Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction
Abstract
Favoring the CO2 reduction reaction (CO2RR) over the hydrogen evolution reaction and controlling the selectivity towards multicarbon products are currently major scientific challenges in sustainable energy research. It is known that the morphology of the catalyst can modulate catalytic activity and selectivity, yet this remains a relatively underexplored area in electrochemical CO2 reduction. In this study, we exploit the material tunability afforded by colloidal chemistry to establish unambiguous structure/property relations between Cu nanocrystals and their behavior as electrocatalysts for CO2 reduction. Our study reveals a non-monotonic size-dependence of the selectivity in cube-shaped copper nanocrystals. Among 24 nm, 44 nm and 63 nm cubes tested, the cubes with 44 nm edge length exhibited the highest selectivity towards CO2RR (80 %) and faradaic efficiency for ethylene (41 %). Finally, statistical analysis of the surface atom density suggests the key role played by edge sites in CO2RR.
- Authors:
-
[1]
- École Polytechnique Fédérale de Lausanne, Sion (Switzerland)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1530238
- Alternate Identifier(s):
- OSTI ID: 1401425
- Grant/Contract Number:
- AC02-05CH11231; SC0004993
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 55; Journal Issue: 19; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; colloidal chemistry; electrochemical CO2 reduction; nanocrystals; nanocubes; selectivity
Citation Formats
Loiudice, Anna, Lobaccaro, Peter, Kamali, Esmail A., Thao, Timothy, Huang, Brandon H., Ager, Joel W., and Buonsanti, Raffaella. Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction. United States: N. p., 2016.
Web. doi:10.1002/anie.201601582.
Loiudice, Anna, Lobaccaro, Peter, Kamali, Esmail A., Thao, Timothy, Huang, Brandon H., Ager, Joel W., & Buonsanti, Raffaella. Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction. United States. https://doi.org/10.1002/anie.201601582
Loiudice, Anna, Lobaccaro, Peter, Kamali, Esmail A., Thao, Timothy, Huang, Brandon H., Ager, Joel W., and Buonsanti, Raffaella. Tue .
"Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction". United States. https://doi.org/10.1002/anie.201601582. https://www.osti.gov/servlets/purl/1530238.
@article{osti_1530238,
title = {Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction},
author = {Loiudice, Anna and Lobaccaro, Peter and Kamali, Esmail A. and Thao, Timothy and Huang, Brandon H. and Ager, Joel W. and Buonsanti, Raffaella},
abstractNote = {Favoring the CO2 reduction reaction (CO2RR) over the hydrogen evolution reaction and controlling the selectivity towards multicarbon products are currently major scientific challenges in sustainable energy research. It is known that the morphology of the catalyst can modulate catalytic activity and selectivity, yet this remains a relatively underexplored area in electrochemical CO2 reduction. In this study, we exploit the material tunability afforded by colloidal chemistry to establish unambiguous structure/property relations between Cu nanocrystals and their behavior as electrocatalysts for CO2 reduction. Our study reveals a non-monotonic size-dependence of the selectivity in cube-shaped copper nanocrystals. Among 24 nm, 44 nm and 63 nm cubes tested, the cubes with 44 nm edge length exhibited the highest selectivity towards CO2RR (80 %) and faradaic efficiency for ethylene (41 %). Finally, statistical analysis of the surface atom density suggests the key role played by edge sites in CO2RR.},
doi = {10.1002/anie.201601582},
journal = {Angewandte Chemie (International Edition)},
number = 19,
volume = 55,
place = {United States},
year = {Tue Apr 05 00:00:00 EDT 2016},
month = {Tue Apr 05 00:00:00 EDT 2016}
}
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Figure-1: (A-C) TEM images of Cu cubes with an average edge length of 24, 44, 63 nm respectively; (D-E) TEM images of Cu spheres with an average diameter of 7.5 and 27 nm, respectively. Scale bar 50 nm. (F) Typical XRD patterns of the Cu spheres (black line) and Cumore »
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