DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: All-Printed, Stretchable Zn-Ag2O Rechargeable Battery via Hyperelastic Binder for Self-Powering Wearable Electronics

Abstract

While several stretchable batteries utilizing either deterministic or random composite architectures have been described, none have been fabricated using inexpensive printing technologies. In this study, the authors printed a highly stretchable, zinc‐silver oxide (Zn‐Ag 2 O) battery by incorporating polystyrene‐ block ‐polyisoprene‐ block ‐polystyrene (SIS) as a hyperelastic binder for custom‐made printable inks. The remarkable mechanical properties of the SIS binder lead to an all‐printed, stretchable Zn‐Ag 2 O rechargeable battery with a ≈2.5 mA h cm −2 reversible capacity density even after multiple iterations of 100% stretching. This battery offers the highest reversible capacity and discharge current density for intrinsically stretchable batteries reported to date. The electrochemical and mechanical properties are characterized under different strain conditions. The new stress‐enduring printable inks pave ways for further developing stretchable electronics for the wide range of wearable applications.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Univ. of California, San Diego, CA (United States)
Publication Date:
Research Org.:
Univ. of California, San Diego, CA (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1533074
Alternate Identifier(s):
OSTI ID: 1401499
Grant/Contract Number:  
AR0000535
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 7; Journal Issue: 8; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; Chemistry; Energy & Fuels; Materials Science; Physics; digital image correlation (DIC); polystyrene-block-polyisoprene-block-polystyrene (SIS); printable electronics; rechargeable Zn-Ag2O batteries; stretchable electronics

Citation Formats

Kumar, Rajan, Shin, Jaewook, Yin, Lu, You, Jung-Min, Meng, Ying Shirley, and Wang, Joseph. All-Printed, Stretchable Zn-Ag2O Rechargeable Battery via Hyperelastic Binder for Self-Powering Wearable Electronics. United States: N. p., 2016. Web. doi:10.1002/aenm.201602096.
Kumar, Rajan, Shin, Jaewook, Yin, Lu, You, Jung-Min, Meng, Ying Shirley, & Wang, Joseph. All-Printed, Stretchable Zn-Ag2O Rechargeable Battery via Hyperelastic Binder for Self-Powering Wearable Electronics. United States. https://doi.org/10.1002/aenm.201602096
Kumar, Rajan, Shin, Jaewook, Yin, Lu, You, Jung-Min, Meng, Ying Shirley, and Wang, Joseph. Mon . "All-Printed, Stretchable Zn-Ag2O Rechargeable Battery via Hyperelastic Binder for Self-Powering Wearable Electronics". United States. https://doi.org/10.1002/aenm.201602096. https://www.osti.gov/servlets/purl/1533074.
@article{osti_1533074,
title = {All-Printed, Stretchable Zn-Ag2O Rechargeable Battery via Hyperelastic Binder for Self-Powering Wearable Electronics},
author = {Kumar, Rajan and Shin, Jaewook and Yin, Lu and You, Jung-Min and Meng, Ying Shirley and Wang, Joseph},
abstractNote = {While several stretchable batteries utilizing either deterministic or random composite architectures have been described, none have been fabricated using inexpensive printing technologies. In this study, the authors printed a highly stretchable, zinc‐silver oxide (Zn‐Ag 2 O) battery by incorporating polystyrene‐ block ‐polyisoprene‐ block ‐polystyrene (SIS) as a hyperelastic binder for custom‐made printable inks. The remarkable mechanical properties of the SIS binder lead to an all‐printed, stretchable Zn‐Ag 2 O rechargeable battery with a ≈2.5 mA h cm −2 reversible capacity density even after multiple iterations of 100% stretching. This battery offers the highest reversible capacity and discharge current density for intrinsically stretchable batteries reported to date. The electrochemical and mechanical properties are characterized under different strain conditions. The new stress‐enduring printable inks pave ways for further developing stretchable electronics for the wide range of wearable applications.},
doi = {10.1002/aenm.201602096},
journal = {Advanced Energy Materials},
number = 8,
volume = 7,
place = {United States},
year = {Mon Dec 19 00:00:00 EST 2016},
month = {Mon Dec 19 00:00:00 EST 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 186 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Flexible and Stretchable Electronics Paving the Way for Soft Robotics
journal, March 2014


Thermoplastic Elastomers
book, January 2013


All‐Printed Stretchable Electrochemical Devices
journal, April 2015

  • Bandodkar, Amay J.; Nuñez‐Flores, Rogelio; Jia, Wenzhao
  • Advanced Materials, Vol. 27, Issue 19
  • DOI: 10.1002/adma.201500768

Soft Conductive Elastomer Materials for Stretchable Electronics and Voltage Controlled Artificial Muscles
journal, October 2012

  • Stoyanov, Hristiyan; Kollosche, Matthias; Risse, Sebastian
  • Advanced Materials, Vol. 25, Issue 4
  • DOI: 10.1002/adma.201202728

Materials and Fractal Designs for 3D Multifunctional Integumentary Membranes with Capabilities in Cardiac Electrotherapy
journal, January 2015


3D Printing of Highly Stretchable and Tough Hydrogels into Complex, Cellularized Structures
journal, June 2015

  • Hong, Sungmin; Sycks, Dalton; Chan, Hon Fai
  • Advanced Materials, Vol. 27, Issue 27
  • DOI: 10.1002/adma.201501099

Wearable Chemical Sensors: Present Challenges and Future Prospects
journal, March 2016


“Cut-and-Paste” Manufacture of Multiparametric Epidermal Sensor Systems
journal, September 2015

  • Yang, Shixuan; Chen, Ying-Chen; Nicolini, Luke
  • Advanced Materials, Vol. 27, Issue 41
  • DOI: 10.1002/adma.201502386

Ultraflexible organic photonic skin
journal, April 2016

  • Yokota, Tomoyuki; Zalar, Peter; Kaltenbrunner, Martin
  • Science Advances, Vol. 2, Issue 4
  • DOI: 10.1126/sciadv.1501856

Stretchable Electronics: Materials Strategies and Devices
journal, December 2008

  • Kim, Dae-Hyeong; Rogers, John A.
  • Advanced Materials, Vol. 20, Issue 24, p. 4887-4892
  • DOI: 10.1002/adma.200801788

Printing Technology
book, December 2013

  • Suganuma, Katsuaki
  • Introduction to Printed Electronics. SpringerBriefs in Electrical and Computer Engineering
  • DOI: 10.1007/978-1-4614-9625-0_2

Stretchable GaAs Photovoltaics with Designs That Enable High Areal Coverage
journal, January 2011


Printable elastic conductors with a high conductivity for electronic textile applications
journal, June 2015

  • Matsuhisa, Naoji; Kaltenbrunner, Martin; Yokota, Tomoyuki
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8461

Stretchable Organic Solar Cells
journal, February 2011

  • Lipomi, Darren J.; Tee, Benjamin C. -K.; Vosgueritchian, Michael
  • Advanced Materials, Vol. 23, Issue 15
  • DOI: 10.1002/adma.201004426

Soft Power: Stretchable and Ultra-Flexible Energy Sources for Wearable and Implantable Devices
book, January 2016

  • O’Connor, Timothy F.; Savagatrup, Suchol; Lipomi, Darren J.
  • Stretchable Bioelectronics for Medical Devices and Systems
  • DOI: 10.1007/978-3-319-28694-5_4

Stretchable, Skin-Mountable, and Wearable Strain Sensors and Their Potential Applications: A Review
journal, February 2016

  • Amjadi, Morteza; Kyung, Ki-Uk; Park, Inkyu
  • Advanced Functional Materials, Vol. 26, Issue 11
  • DOI: 10.1002/adfm.201504755

A wearable chemical–electrophysiological hybrid biosensing system for real-time health and fitness monitoring
journal, May 2016

  • Imani, Somayeh; Bandodkar, Amay J.; Mohan, A. M. Vinu
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11650

Cable-Type Flexible Lithium Ion Battery Based on Hollow Multi-Helix Electrodes
journal, August 2012

  • Kwon, Yo Han; Woo, Sang-Wook; Jung, Hye-Ran
  • Advanced Materials, Vol. 24, Issue 38
  • DOI: 10.1002/adma.201202196

Design of conductive composite elastomers for stretchable electronics
journal, April 2014


Soft, stretchable, fully implantable miniaturized optoelectronic systems for wireless optogenetics
journal, November 2015

  • Park, Sung Il; Brenner, Daniel S.; Shin, Gunchul
  • Nature Biotechnology, Vol. 33, Issue 12
  • DOI: 10.1038/nbt.3415

Kirigami-based stretchable lithium-ion batteries
journal, June 2015

  • Song, Zeming; Wang, Xu; Lv, Cheng
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep10988

Direct Pen Writing of Adhesive Particle-Free Ultrahigh Silver Salt-Loaded Composite Ink for Stretchable Circuits
journal, December 2015


A graphene-based electrochemical device with thermoresponsive microneedles for diabetes monitoring and therapy
journal, March 2016

  • Lee, Hyunjae; Choi, Tae Kyu; Lee, Young Bum
  • Nature Nanotechnology, Vol. 11, Issue 6
  • DOI: 10.1038/nnano.2016.38

Power Supply, Generation, and Storage in Stretchable Electronics
book, January 2012


Elastomeric polymer light-emitting devices and displays
journal, September 2013


An epidermal alkaline rechargeable Ag–Zn printable tattoo battery for wearable electronics
journal, January 2014

  • Berchmans, Sheela; Bandodkar, Amay J.; Jia, Wenzhao
  • J. Mater. Chem. A, Vol. 2, Issue 38
  • DOI: 10.1039/C4TA03256J

Smart bandage with wireless connectivity for uric acid biosensing as an indicator of wound status
journal, July 2015


All-Graphene Core-Sheath Microfibers for All-Solid-State, Stretchable Fibriform Supercapacitors and Wearable Electronic Textiles
journal, March 2013


Deposition of ZnO on bismuth species towards a rechargeable Zn-based aqueous battery
journal, January 2016

  • Shin, JaeWook; You, Jung-Min; Lee, Jungwoo Z.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 38
  • DOI: 10.1039/C6CP04566A

A Stencil Printed, High Energy Density Silver Oxide Battery Using a Novel Photopolymerizable Poly(acrylic acid) Separator
journal, December 2014


Advances and Future Challenges in Printed Batteries
journal, September 2015

  • Sousa, Ricardo E.; Costa, Carlos M.; Lanceros-Méndez, Senentxu
  • ChemSusChem, Vol. 8, Issue 21
  • DOI: 10.1002/cssc.201500657

An Effective Mixing for Lithium Ion Battery Slurries
journal, January 2014

  • Liu, Darjen; Chen, Li-Chun; Liu, Ta-Jo
  • Advances in Chemical Engineering and Science, Vol. 04, Issue 04
  • DOI: 10.4236/aces.2014.44053

Vulcanization
book, January 2013


Encapsulated, High-Performance, Stretchable Array of Stacked Planar Micro-Supercapacitors as Waterproof Wearable Energy Storage Devices
journal, June 2016

  • Kim, Hyoungjun; Yoon, Jangyeol; Lee, Geumbee
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 25
  • DOI: 10.1021/acsami.6b03504

Noninvasive Alcohol Monitoring Using a Wearable Tattoo-Based Iontophoretic-Biosensing System
journal, July 2016


Fractal design concepts for stretchable electronics
journal, February 2014

  • Fan, Jonathan A.; Yeo, Woon-Hong; Su, Yewang
  • Nature Communications, Vol. 5, Article No. 3266 (2014)
  • DOI: 10.1038/ncomms4266

Highly Stretchable Fully-Printed CNT-Based Electrochemical Sensors and Biofuel Cells: Combining Intrinsic and Design-Induced Stretchability
journal, December 2015


Synthesis and Applications of Copolymers
book, January 2014


Wearable Fall Detector using Integrated Sensors and Energy Devices
journal, November 2015

  • Jung, Sungmook; Hong, Seungki; Kim, Jaemin
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep17081

Tattoo-Based Noninvasive Glucose Monitoring: A Proof-of-Concept Study
journal, December 2014

  • Bandodkar, Amay J.; Jia, Wenzhao; Yardımcı, Ceren
  • Analytical Chemistry, Vol. 87, Issue 1
  • DOI: 10.1021/ac504300n

Stretchable Silver-Zinc Batteries Based on Embedded Nanowire Elastic Conductors
journal, October 2013


Methods of Enhancing Miscibility
book, January 1979


Materials and Designs for Wireless Epidermal Sensors of Hydration and Strain
journal, March 2014

  • Huang, Xian; Liu, Yuhao; Cheng, Huanyu
  • Advanced Functional Materials, Vol. 24, Issue 25
  • DOI: 10.1002/adfm.201303886

Highly Stretchable Alkaline Batteries Based on an Embedded Conductive Fabric
journal, July 2012

  • Gaikwad, Abhinav M.; Zamarayeva, Alla M.; Rousseau, Jamesley
  • Advanced Materials, Vol. 24, Issue 37, p. 5071-5076
  • DOI: 10.1002/adma.201201329

Two-dimensional digital image correlation for in-plane displacement and strain measurement: a review
journal, April 2009


Balloon-Embedded Sensors Withstanding Extreme Multiaxial Stretching and Global Bending Mechanical Stress: Towards Environmental and Security Monitoring
journal, May 2016

  • Cánovas, Rocío; Parrilla, Marc; Mercier, Patrick
  • Advanced Materials Technologies, Vol. 1, Issue 5
  • DOI: 10.1002/admt.201600061

Multifunctional wearable devices for diagnosis and therapy of movement disorders
journal, March 2014

  • Son, Donghee; Lee, Jongha; Qiao, Shutao
  • Nature Nanotechnology, Vol. 9, Issue 5
  • DOI: 10.1038/nnano.2014.38

Intrinsically stretchable and rechargeable batteries for self-powered stretchable electronics
journal, January 2013

  • Kettlgruber, Gerald; Kaltenbrunner, Martin; Siket, Christian M.
  • Journal of Materials Chemistry A, Vol. 1, Issue 18
  • DOI: 10.1039/c3ta00019b

Stretchable batteries with self-similar serpentine interconnects and integrated wireless recharging systems
journal, February 2013

  • Xu, Sheng; Zhang, Yihui; Cho, Jiung
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2553

Highly Flexible, Printed Alkaline Batteries Based on Mesh-Embedded Electrodes
journal, June 2011

  • Gaikwad, Abhinav M.; Whiting, Gregory L.; Steingart, Daniel A.
  • Advanced Materials, Vol. 23, Issue 29
  • DOI: 10.1002/adma.201100894

Fabrication of a High-Performance Flexible Silver-Zinc Wire Battery
journal, March 2016

  • Zamarayeva, Alla M.; Gaikwad, Abhinav M.; Deckman, Igal
  • Advanced Electronic Materials, Vol. 2, Issue 5
  • DOI: 10.1002/aelm.201500296

Stretchable Figures of Merit in Deformable Electronics
journal, November 2015


Food packaging
book, January 2018


Food Packaging
book, January 2019


Food Packaging
book, December 2000


Food Packaging Principles and Practice
book, September 2005


Food Packaging
book, December 2015


Works referencing / citing this record:

Wearable Supercapacitors Printed on Garments
journal, January 2018

  • Lee, Seong-Sun; Choi, Keun-Ho; Kim, Se-Hee
  • Advanced Functional Materials, Vol. 28, Issue 11
  • DOI: 10.1002/adfm.201705571

Realizing a Rechargeable High‐Performance Cu–Zn Battery by Adjusting the Solubility of Cu 2+
journal, September 2019

  • Zhu, Qiancheng; Cheng, Mingyu; Zhang, Bowen
  • Advanced Functional Materials, Vol. 29, Issue 50
  • DOI: 10.1002/adfm.201905979

The Road Towards Planar Microbatteries and Micro‐Supercapacitors: From 2D to 3D Device Geometries
journal, June 2019


Nanomaterial‐Enabled Flexible and Stretchable Sensing Systems: Processing, Integration, and Applications
journal, August 2019


Freestanding Functional Structures by Aerosol‐Jet Printing for Stretchable Electronics and Sensing Applications
journal, March 2019

  • Jing, Qingshen; Choi, Yeon Sik; Smith, Michael
  • Advanced Materials Technologies, Vol. 4, Issue 7
  • DOI: 10.1002/admt.201900048

Laser‐Induced Graphene Composites for Printed, Stretchable, and Wearable Electronics
journal, May 2019

  • Tehrani, Farshad; Beltrán‐Gastélum, Mara; Sheth, Karan
  • Advanced Materials Technologies, Vol. 4, Issue 8
  • DOI: 10.1002/admt.201900162

Multifunctional Ultrastretchable Printed Soft Electronic Devices for Wearable Applications
journal, November 2019

  • Tian, Bin; Liu, Qun; Luo, Chengsheng
  • Advanced Electronic Materials, Vol. 6, Issue 2
  • DOI: 10.1002/aelm.201900922

Recent Progress of the Solid-State Electrolytes for High-Energy Metal-Based Batteries
journal, January 2018


Highly Stretchable Separator Membrane for Deformable Energy-Storage Devices
journal, June 2018

  • Shin, Myoungsoo; Song, Woo-Jin; Son, Hye Bin
  • Advanced Energy Materials, Vol. 8, Issue 23
  • DOI: 10.1002/aenm.201801025

Recent Advances in Flexible Zinc-Based Rechargeable Batteries
journal, November 2018


Scaling Printable Zn–Ag 2 O Batteries for Integrated Electronics
journal, February 2019

  • Kumar, Rajan; Johnson, Kevin M.; Williams, Nicholas X.
  • Advanced Energy Materials, Vol. 9, Issue 13
  • DOI: 10.1002/aenm.201803645

Dendrite‐Free Flexible Fiber‐Shaped Zn Battery with Long Cycle Life in Water and Air
journal, September 2019

  • Guan, Qun; Li, Yongpeng; Bi, Xuanxuan
  • Advanced Energy Materials, Vol. 9, Issue 41
  • DOI: 10.1002/aenm.201901434

Rechargeable Soft‐Matter EGaIn‐MnO 2 Battery for Stretchable Electronics
journal, October 2019

  • Liu, Dongye; Su, Laisuo; Liao, Jiahe
  • Advanced Energy Materials, Vol. 9, Issue 46
  • DOI: 10.1002/aenm.201902798

Recent Advances in Polymer Electrolytes for Zinc Ion Batteries: Mechanisms, Properties, and Perspectives
journal, March 2020


Recent Progress in Stretchable Batteries for Wearable Electronics
journal, February 2019

  • Song, Woo‐Jin; Yoo, Seungmin; Song, Gyujin
  • Batteries & Supercaps, Vol. 2, Issue 3
  • DOI: 10.1002/batt.201800140

Large-Scale Fabrication of Flexible On-Chip Micro-Supercapacitors by a Mechanical Scribing Process
journal, May 2018


A High‐Rate and Long‐Life Aqueous Rechargeable Ammonium Zinc Hybrid Battery
journal, July 2019


Fingerprint-Inspired Flexible Tactile Sensor for Accurately Discerning Surface Texture
journal, March 2018


Highly Stable Battery Pack via Insulated, Reinforced, Buckling-Enabled Interconnect Array
journal, July 2018


Recent Advances in Stretchable Supercapacitors Enabled by Low-Dimensional Nanomaterials
journal, November 2018


Flexible Zn-Ion Batteries: Recent Progresses and Challenges
journal, January 2019


Advanced Wearable Microfluidic Sensors for Healthcare Monitoring
journal, October 2019


Integrating a Triboelectric Nanogenerator and a Zinc-Ion Battery on a Designed Flexible 3D Spacer Fabric
journal, July 2018


Recent progress on printable power supply devices and systems with nanomaterials
journal, May 2018


Mechanically robust stretchable organic optoelectronic devices built using a simple and universal stencil-pattern transferring technology
journal, July 2018


Fully laser-patterned stretchable microsupercapacitors integrated with soft electronic circuit components
journal, October 2018


Decoupling of mechanical properties and ionic conductivity in supramolecular lithium ion conductors
journal, November 2019


Wearable biosensors for healthcare monitoring
journal, February 2019

  • Kim, Jayoung; Campbell, Alan S.; de Ávila, Berta Esteban-Fernández
  • Nature Biotechnology, Vol. 37, Issue 4
  • DOI: 10.1038/s41587-019-0045-y

Flexible plastic, paper and textile lab-on-a chip platforms for electrochemical biosensing
journal, January 2018

  • Economou, Anastasios; Kokkinos, Christos; Prodromidis, Mamas
  • Lab on a Chip, Vol. 18, Issue 13
  • DOI: 10.1039/c8lc00025e

All-printed, low-cost, tunable sensing range strain sensors based on Ag nanodendrite conductive inks for wearable electronics
journal, January 2019

  • Tian, Bin; Yao, Weijing; Zeng, Pan
  • Journal of Materials Chemistry C, Vol. 7, Issue 4
  • DOI: 10.1039/c8tc04753g

Poly(ethylene glycol) nanocomposites of sub-nanometer metal oxide clusters for dynamic semi-solid proton conductive electrolytes
journal, January 2019

  • Zheng, Zhao; Zhou, Qianjie; Li, Mu
  • Chemical Science, Vol. 10, Issue 31
  • DOI: 10.1039/c9sc02779c

Stretchable electronics: functional materials, fabrication strategies and applications
journal, March 2019


Synthesis and kinetics of micron-scale silver(I) oxide via efficient chemical precipitation process
journal, September 2019


Supercapacitors on demand: all-printed energy storage devices with adaptable design
journal, February 2019

  • Brooke, Robert; Edberg, Jesper; Say, Mehmet Girayhan
  • Flexible and Printed Electronics, Vol. 4, Issue 1
  • DOI: 10.1088/2058-8585/aafc4f

Soft Material-Enabled, Flexible Hybrid Electronics for Medicine, Healthcare, and Human-Machine Interfaces
journal, January 2018

  • Herbert, Robert; Kim, Jong-Hoon; Kim, Yun
  • Materials, Vol. 11, Issue 2
  • DOI: 10.3390/ma11020187

Fabrication Approaches to Interconnect Based Devices for Stretchable Electronics: A Review
journal, March 2018


Freestanding Functional Structures by Aerosol-Jet Printing for Stretchable Electronics and Sensing Applications
text, January 2019

  • Jing, Qingshen; Choi, Ys; Smith, M.
  • Apollo - University of Cambridge Repository
  • DOI: 10.17863/cam.37342

Mechanically robust stretchable organic optoelectronic devices built using a simple and universal stencil-pattern transferring technology
journal, July 2018


Decoupling of mechanical properties and ionic conductivity in supramolecular lithium ion conductors
journal, November 2019


Soft Material-Enabled, Flexible Hybrid Electronics for Medicine, Healthcare, and Human-Machine Interfaces
journal, January 2018

  • Herbert, Robert; Kim, Jong-Hoon; Kim, Yun
  • Materials, Vol. 11, Issue 2
  • DOI: 10.3390/ma11020187

Fabrication Approaches to Interconnect Based Devices for Stretchable Electronics: A Review
journal, March 2018