Organic Dye Graphene Hybrid Structures with Spectral Color Selectivity
Abstract
This study characterizes a hybrid structure formed between graphene and organic dye molecules for use in photodetectors with spectral color selectivity. Rhodamine‐based organic dye molecules with red, green, or blue light absorption profiles are deposited onto a graphene surface by dip‐coating. UV–vis absorption spectroscopy, charge transport measurements, and density functional theory based calculations reveal that the photoresponses of the dye graphene hybrid films are governed by the light absorption of the dye molecules and also by the photo‐excited‐charge‐transfer‐induced photocurrent gain. The hybrid films respond only to photons with an energy exceeding the band gap of the immobilized dye. Dye‐Graphene charge transfer is affected by the distance and direction of the dipole moment between the two layers. The resulting hybrid films exhibit spectral color selectivities with responsivities of ≈10 3 A W −1 and specific detectivities of ≈10 10 Jones. This study demonstrates the successful operation of photodetectors with a full‐color optical bandwidth using hybrid graphene structures coated with a mixture of dyes. The strategy of building a simple hybrid photodetector can further offer many opportunities to be also tuned for other optical functionalities using a variety of commercially available dye molecules.
- Authors:
-
- SKKU Advanced Institute of Nanotechnology (SAINT) Sungkyunkwan University Suwon 440‐746 Korea
- Department of Materials Science and Engineering Northwestern University 2220 Campus Drive Evanston IL 60208 USA
- Department of Chemical Engineering Soongsil University Seoul 156‐743 Korea
- Division of Nano &, Energy Convergence Research Daegu Gyeongbuk Institute of Science and Technology (DGIST) Daegu 711‐873 Korea
- SKKU Advanced Institute of Nanotechnology (SAINT) Sungkyunkwan University Suwon 440‐746 Korea, School of Chemical Engineering Sungkyunkwan University Suwon 440‐746 Korea
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401456
- Grant/Contract Number:
- DE‐FG02‐07ER46433
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Name: Advanced Functional Materials Journal Volume: 26 Journal Issue: 36; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Gim, Yu Seong, Lee, Youngbin, Kim, Soo, Hao, Shiqiang, Kang, Moon Sung, Yoo, Won Jong, Kim, Hyunmin, Wolverton, Chris, and Cho, Jeong Ho. Organic Dye Graphene Hybrid Structures with Spectral Color Selectivity. Germany: N. p., 2016.
Web. doi:10.1002/adfm.201601200.
Gim, Yu Seong, Lee, Youngbin, Kim, Soo, Hao, Shiqiang, Kang, Moon Sung, Yoo, Won Jong, Kim, Hyunmin, Wolverton, Chris, & Cho, Jeong Ho. Organic Dye Graphene Hybrid Structures with Spectral Color Selectivity. Germany. https://doi.org/10.1002/adfm.201601200
Gim, Yu Seong, Lee, Youngbin, Kim, Soo, Hao, Shiqiang, Kang, Moon Sung, Yoo, Won Jong, Kim, Hyunmin, Wolverton, Chris, and Cho, Jeong Ho. Mon .
"Organic Dye Graphene Hybrid Structures with Spectral Color Selectivity". Germany. https://doi.org/10.1002/adfm.201601200.
@article{osti_1401456,
title = {Organic Dye Graphene Hybrid Structures with Spectral Color Selectivity},
author = {Gim, Yu Seong and Lee, Youngbin and Kim, Soo and Hao, Shiqiang and Kang, Moon Sung and Yoo, Won Jong and Kim, Hyunmin and Wolverton, Chris and Cho, Jeong Ho},
abstractNote = {This study characterizes a hybrid structure formed between graphene and organic dye molecules for use in photodetectors with spectral color selectivity. Rhodamine‐based organic dye molecules with red, green, or blue light absorption profiles are deposited onto a graphene surface by dip‐coating. UV–vis absorption spectroscopy, charge transport measurements, and density functional theory based calculations reveal that the photoresponses of the dye graphene hybrid films are governed by the light absorption of the dye molecules and also by the photo‐excited‐charge‐transfer‐induced photocurrent gain. The hybrid films respond only to photons with an energy exceeding the band gap of the immobilized dye. Dye‐Graphene charge transfer is affected by the distance and direction of the dipole moment between the two layers. The resulting hybrid films exhibit spectral color selectivities with responsivities of ≈10 3 A W −1 and specific detectivities of ≈10 10 Jones. This study demonstrates the successful operation of photodetectors with a full‐color optical bandwidth using hybrid graphene structures coated with a mixture of dyes. The strategy of building a simple hybrid photodetector can further offer many opportunities to be also tuned for other optical functionalities using a variety of commercially available dye molecules.},
doi = {10.1002/adfm.201601200},
journal = {Advanced Functional Materials},
number = 36,
volume = 26,
place = {Germany},
year = {Mon Jul 18 00:00:00 EDT 2016},
month = {Mon Jul 18 00:00:00 EDT 2016}
}
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Works referenced in this record:
An Improved Method for the Assembly of Amino-Terminated Monolayers on SiO 2 and the Vapor Deposition of Gold Layers
journal, June 1999
- Siqueira Petri, Denise F.; Wenz, Gerhard; Schunk, Peter
- Langmuir, Vol. 15, Issue 13
Dye-Sensitized MoS 2 Photodetector with Enhanced Spectral Photoresponse
journal, July 2014
- Yu, Seong Hun; Lee, Youngbin; Jang, Sung Kyu
- ACS Nano, Vol. 8, Issue 8
Epitaxial growth of single-domain graphene on hexagonal boron nitride
journal, July 2013
- Yang, Wei; Chen, Guorui; Shi, Zhiwen
- Nature Materials, Vol. 12, Issue 9
Studies on photodegradation of two commercial dyes in aqueous phase using different photocatalysts
journal, March 2007
- Kansal, S.; Singh, M.; Sud, D.
- Journal of Hazardous Materials, Vol. 141, Issue 3
Pressure-induced chemical enhancement in Raman scattering from graphene–Rhodamine 6G–graphene sandwich structures
journal, August 2015
- Lee, Youngbin; Kim, Hyunmin; Lee, Jae-Bok
- Carbon, Vol. 89
The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper
journal, October 2013
- Hao, Y.; Bharathi, M. S.; Wang, L.
- Science, Vol. 342, Issue 6159
Fluorescence quantum yields of some rhodamine dyes
journal, December 1982
- Kubin, R. F.; Fletcher, A. N.
- Journal of Luminescence, Vol. 27, Issue 4
Biologically inspired graphene-chlorophyll phototransistors with high gain
journal, November 2013
- Chen, Shao-Yu; Lu, Yi-Ying; Shih, Fu-Yu
- Carbon, Vol. 63
Wafer-Scale Growth of Single-Crystal Monolayer Graphene on Reusable Hydrogen-Terminated Germanium
journal, April 2014
- Lee, J.-H.; Lee, E. K.; Joo, W.-J.
- Science, Vol. 344, Issue 6181, p. 286-289
Graphene–MoS2 hybrid structures for multifunctional photoresponsive memory devices
journal, October 2013
- Roy, Kallol; Padmanabhan, Medini; Goswami, Srijit
- Nature Nanotechnology, Vol. 8, Issue 11
Graphene and Graphene-like Two-Dimensional Materials in Photodetection: Mechanisms and Methodology
journal, April 2014
- Sun, Zhenhua; Chang, Haixin
- ACS Nano, Vol. 8, Issue 5
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Molecular Engineering of Organic Dyes for Improved Recombination Lifetime in Solid-State Dye-Sensitized Solar Cells
journal, April 2013
- Nguyen, William H.; Bailie, Colin D.; Burschka, Julian
- Chemistry of Materials, Vol. 25, Issue 9
High-Detectivity Polymer Photodetectors with Spectral Response from 300 nm to 1450 nm
journal, August 2009
- Gong, X.; Tong, M.; Xia, Y.
- Science, Vol. 325, Issue 5948
Hybrid graphene–quantum dot phototransistors with ultrahigh gain
journal, May 2012
- Konstantatos, Gerasimos; Badioli, Michela; Gaudreau, Louis
- Nature Nanotechnology, Vol. 7, Issue 6
General observation of n-type field-effect behaviour in organic semiconductors
journal, March 2005
- Chua, Lay-Lay; Zaumseil, Jana; Chang, Jui-Fen
- Nature, Vol. 434, Issue 7030
Formation and Dissociation of Rhodamine 800 Dimers in Water: Steady-State and Ultrafast Spectroscopic Study
journal, March 2006
- Sekiguchi, Kentaro; Yamaguchi, Shoichi; Tahara, Tahei
- The Journal of Physical Chemistry A, Vol. 110, Issue 8
Excitation transfer mechanism along the visible to the Near-IR in rhodamine J-heteroaggregates
journal, January 2010
- Sánchez-Valencia, Juan R.; Toudert, Johann; González-García, Lola
- Chemical Communications, Vol. 46, Issue 24
Vibrational interaction between molecules adsorbed on a metal surface: The dipole-dipole interaction
journal, December 1981
- Persson, B. N. J.; Ryberg, R.
- Physical Review B, Vol. 24, Issue 12
Dramatically Enhanced Photoresponse of Reduced Graphene Oxide with Linker-Free Anchored CdSe Nanoparticles
journal, May 2010
- Lin, Yue; Zhang, Kun; Chen, Wufeng
- ACS Nano, Vol. 4, Issue 6
Graphene: Electronic and Photonic Properties and Devices
journal, November 2010
- Avouris, Phaedon
- Nano Letters, Vol. 10, Issue 11, p. 4285-4294
Understanding Charge Transfer at PbS-Decorated Graphene Surfaces toward a Tunable Photosensor
journal, April 2012
- Zhang, Dayong; Gan, Lin; Cao, Yang
- Advanced Materials, Vol. 24, Issue 20
Graphene-Ruthenium Complex Hybrid Photodetectors with Ultrahigh Photoresponsivity
journal, May 2014
- Liu, Xien; Lee, Eun Kwang; Oh, Joon Hak
- Small, Vol. 10, Issue 18
Ab initiomolecular dynamics for liquid metals
journal, January 1993
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 47, Issue 1, p. 558-561
Graphene photonics and optoelectronics
journal, August 2010
- Bonaccorso, F.; Sun, Z.; Hasan, T.
- Nature Photonics, Vol. 4, Issue 9
A graphene-based broadband optical modulator
journal, May 2011
- Liu, Ming; Yin, Xiaobo; Ulin-Avila, Erick
- Nature, Vol. 474, Issue 7349
Graphene-based hybrid materials and devices for biosensing
journal, November 2011
- Artiles, Mayra S.; Rout, Chandra Sekhar; Fisher, Timothy S.
- Advanced Drug Delivery Reviews, Vol. 63, Issue 14-15
Visible semiconductor laser fluorometry
journal, October 1989
- Imasaka, Totaro.; Tsukamoto, Atsushi.; Ishibashi, Nobuhiko.
- Analytical Chemistry, Vol. 61, Issue 20
Fluorescence Properties of Rhodamine 800 in Whole Blood and Plasma
journal, March 2000
- Abugo, Omoefe O.; Nair, Rajesh; Lakowicz, Joseph R.
- Analytical Biochemistry, Vol. 279, Issue 2
Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells
journal, January 2008
- Wang, Xuan; Zhi, Linjie; Müllen, Klaus
- Nano Letters, Vol. 8, Issue 1, p. 323-327
Inverse Transfer Method Using Polymers with Various Functional Groups for Controllable Graphene Doping
journal, July 2014
- Lee, Seong Kyu; Yang, Jae Won; Kim, Hyun Ho
- ACS Nano, Vol. 8, Issue 8
Visible Photoresponse of Single-Layer Graphene Decorated with TiO 2 Nanoparticles
journal, February 2013
- Zheng, Kaihong; Meng, Fanben; Jiang, Lin
- Small, Vol. 9, Issue 12
Growth of Ultrasmooth Octadecyltrichlorosilane Self-Assembled Monolayers on SiO 2
journal, February 2003
- Wang, Yuliang; Lieberman, Marya
- Langmuir, Vol. 19, Issue 4
An Efficient Organic-Dye-Sensitized Solar Cell with in situ Polymerized Poly(3,4-ethylenedioxythiophene) as a Hole-Transporting Material
journal, May 2010
- Liu, Xizhe; Zhang, Wei; Uchida, Satoshi
- Advanced Materials, Vol. 22, Issue 20
Graphene photodetectors for high-speed optical communications
journal, March 2010
- Mueller, Thomas; Xia, Fengnian; Avouris, Phaedon
- Nature Photonics, Vol. 4, Issue 5
Can Graphene be used as a Substrate for Raman Enhancement?
journal, February 2010
- Ling, Xi; Xie, Liming; Fang, Yuan
- Nano Letters, Vol. 10, Issue 2
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Wavelength-Selective Dual p- and n-Type Carrier Transport of an Organic/Graphene/Inorganic Heterostructure
journal, November 2014
- Ho, Po-Hsun; Li, Shao-Sian; Liou, Yi-Ting
- Advanced Materials, Vol. 27, Issue 2
Systematic Doping Control of CVD Graphene Transistors with Functionalized Aromatic Self-Assembled Monolayers
journal, March 2014
- Cernetic, Nathan; Wu, Sanfeng; Davies, Joshua A.
- Advanced Functional Materials, Vol. 24, Issue 22
Infrared Photodetectors Based on CVD-Grown Graphene and PbS Quantum Dots with Ultrahigh Responsivity
journal, August 2012
- Sun, Zhenhua; Liu, Zhike; Li, Jinhua
- Advanced Materials, Vol. 24, Issue 43
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Ligand-Induced Control of Photoconductive Gain and Doping in a Hybrid Graphene-Quantum Dot Transistor
journal, June 2015
- Turyanska, Lyudmila; Makarovsky, Oleg; Svatek, Simon A.
- Advanced Electronic Materials, Vol. 1, Issue 7
Water on graphene: Hydrophobicity and dipole moment using density functional theory
journal, June 2009
- Leenaerts, O.; Partoens, B.; Peeters, F. M.
- Physical Review B, Vol. 79, Issue 23
Synthesis and applications of Rhodamine derivatives as fluorescent probes
journal, January 2009
- Beija, Mariana; Afonso, Carlos A. M.; Martinho, José M. G.
- Chemical Society Reviews, Vol. 38, Issue 8
Infrared Photodetectors Based on Reduced Graphene Oxide and Graphene Nanoribbons
journal, July 2011
- Chitara, Basant; Panchakarla, L. S.; Krupanidhi, S. B.
- Advanced Materials, Vol. 23, Issue 45
Photoinduced doping in heterostructures of graphene and boron nitride
journal, April 2014
- Ju, L.; Velasco, J.; Huang, E.
- Nature Nanotechnology, Vol. 9, Issue 5
High-Performance Perovskite-Graphene Hybrid Photodetector
journal, October 2014
- Lee, Youngbin; Kwon, Jeong; Hwang, Euyheon
- Advanced Materials, Vol. 27, Issue 1
Photocurrent Imaging and Efficient Photon Detection in a Graphene Transistor
journal, March 2009
- Xia, Fengnian; Mueller, Thomas; Golizadeh-Mojarad, Roksana
- Nano Letters, Vol. 9, Issue 3
Hybrid structures of organic dye and graphene for ultrahigh gain photodetectors
journal, July 2015
- Lee, Youngbin; Yu, Seong Hun; Jeon, Jiwon
- Carbon, Vol. 88
Photoconductor gain mechanisms in GaN ultraviolet detectors
journal, August 1997
- Muñoz, E.; Monroy, E.; Garrido, J. A.
- Applied Physics Letters, Vol. 71, Issue 7
Plasmon resonance enhanced multicolour photodetection by graphene
journal, September 2011
- Liu, Yuan; Cheng, Rui; Liao, Lei
- Nature Communications, Vol. 2, Issue 1
Graphene as a Substrate To Suppress Fluorescence in Resonance Raman Spectroscopy
journal, July 2009
- Xie, Liming; Ling, Xi; Fang, Yuan
- Journal of the American Chemical Society, Vol. 131, Issue 29
Strong plasmonic enhancement of photovoltage in graphene
journal, August 2011
- Echtermeyer, T. J.; Britnell, L.; Jasnos, P. K.
- Nature Communications, Vol. 2, Issue 1
Microcavity-Integrated Graphene Photodetector
journal, May 2012
- Furchi, Marco; Urich, Alexander; Pospischil, Andreas
- Nano Letters, Vol. 12, Issue 6
Broadband high photoresponse from pure monolayer graphene photodetector
journal, May 2013
- Zhang, By Yongzhe; Liu, Tao; Meng, Bo
- Nature Communications, Vol. 4, Issue 1
Graphene photodetectors with ultra-broadband and high responsivity at room temperature
journal, March 2014
- Liu, Chang-Hua; Chang, You-Chia; Norris, Theodore B.
- Nature Nanotechnology, Vol. 9, Issue 4