The Distortion‐Adjusted Change of Thermal Expansion Behavior of Cubic Magnetic Semiconductor (Sc 1− x M x )F 3 (M = Al, Fe)

Han, Fei; Chen, Jun; Hu, Lei; Ren, Yang; Rong, Yangchun; Pan, Zhao; Deng, Jinxia; Xing, Xianran; White, ed., M. A.

doi:10.1111/jace.14399

Title: The Distortion‐Adjusted Change of Thermal Expansion Behavior of Cubic Magnetic Semiconductor (Sc _{1− x} M _x )F ₃ (M = Al, Fe)

Abstract

For the study of negative thermal expansion (NTE) compounds, it is critical to effectively control the thermal expansion. In this letter, a chemical approach has been taken to control the thermal expansion behavior in ScF ₃ which has a strong NTE. Owing to the difference of radius of substituting ions, local distortion inevitably emerges in the lattice matrix, which is verified by pair distribution function analysis of high‐resolution synchrotron X‐ray scattering. It is a valuable clue that the thermal expansion behaviors in the ScF ₃ based systems and other trifluorides are correlated closely to structural distortion of metal‐F‐metal linkages. In addition, the introduction of 3 d transition‐metal enables its semiconductor and ferromagnetic characteristics. This study provides important reference opinion for the control of thermal expansion and introduction of multifunctionalization for those NTE compounds with open framework structure.

Authors:

Han, Fei ^[1]; Chen, Jun ^[1]; Hu, Lei ^[1]; Ren, Yang ^[2]; Rong, Yangchun ^[1]; Pan, Zhao ^[1]; Deng, Jinxia ^[1]; Xing, Xianran ^[1]; White, ed., M. A.

Department of Physical Chemistry University of Science and Technology Beijing Beijing 100083 China
Argonne National Laboratory X‐Ray Science Division Argonne Illinois 60439

Publication Date:: Thu Jul 28 00:00:00 EDT 2016

Sponsoring Org.:: USDOE

OSTI Identifier:: 1401694

Grant/Contract Number:: DE‐AC02‐06CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of the American Ceramic Society

Additional Journal Information:: Journal Name: Journal of the American Ceramic Society Journal Volume: 99 Journal Issue: 9; Journal ID: ISSN 0002-7820

Publisher:: Wiley-Blackwell

Country of Publication:: United States

Language:: English

Citation Formats


                    Han, Fei, Chen, Jun, Hu, Lei, Ren, Yang, Rong, Yangchun, Pan, Zhao, Deng, Jinxia, Xing, Xianran, and White, ed., M. A. The Distortion‐Adjusted Change of Thermal Expansion Behavior of Cubic Magnetic Semiconductor (Sc 1− x M x )F 3 (M = Al, Fe).  United States: N. p., 2016. 
Web.  doi:10.1111/jace.14399.

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                    Han, Fei, Chen, Jun, Hu, Lei, Ren, Yang, Rong, Yangchun, Pan, Zhao, Deng, Jinxia, Xing, Xianran, & White, ed., M. A. The Distortion‐Adjusted Change of Thermal Expansion Behavior of Cubic Magnetic Semiconductor (Sc 1− x M x )F 3 (M = Al, Fe).  United States.  https://doi.org/10.1111/jace.14399

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                    Han, Fei, Chen, Jun, Hu, Lei, Ren, Yang, Rong, Yangchun, Pan, Zhao, Deng, Jinxia, Xing, Xianran, and White, ed., M. A. Thu .  
"The Distortion‐Adjusted Change of Thermal Expansion Behavior of Cubic Magnetic Semiconductor (Sc 1− x M x )F 3 (M = Al, Fe)".  United States.  https://doi.org/10.1111/jace.14399.

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@article{osti_1401694,

  title        = {The Distortion‐Adjusted Change of Thermal Expansion Behavior of Cubic Magnetic Semiconductor (Sc 1− x M x )F 3 (M = Al, Fe)},

  author       = {Han, Fei and Chen, Jun and Hu, Lei and Ren, Yang and Rong, Yangchun and Pan, Zhao and Deng, Jinxia and Xing, Xianran and White, ed., M. A.},

  abstractNote = {For the study of negative thermal expansion (NTE) compounds, it is critical to effectively control the thermal expansion. In this letter, a chemical approach has been taken to control the thermal expansion behavior in ScF 3 which has a strong NTE. Owing to the difference of radius of substituting ions, local distortion inevitably emerges in the lattice matrix, which is verified by pair distribution function analysis of high‐resolution synchrotron X‐ray scattering. It is a valuable clue that the thermal expansion behaviors in the ScF 3 based systems and other trifluorides are correlated closely to structural distortion of metal‐F‐metal linkages. In addition, the introduction of 3 d transition‐metal enables its semiconductor and ferromagnetic characteristics. This study provides important reference opinion for the control of thermal expansion and introduction of multifunctionalization for those NTE compounds with open framework structure.},

  doi          = {10.1111/jace.14399},

  journal      = {Journal of the American Ceramic Society},

  number       = 9,

  volume       = 99,

  place        = {United States},

  year         = {Thu Jul 28 00:00:00 EDT 2016},

  month        = {Thu Jul 28 00:00:00 EDT 2016}

}

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Works referenced in this record:

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Synthesis, structural and optical properties of CeO2 nanoparticles synthesized by a simple polyvinyl pyrrolidone (PVP) solution route
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Title: The Distortion‐Adjusted Change of Thermal Expansion Behavior of Cubic Magnetic Semiconductor (Sc 1− x M x )F 3 (M = Al, Fe)

Abstract

Citation Formats

Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8 journal, April 1996

Giant negative thermal expansion in Ge-doped anti-perovskite manganese nitrides journal, December 2005

Compositional Dependence of Negative Thermal Expansion in the Prussian Blue Analogues M II Pt IV (CN) 6 (M = Mn, Fe, Co, Ni, Cu, Zn, Cd) journal, May 2006

Solid solubility, phase transitions, thermal expansion, and compressibility in Sc1−Al F3 journal, February 2015

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF 3 journal, November 2010

Synthesis, structural and optical properties of CeO2 nanoparticles synthesized by a simple polyvinyl pyrrolidone (PVP) solution route journal, May 2009

A study of the structural phase transitions in AlF 3 : X-ray powder diffraction, differential scanning calorimetry (DSC) and Raman scattering investigations of the lattice dynamics and phonon spectrum journal, July 1990

High-Curie - Temperature Ferromagnetism in (Sc,Fe)F 3 Fluorides and its Dependence on Chemical Valence journal, July 2015

Zero Thermal Expansion and Ferromagnetism in Cubic Sc 1– x M x F 3 (M = Ga, Fe) over a Wide Temperature Range journal, September 2014

A century of zero expansion journal, July 1999

Negative thermal expansion of ScF 3 : Insights from density-functional molecular dynamics in the isothermal-isobaric ensemble journal, December 2015

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Giant Negative Thermal Expansion in NaZn 13 -Type La(Fe, Si, Co) 13 Compounds journal, July 2013

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Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer journal, June 2011

The Role of Spontaneous Polarization in the Negative Thermal Expansion of Tetragonal PbTiO 3 -Based Compounds journal, July 2011

Powder X-ray diffraction study of the rhombohedral to cubic phase transition in TiF3 journal, January 2002

Title: The Distortion‐Adjusted Change of Thermal Expansion Behavior of Cubic Magnetic Semiconductor (Sc _{1− x} M _x )F ₃ (M = Al, Fe)

Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8
journal, April 1996

Giant negative thermal expansion in Ge-doped anti-perovskite manganese nitrides
journal, December 2005

Compositional Dependence of Negative Thermal Expansion in the Prussian Blue Analogues M ^II Pt ^IV (CN) ₆ (M = Mn, Fe, Co, Ni, Cu, Zn, Cd)
journal, May 2006

Solid solubility, phase transitions, thermal expansion, and compressibility in Sc1−Al F3
journal, February 2015

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF ₃
journal, November 2010

Synthesis, structural and optical properties of CeO2 nanoparticles synthesized by a simple polyvinyl pyrrolidone (PVP) solution route
journal, May 2009

A study of the structural phase transitions in AlF ₃ : X-ray powder diffraction, differential scanning calorimetry (DSC) and Raman scattering investigations of the lattice dynamics and phonon spectrum
journal, July 1990

High-Curie - Temperature Ferromagnetism in (Sc,Fe)F ₃ Fluorides and its Dependence on Chemical Valence
journal, July 2015

Zero Thermal Expansion and Ferromagnetism in Cubic Sc _{1– x} M _x F ₃ (M = Ga, Fe) over a Wide Temperature Range
journal, September 2014

A century of zero expansion
journal, July 1999

Negative thermal expansion of ${ScF}_{3}$ : Insights from density-functional molecular dynamics in the isothermal-isobaric ensemble
journal, December 2015

Negative thermal expansion materials †
journal, January 1999

Giant Negative Thermal Expansion in NaZn ₁₃ -Type La(Fe, Si, Co) ₁₃ Compounds
journal, July 2013

Evolution of Negative Thermal Expansion and Phase Transitions in Sc _1-x Ti _x F ₃
journal, February 2014

Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
journal, June 2011

The Role of Spontaneous Polarization in the Negative Thermal Expansion of Tetragonal PbTiO ₃ -Based Compounds
journal, July 2011

Powder X-ray diffraction study of the rhombohedral to cubic phase transition in TiF3
journal, January 2002