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Title: Mesoporous Ruthenium/Ruthenium Oxide Thin Films: Active Electrocatalysts for the Oxygen Evolution Reaction

Authors:
 [1];  [2];  [2];  [2];  [3]
  1. Department of Physics, Technical University of Denmark, DK-2800 Kongens Lyngby Denmark, Department of Chemical Engineering, Stanford University, Stanford, California 94305 USA, SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, 2575 Sand Hill Road Menlo Park, California 94025 USA
  2. Department of Chemical Engineering, Stanford University, Stanford, California 94305 USA
  3. Department of Chemical Engineering, Stanford University, Stanford, California 94305 USA, SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, 2575 Sand Hill Road Menlo Park, California 94025 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1401560
Grant/Contract Number:  
EE006670
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemElectroChem
Additional Journal Information:
Journal Name: ChemElectroChem Journal Volume: 4 Journal Issue: 10; Journal ID: ISSN 2196-0216
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Kibsgaard, Jakob, Hellstern, Thomas R., Choi, Shin-Jung, Reinecke, Benjamin N., and Jaramillo, Thomas F. Mesoporous Ruthenium/Ruthenium Oxide Thin Films: Active Electrocatalysts for the Oxygen Evolution Reaction. Germany: N. p., 2017. Web. doi:10.1002/celc.201700334.
Kibsgaard, Jakob, Hellstern, Thomas R., Choi, Shin-Jung, Reinecke, Benjamin N., & Jaramillo, Thomas F. Mesoporous Ruthenium/Ruthenium Oxide Thin Films: Active Electrocatalysts for the Oxygen Evolution Reaction. Germany. doi:10.1002/celc.201700334.
Kibsgaard, Jakob, Hellstern, Thomas R., Choi, Shin-Jung, Reinecke, Benjamin N., and Jaramillo, Thomas F. Tue . "Mesoporous Ruthenium/Ruthenium Oxide Thin Films: Active Electrocatalysts for the Oxygen Evolution Reaction". Germany. doi:10.1002/celc.201700334.
@article{osti_1401560,
title = {Mesoporous Ruthenium/Ruthenium Oxide Thin Films: Active Electrocatalysts for the Oxygen Evolution Reaction},
author = {Kibsgaard, Jakob and Hellstern, Thomas R. and Choi, Shin-Jung and Reinecke, Benjamin N. and Jaramillo, Thomas F.},
abstractNote = {},
doi = {10.1002/celc.201700334},
journal = {ChemElectroChem},
number = 10,
volume = 4,
place = {Germany},
year = {2017},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/celc.201700334

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Cited by: 8 works
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Works referenced in this record:

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices
journal, March 2015

  • McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/ja510442p

Addressing the terawatt challenge: scalability in the supply of chemical elements for renewable energy
journal, January 2012

  • Vesborg, Peter C. K.; Jaramillo, Thomas F.
  • RSC Advances, Vol. 2, Issue 21
  • DOI: 10.1039/c2ra20839c

Ordered mesoporous materials
journal, February 1999


Uncovering the Stabilization Mechanism in Bimetallic Ruthenium–Iridium Anodes for Proton Exchange Membrane Electrolyzers
journal, August 2016

  • Saveleva, Viktoriia A.; Wang, Li; Luo, Wen
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 16
  • DOI: 10.1021/acs.jpclett.6b01500

Mass Transport and Electrode Accessibility Through Periodic Self-Assembled Nanoporous Silica Thin Films
journal, May 2007

  • Wei, Ta-Chen; Hillhouse, Hugh W.
  • Langmuir, Vol. 23, Issue 10
  • DOI: 10.1021/la062699d

A comparative study of the oxygen evolution reaction on oxidised nickel, cobalt and iron electrodes in base
journal, March 2010


Nanoscopic Templates from Oriented Block Copolymer Films
journal, June 2000


Nanofabrication of Double-Gyroid Thin Films
journal, February 2007

  • Urade, Vikrant N.; Wei, Ta-Chen; Tate, Michael P.
  • Chemistry of Materials, Vol. 19, Issue 4
  • DOI: 10.1021/cm062136n

Electronic connection to the interior of a mesoporous insulator with nanowires of crystalline RuO2
journal, July 2000

  • Ryan, Joseph V.; Berry, Alan D.; Anderson, Michele L.
  • Nature, Vol. 406, Issue 6792, p. 169-172
  • DOI: 10.1038/35018040

Sputtered thin-film pH electrodes of platinum, palladium, ruthenium, and iridium oxides
journal, October 1995

  • Kreider, Kenneth G.; Tarlov, Michael J.; Cline, James P.
  • Sensors and Actuators B: Chemical, Vol. 28, Issue 3
  • DOI: 10.1016/0925-4005(95)01655-4

Oxygen evolution on well-characterized mass-selected Ru and RuO 2 nanoparticles
journal, January 2015

  • Paoli, Elisa A.; Masini, Federico; Frydendal, Rasmus
  • Chemical Science, Vol. 6, Issue 1
  • DOI: 10.1039/C4SC02685C

The oxygen evolution reaction on platinum, iridium, ruthenium and their alloys at 80°C in acid solutions
journal, June 1978


Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity
journal, August 2003


The Gyroid: A New Equilibrium Morphology in Weakly Segregated Diblock Copolymers
journal, July 1994

  • Hajduk, Damian A.; Harper, Paul E.; Gruner, Sol M.
  • Macromolecules, Vol. 27, Issue 15
  • DOI: 10.1021/ma00093a006

A general route for RuO 2 deposition on metal oxides from RuO 4
journal, January 2012

  • Kleiman-Shwarsctein, Alan; Laursen, Anders B.; Cavalca, Filippo
  • Chem. Commun., Vol. 48, Issue 7
  • DOI: 10.1039/C1CC16759F

A highly active and stable IrO x /SrIrO 3 catalyst for the oxygen evolution reaction
journal, September 2016


Nanotube-Based Ultrafast Electrochromic Display
journal, January 2005


Improved Electrode Performance of Porous LiFePO4 Using RuO2 as an Oxidic Nanoscale Interconnect
journal, August 2007

  • Hu, Y.-S.; Guo, Y.-G.; Dominko, R.
  • Advanced Materials, Vol. 19, Issue 15, p. 1963-1966
  • DOI: 10.1002/adma.200700697

Physikalisch-chemische Probleme bei der Erzeugung und Speicherung chemischer sekundärer Energieträger
journal, October 1980

  • Stucki, S.; Menth, A.
  • Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 84, Issue 10
  • DOI: 10.1002/bbpc.19800841012

Templating Mesoporous Zeolites
journal, February 2008

  • Egeblad, Kresten; Christensen, Christina H.; Kustova, Marina
  • Chemistry of Materials, Vol. 20, Issue 3
  • DOI: 10.1021/cm702224p

Ruthenium Oxide Thin Film Electrodes for Supercapacitors
journal, January 2001

  • Kim, Il-Hwan; Kim, Kwang-Bum
  • Electrochemical and Solid-State Letters, Vol. 4, Issue 5
  • DOI: 10.1149/1.1359956

Block Copolymers—Designer Soft Materials
journal, February 1999

  • Bates, Frank S.; Fredrickson, Glenn H.
  • Physics Today, Vol. 52, Issue 2
  • DOI: 10.1063/1.882522

Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures
journal, June 1998

  • Zhao, Dongyuan; Huo, Qisheng; Feng, Jianglin
  • Journal of the American Chemical Society, Vol. 120, Issue 24
  • DOI: 10.1021/ja974025i

Meso-Structured Platinum Thin Films: Active and Stable Electrocatalysts for the Oxygen Reduction Reaction
journal, April 2012

  • Kibsgaard, Jakob; Gorlin, Yelena; Chen, Zhebo
  • Journal of the American Chemical Society, Vol. 134, Issue 18
  • DOI: 10.1021/ja2120162

Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts
journal, June 2004

  • Mallat, Tamas; Baiker, Alfons
  • Chemical Reviews, Vol. 104, Issue 6
  • DOI: 10.1021/cr0200116

Structure influence on electrocatalysis and adsorption of intermediates in the anodic O2 evolution at dimorphic α- and β-PbO2
journal, March 1994

  • Ho, J. C. K.; Filho, G. Tremiliosi; Simpraga, R.
  • Journal of Electroanalytical Chemistry, Vol. 366, Issue 1-2
  • DOI: 10.1016/0022-0728(93)03066-X

Synthesis and Activities of Rutile IrO 2 and RuO 2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions
journal, January 2012

  • Lee, Youngmin; Suntivich, Jin; May, Kevin J.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 3
  • DOI: 10.1021/jz2016507

Electrocatalysis: understanding the success of DSA®
journal, May 2000


Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
journal, October 2012

  • Kibsgaard, Jakob; Chen, Zhebo; Reinecke, Benjamin N.
  • Nature Materials, Vol. 11, Issue 11, p. 963-969
  • DOI: 10.1038/nmat3439

Ruthenium-based electrocatalysts for oxygen reduction reaction—a review
journal, April 2007


Electrocatalysis of H2 evolution by thermally prepared ruthenium oxide
journal, February 2007


Rotating ring–disc electrode study of the enhanced oxygen evolution on an activated ruthenium electrode
journal, January 1990


Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials
journal, July 2012

  • Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter
  • ACS Catalysis, Vol. 2, Issue 8
  • DOI: 10.1021/cs3003098

Supported Ruthenium Catalyst for the Heterogeneous Oxidation of Alcohols with Molecular Oxygen
journal, December 2002


Structure sensitivity of supported ruthenium catalysts for ammonia synthesis
journal, December 2000

  • Jacobsen, Claus J. H.; Dahl, Søren; Hansen, Poul L.
  • Journal of Molecular Catalysis A: Chemical, Vol. 163, Issue 1-2
  • DOI: 10.1016/S1381-1169(00)00396-4

Interaction of CO with hydrous ruthenium oxide and development of a chemoresistive ambient CO sensor
journal, March 2011

  • Adeyemo, Adedunni; Hunter, Gary; Dutta, Prabir K.
  • Sensors and Actuators B: Chemical, Vol. 152, Issue 2
  • DOI: 10.1016/j.snb.2010.12.027

Mesoporous IrO 2 Films Templated by PEO-PB-PEO Block-Copolymers: Self-Assembly, Crystallization Behavior, and Electrocatalytic Performance
journal, July 2011

  • Ortel, Erik; Reier, Tobias; Strasser, Peter
  • Chemistry of Materials, Vol. 23, Issue 13
  • DOI: 10.1021/cm200761f

Electron spectroscopy characterization of an activated ruthenium electrode
journal, September 1993

  • Vuković, Marijan; Valla, Tonica; Milun, Milorad
  • Journal of Electroanalytical Chemistry, Vol. 356, Issue 1-2
  • DOI: 10.1016/0022-0728(93)80512-G

Reduction of carbon dioxide on ruthenium oxide and modified ruthenium oxide electrodes in 0.5 M NaHCO3
journal, January 1997

  • Popić, J. P.; Avramov-Ivić, M. L.; Vuković, N. B.
  • Journal of Electroanalytical Chemistry, Vol. 421, Issue 1-2, p. 105-110
  • DOI: 10.1016/S0022-0728(96)04823-1

Electrodeposition of mesoporous ruthenium oxide using an aqueous mixture of CTAB and SDS as a templating agent
journal, January 2012


Electrochemical chlorine evolution at rutile oxide (110) surfaces
journal, January 2010

  • Hansen, Heine A.; Man, Isabela C.; Studt, Felix
  • Phys. Chem. Chem. Phys., Vol. 12, Issue 1
  • DOI: 10.1039/B917459A

Ruthenium dioxide-based film electrodes: III. Effect of chemical composition and surface morphology on oxygen evolution in acid solutions
journal, March 1978

  • Lodi, G.; Sivieri, E.; De Battisti, A.
  • Journal of Applied Electrochemistry, Vol. 8, Issue 2
  • DOI: 10.1007/BF00617671

Growth and characterization of nanosized structures of conducting polymers
journal, March 2001


Design, Synthesis, and Properties of Inorganic and Hybrid Thin Films Having Periodically Organized Nanoporosity
journal, February 2008

  • Sanchez, Clément; Boissière, Cédric; Grosso, David
  • Chemistry of Materials, Vol. 20, Issue 3
  • DOI: 10.1021/cm702100t

Ruthenium Dioxide as Cathode Material for Hydrogen Evolution in Hydroxide and Chlorate Solutions
journal, January 1993

  • Cornell, Ann
  • Journal of The Electrochemical Society, Vol. 140, Issue 11
  • DOI: 10.1149/1.2220996

Block‐Copolymer‐Templated Synthesis of Electroactive RuO 2 ‐Based Mesoporous Thin Films
journal, June 2009

  • Sassoye, Capucine; Laberty, Christel; Le Khanh, Hung
  • Advanced Functional Materials, Vol. 19, Issue 12
  • DOI: 10.1002/adfm.200801831

Electrocatalytic activation of ruthenium electrodes for the Cl2 and O2 evolution reactions by anodic/cathodic cycling
journal, March 1982

  • Vuković, M.; Angerstein-Kozlowska, H.; Conway, B. E.
  • Journal of Applied Electrochemistry, Vol. 12, Issue 2
  • DOI: 10.1007/BF00616901

Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron (Oxy)Hydroxide Catalysts
journal, August 2015

  • Swierk, John R.; Klaus, Shannon; Trotochaud, Lena
  • The Journal of Physical Chemistry C, Vol. 119, Issue 33
  • DOI: 10.1021/acs.jpcc.5b05861

Transition from “Supercapacitor” to “Battery” Behavior in Electrochemical Energy Storage
journal, January 1991

  • Conway, B. E.
  • Journal of The Electrochemical Society, Vol. 138, Issue 6, p. 1539-1548
  • DOI: 10.1149/1.2085829

Direct synthesis of electroactive mesoporous hydrous crystalline RuO2 templated by a cationic surfactant
journal, January 2010

  • Oh, Si Hyoung; Nazar, Linda F.
  • Journal of Materials Chemistry, Vol. 20, Issue 19
  • DOI: 10.1039/b926734d

On the Origin of the Improved Ruthenium Stability in RuO 2 –IrO 2 Mixed Oxides
journal, January 2016

  • Kasian, Olga; Geiger, Simon; Stock, Philipp
  • Journal of The Electrochemical Society, Vol. 163, Issue 11
  • DOI: 10.1149/2.0131611jes