, Issue 2
Reversible sodium storage via conversion reaction of a MoS 2 –C composite
journal, January 2014
- Wang, Yun-Xiao; Seng, Kuok Hau; Chou, Shu-Lei
- Chem. Commun., Vol. 50, Issue 73
Superior Electrochemical Performance and Storage Mechanism of Na 3 V 2 (PO 4 ) 3 Cathode for Room-Temperature Sodium-Ion Batteries
journal, October 2012
- Jian, Zelang; Han, Wenze; Lu, Xia
- Advanced Energy Materials, Vol. 3, Issue 2
Thick Electrodes for High Energy Lithium Ion Batteries
journal, January 2015
- Singh, Madhav; Kaiser, Jörg; Hahn, Horst
- Journal of The Electrochemical Society, Vol. 162, Issue 7
Nanoflake-Assembled Hierarchical Na 3 V 2 (PO 4 ) 3 /C Microflowers: Superior Li Storage Performance and Insertion/Extraction Mechanism
journal, February 2015
- An, Qinyou; Xiong, Fangyu; Wei, Qiulong
- Advanced Energy Materials, Vol. 5, Issue 10
Ultrathin MoS 2 Nanosheets as Anode Materials for Sodium-Ion Batteries with Superior Performance
journal, December 2014
- Su, Dawei; Dou, Shixue; Wang, Guoxiu
- Advanced Energy Materials, Vol. 5, Issue 6
Two-Dimensional Transition Metal Dichalcogenide Monolayers as Promising Sodium Ion Battery Anodes
journal, November 2015
- Yang, Eunjeong; Ji, Hyunjun; Jung, Yousung
- The Journal of Physical Chemistry C, Vol. 119, Issue 47
Evidence from in Situ X-ray Absorption Spectroscopy for the Involvement of Terminal Disulfide in the Reduction of Protons by an Amorphous Molybdenum Sulfide Electrocatalyst
journal, December 2014
- Lassalle-Kaiser, Benedikt; Merki, Daniel; Vrubel, Heron
- Journal of the American Chemical Society, Vol. 137, Issue 1
Iron-based sodium-ion full batteries
journal, January 2016
- Ye, Hualin; Wang, Yeyun; Zhao, Feipeng
- Journal of Materials Chemistry A, Vol. 4, Issue 5
Model oxide supported MoS2 HDS catalysts: structure and surface properties
journal, January 2011
- Cesano, Federico; Bertarione, Serena; Piovano, Andrea
- Catalysis Science & Technology, Vol. 1, Issue 1
Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water
journal, January 2011
- Merki, Daniel; Fierro, Stéphane; Vrubel, Heron
- Chem. Sci., Vol. 2, Issue 7, p. 1262-1267
Solution-Processed Two-Dimensional Metal Dichalcogenide-Based Nanomaterials for Energy Storage and Conversion
journal, April 2016
- Cao, Xiehong; Tan, Chaoliang; Zhang, Xiao
- Advanced Materials, Vol. 28, Issue 29
A high tap density secondary silicon particle anode fabricated by scalable mechanical pressing for lithium-ion batteries
journal, January 2015
- Lin, Dingchang; Lu, Zhenda; Hsu, Po-Chun
- Energy & Environmental Science, Vol. 8, Issue 8
WinXAS a Program for X-ray Absorption Spectroscopy Data Analysis under MS-Windows
journal, March 1998
- Ressler, T.
- Journal of Synchrotron Radiation, Vol. 5, Issue 2, p. 118-122
High mass loading, binder-free MXene anodes for high areal capacity Li-ion batteries
journal, May 2015
- Kim, Seon Joon; Naguib, Michael; Zhao, Mengqiang
- Electrochimica Acta, Vol. 163
Enhanced photoelectrochemical hydrogen production using silicon nanowires@MoS3
journal, November 2013
- Huang, Zhipeng; Wang, Chifang; Pan, Lei
- Nano Energy, Vol. 2, Issue 6