Disordered 3 D Multi‐layer Graphene Anode Material from CO 2 for Sodium‐Ion Batteries
Abstract
Abstract We report the application of disordered 3 D multi‐layer graphene, synthesized directly from CO 2 gas through a reaction with Li at 550 °C, as an anode for Na‐ion batteries (SIBs) toward a sustainable and greener future. The material exhibited a reversible capacity of ∼190 mA h g −1 with a Coulombic efficiency of 98.5 % at a current density of 15 mA g −1 . The discharge capacity at higher potentials (>0.2 V vs. Na/Na + ) is ascribed to Na‐ion adsorption at defect sites, whereas the capacity at low potentials (<0.2 V) is ascribed to intercalation between graphene sheets through electrochemical characterization, Raman spectroscopy, and small‐angle X‐ray scattering experiments. The disordered multi‐layer graphene electrode demonstrated a great rate capability and cyclability. This novel approach to synthesize disordered 3 D multi‐layer graphene from CO 2 gas makes it attractive not only as an anode material for SIBs but also to mitigate CO 2 emission.
- Authors:
-
- Micron School of Materials Boise State University 1910 University Dr Boise ID 83725 USA
- Department of Materials Science and Engineering Michigan Technological University 1400 Townsend Drive Houghton MI 49931-1295 USA
- Center for Nanoscale Materials Argonne National Laboratory 9700 S. Cass Avenue Lemont IL 60439 USA
- Advanced Photon Source Argonne National Laboratory 9700 S. Cass Avenue Lemont IL 60439 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401671
- Grant/Contract Number:
- AC02-06CH11357; DEAC02-06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemSusChem
- Additional Journal Information:
- Journal Name: ChemSusChem Journal Volume: 9 Journal Issue: 12; Journal ID: ISSN 1864-5631
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Smith, Kassiopeia, Parrish, Riley, Wei, Wei, Liu, Yuzi, Li, Tao, Hu, Yun Hang, and Xiong, Hui. Disordered 3 D Multi‐layer Graphene Anode Material from CO 2 for Sodium‐Ion Batteries. Germany: N. p., 2016.
Web. doi:10.1002/cssc.201600117.
Smith, Kassiopeia, Parrish, Riley, Wei, Wei, Liu, Yuzi, Li, Tao, Hu, Yun Hang, & Xiong, Hui. Disordered 3 D Multi‐layer Graphene Anode Material from CO 2 for Sodium‐Ion Batteries. Germany. https://doi.org/10.1002/cssc.201600117
Smith, Kassiopeia, Parrish, Riley, Wei, Wei, Liu, Yuzi, Li, Tao, Hu, Yun Hang, and Xiong, Hui. Thu .
"Disordered 3 D Multi‐layer Graphene Anode Material from CO 2 for Sodium‐Ion Batteries". Germany. https://doi.org/10.1002/cssc.201600117.
@article{osti_1401671,
title = {Disordered 3 D Multi‐layer Graphene Anode Material from CO 2 for Sodium‐Ion Batteries},
author = {Smith, Kassiopeia and Parrish, Riley and Wei, Wei and Liu, Yuzi and Li, Tao and Hu, Yun Hang and Xiong, Hui},
abstractNote = {Abstract We report the application of disordered 3 D multi‐layer graphene, synthesized directly from CO 2 gas through a reaction with Li at 550 °C, as an anode for Na‐ion batteries (SIBs) toward a sustainable and greener future. The material exhibited a reversible capacity of ∼190 mA h g −1 with a Coulombic efficiency of 98.5 % at a current density of 15 mA g −1 . The discharge capacity at higher potentials (>0.2 V vs. Na/Na + ) is ascribed to Na‐ion adsorption at defect sites, whereas the capacity at low potentials (<0.2 V) is ascribed to intercalation between graphene sheets through electrochemical characterization, Raman spectroscopy, and small‐angle X‐ray scattering experiments. The disordered multi‐layer graphene electrode demonstrated a great rate capability and cyclability. This novel approach to synthesize disordered 3 D multi‐layer graphene from CO 2 gas makes it attractive not only as an anode material for SIBs but also to mitigate CO 2 emission.},
doi = {10.1002/cssc.201600117},
journal = {ChemSusChem},
number = 12,
volume = 9,
place = {Germany},
year = {Thu Apr 28 00:00:00 EDT 2016},
month = {Thu Apr 28 00:00:00 EDT 2016}
}
https://doi.org/10.1002/cssc.201600117
Web of Science
Works referenced in this record:
Mechanisms for Lithium Insertion in Carbonaceous Materials
journal, October 1995
- Dahn, J. R.; Zheng, T.; Liu, Y.
- Science, Vol. 270, Issue 5236
Amorphous TiO 2 Nanotube Anode for Rechargeable Sodium Ion Batteries
journal, September 2011
- Xiong, Hui; Slater, Michael D.; Balasubramanian, Mahalingam
- The Journal of Physical Chemistry Letters, Vol. 2, Issue 20
High-Performance Sodium Ion Batteries Based on a 3D Anode from Nitrogen-Doped Graphene Foams
journal, February 2015
- Xu, Jiantie; Wang, Min; Wickramaratne, Nilantha P.
- Advanced Materials, Vol. 27, Issue 12
Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011
- Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
- Advanced Functional Materials, Vol. 21, Issue 20
Porous carbon sphere anodes for enhanced lithium-ion storage
journal, January 2015
- Etacheri, Vinodkumar; Wang, Chengwei; O'Connell, Michael J.
- Journal of Materials Chemistry A, Vol. 3, Issue 18
Negative electrodes for Na-ion batteries
journal, January 2014
- Dahbi, Mouad; Yabuuchi, Naoaki; Kubota, Kei
- Physical Chemistry Chemical Physics, Vol. 16, Issue 29
Sodium intercalation chemistry in graphite
journal, January 2015
- Kim, Haegyeom; Hong, Jihyun; Yoon, Gabin
- Energy & Environmental Science, Vol. 8, Issue 10
Resource constraints on the battery energy storage potential for grid and transportation applications
journal, February 2011
- Wadia, Cyrus; Albertus, Paul; Srinivasan, Venkat
- Journal of Power Sources, Vol. 196, Issue 3, p. 1593-1598
Electrochemical performance of carbon onions, nanodiamonds, carbon black and multiwalled nanotubes in electrical double layer capacitors
journal, November 2007
- Portet, C.; Yushin, G.; Gogotsi, Y.
- Carbon, Vol. 45, Issue 13, p. 2511-2518
Synthesis of 3D cauliflower-fungus-like graphene from CO 2 as a highly efficient counter electrode material for dye-sensitized solar cells
journal, January 2014
- Wei, Wei; Sun, Kai; Hu, Yun Hang
- J. Mater. Chem. A, Vol. 2, Issue 40
Effect of turbostratic disorder in graphitic carbon hosts on the intercalation of lithium
journal, January 1995
- Zheng, Tao; Reimers, J. N.; Dahn, J. R.
- Physical Review B, Vol. 51, Issue 2
Recent Development on Anodes for Na-Ion Batteries
journal, January 2015
- Bommier, Clement; Ji, Xiulei
- Israel Journal of Chemistry, Vol. 55, Issue 5
Electrochemical Insertion of Sodium into Carbon
journal, January 1993
- Doeff, Marca M.
- Journal of The Electrochemical Society, Vol. 140, Issue 12
Carbon Nanosheet Frameworks Derived from Peat Moss as High Performance Sodium Ion Battery Anodes
journal, November 2013
- Ding, Jia; Wang, Huanlei; Li, Zhi
- ACS Nano, Vol. 7, Issue 12
Functionalized N-doped interconnected carbon nanofibers as an anode material for sodium-ion storage with excellent performance
journal, April 2013
- Wang, Zhaohui; Qie, Long; Yuan, Lixia
- Carbon, Vol. 55
Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials
journal, January 2011
- Ong, Shyue Ping; Chevrier, Vincent L.; Hautier, Geoffroy
- Energy & Environmental Science, Vol. 4, Issue 9
High Capacity Anode Materials for Rechargeable Sodium-Ion Batteries
journal, January 2000
- Stevens, D. A.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 147, Issue 4
Expanded graphite as superior anode for sodium-ion batteries
journal, June 2014
- Wen, Yang; He, Kai; Zhu, Yujie
- Nature Communications, Vol. 5, Issue 1
In Operando Monitoring of the Pore Dynamics in Ordered Mesoporous Electrode Materials by Small Angle X-ray Scattering
journal, April 2015
- Park, Gwi Ok; Yoon, Jeongbae; Park, Eunjun
- ACS Nano, Vol. 9, Issue 5
Sodium and sodium-ion energy storage batteries
journal, August 2012
- Ellis, Brian L.; Nazar, Linda F.
- Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012
- Palomares, Verónica; Serras, Paula; Villaluenga, Irune
- Energy & Environmental Science, Vol. 5, Issue 3
Nanostructured Bilayered Vanadium Oxide Electrodes for Rechargeable Sodium-Ion Batteries
journal, December 2011
- Tepavcevic, Sanja; Xiong, Hui; Stamenkovic, Vojislav R.
- ACS Nano, Vol. 6, Issue 1
Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes
journal, February 2011
- Kim, Donghan; Kang, Sun-Ho; Slater, Michael
- Advanced Energy Materials, Vol. 1, Issue 3, p. 333-336
Lithium Insertion in High Capacity Carbonaceous Materials
journal, January 1995
- Zheng, Tao
- Journal of The Electrochemical Society, Vol. 142, Issue 8
Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries
journal, August 2015
- Xiang, Xingde; Zhang, Kai; Chen, Jun
- Advanced Materials, Vol. 27, Issue 36
Materials Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid
journal, June 2012
- Liu, Jun; Zhang, Ji-Guang; Yang, Zhenguo
- Advanced Functional Materials, Vol. 23, Issue 8
Sodium-Ion Batteries
journal, May 2012
- Slater, Michael D.; Kim, Donghan; Lee, Eungje
- Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications
journal, June 2012
- Cao, Yuliang; Xiao, Lifen; Sushko, Maria L.
- Nano Letters, Vol. 12, Issue 7
Identifying the Critical Role of Li Substitution in P2–Na x [Li y Ni z Mn 1– y – z ]O 2 (0 < x , y , z < 1) Intercalation Cathode Materials for High-Energy Na-Ion Batteries
journal, December 2013
- Xu, Jing; Lee, Dae Hoe; Clément, Raphaële J.
- Chemistry of Materials, Vol. 26, Issue 2
Defective Graphene as a High-Capacity Anode Material for Na- and Ca-Ion Batteries
journal, January 2014
- Datta, Dibakar; Li, Junwen; Shenoy, Vivek B.
- ACS Applied Materials & Interfaces, Vol. 6, Issue 3
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon
journal, August 2015
- Bommier, Clement; Surta, Todd Wesley; Dolgos, Michelle
- Nano Letters, Vol. 15, Issue 9
Ab initio study of sodium intercalation into disordered carbon
journal, January 2015
- Tsai, Ping-chun; Chung, Sai-Cheong; Lin, Shih-kang
- Journal of Materials Chemistry A, Vol. 3, Issue 18
The Mechanisms of Lithium and Sodium Insertion in Carbon Materials
journal, January 2001
- Stevens, D. A.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 148, Issue 8
Update on Na-based battery materials. A growing research path
journal, January 2013
- Palomares, Verónica; Casas-Cabanas, Montse; Castillo-Martínez, Elizabeth
- Energy & Environmental Science, Vol. 6, Issue 8
Density Functional Theory Calculations of Alkali Metal (Li, Na, and K) Graphite Intercalation Compounds
journal, December 2013
- Okamoto, Yasuharu
- The Journal of Physical Chemistry C, Vol. 118, Issue 1
Carbon black: a promising electrode material for sodium-ion batteries
journal, November 2001
- Alcántara, Ricardo; Jiménez-Mateos, Juan M.; Lavela, Pedro
- Electrochemistry Communications, Vol. 3, Issue 11, p. 639-642
3D flower-structured graphene from CO 2 for supercapacitors with ultrahigh areal capacitance at high current density
journal, January 2015
- Chang, Liang; Wei, Wei; Sun, Kai
- Journal of Materials Chemistry A, Vol. 3, Issue 19