The Effect of Relative Density on the Mechanical Properties of Hot‐Pressed Cubic Li 7 La 3 Zr 2 O 12

Kim, Yunsung; Jo, Hyungyung; Allen, Jan L.; Choe, Heeman; Wolfenstine, Jeff; Sakamoto, Jeff; Pharr, ed., G.

doi:10.1111/jace.14084

Title: The Effect of Relative Density on the Mechanical Properties of Hot‐Pressed Cubic Li ₇ La ₃ Zr ₂ O ₁₂

Authors:

Kim, Yunsung ^[1]; Jo, Hyungyung ^[2]; Allen, Jan L. ^[3]; Choe, Heeman ^[2]; Wolfenstine, Jeff ^[3]; Sakamoto, Jeff ^[4]; Pharr, ed., G.

Department of Chemical Engineering and Materials Science Michigan State University East Lansing Michigan 48824‐1226
Department of Advanced Materials Engineering Kookmin University Seoul 136‐702 Korea
Army Research Laboratory RDRL‐SED‐C 2800 Powder Mill Road Adelphi Maryland 20783
Department of Mechanical Engineering University of Michigan Ann Arbor Michigan 48109‐2125

Publication Date:: Mon Jan 18 00:00:00 EST 2016

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1401415

Grant/Contract Number:: AR0000399; EE00006821

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of the American Ceramic Society

Additional Journal Information:: Journal Name: Journal of the American Ceramic Society Journal Volume: 99 Journal Issue: 4; Journal ID: ISSN 0002-7820

Publisher:: American Ceramic Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Kim, Yunsung, Jo, Hyungyung, Allen, Jan L., Choe, Heeman, Wolfenstine, Jeff, Sakamoto, Jeff, and Pharr, ed., G. The Effect of Relative Density on the Mechanical Properties of Hot‐Pressed Cubic Li 7 La 3 Zr 2 O 12.  United States: N. p., 2016. 
Web.  doi:10.1111/jace.14084.

Copy to clipboard


                    Kim, Yunsung, Jo, Hyungyung, Allen, Jan L., Choe, Heeman, Wolfenstine, Jeff, Sakamoto, Jeff, & Pharr, ed., G. The Effect of Relative Density on the Mechanical Properties of Hot‐Pressed Cubic Li 7 La 3 Zr 2 O 12.  United States.  https://doi.org/10.1111/jace.14084

Copy to clipboard


                    Kim, Yunsung, Jo, Hyungyung, Allen, Jan L., Choe, Heeman, Wolfenstine, Jeff, Sakamoto, Jeff, and Pharr, ed., G. Mon .  
"The Effect of Relative Density on the Mechanical Properties of Hot‐Pressed Cubic Li 7 La 3 Zr 2 O 12".  United States.  https://doi.org/10.1111/jace.14084.

Copy to clipboard


                    
@article{osti_1401415,

  title        = {The Effect of Relative Density on the Mechanical Properties of Hot‐Pressed Cubic Li 7 La 3 Zr 2 O 12},

  author       = {Kim, Yunsung and Jo, Hyungyung and Allen, Jan L. and Choe, Heeman and Wolfenstine, Jeff and Sakamoto, Jeff and Pharr, ed., G.},

  abstractNote = {},

  doi          = {10.1111/jace.14084},

  journal      = {Journal of the American Ceramic Society},

  number       = 4,

  volume       = 99,

  place        = {United States},

  year         = {Mon Jan 18 00:00:00 EST 2016},

  month        = {Mon Jan 18 00:00:00 EST 2016}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1111/jace.14084

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 116 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

A Critical Review of Li∕Air Batteries
journal, January 2012

Christensen, Jake; Albertus, Paul; Sanchez-Carrera, Roel S.
Journal of The Electrochemical Society, Vol. 159, Issue 2, p. R1-R30
DOI: 10.1149/2.086202jes

Optimizing Li+ conductivity in a garnet framework
journal, January 2012

Li, Yutao; Han, Jian- Tao; Wang, Chang- An
Journal of Materials Chemistry, Vol. 22, Issue 30
DOI: 10.1039/c2jm31413d

Effects of penta- and trivalent dopants on structure and conductivity of Li7La3Zr2O12
journal, June 2015

Gu, W.; Ezbiri, M.; Prasada Rao, R.
Solid State Ionics, Vol. 274
DOI: 10.1016/j.ssi.2015.03.019

Li7La3Zr2O12 electrolyte stability in air and fabrication of a Li/Li7La3Zr2O12/Cu0.1V2O5 solid-state battery
journal, October 2013

Jin, Ying; McGinn, Paul J.
Journal of Power Sources, Vol. 239
DOI: 10.1016/j.jpowsour.2013.03.155

Systematic hardness measurements on some rare earth garnet crystal
journal, October 2001

Sirdeshmukh, D. B.; Sirdeshmukh, L.; Subhadra, K. G.
Bulletin of Materials Science, Vol. 24, Issue 5
DOI: 10.1007/BF02706717

Effect of sintering temperature on structure and ionic conductivity of Li7−xLa3Zr2O12−0.5x (x=0.5~0.7) ceramics
journal, December 2011

Huang, Mian; Liu, Ting; Deng, Yufeng
Solid State Ionics, Vol. 204-205
DOI: 10.1016/j.ssi.2011.10.003

Nebulized spray pyrolysis of Al-doped Li7La3Zr2O12 solid electrolyte for battery applications
journal, October 2014

Djenadic, Ruzica; Botros, Miriam; Benel, Cahit
Solid State Ionics, Vol. 263
DOI: 10.1016/j.ssi.2014.05.007

Effect of Grain Size and Poling on the Fracture Mode of Lead Zirconate Titanate Ceramics
journal, January 1990

Kim, Sang-Beom; Kim, Doh-Yeon; Kim, Jeong-Joo
Journal of the American Ceramic Society, Vol. 73, Issue 1
DOI: 10.1111/j.1151-2916.1990.tb05113.x

First-principles density functional calculation of electrochemical stability of fast Li ion conducting garnet-type oxides
journal, January 2012

Nakayama, Masanobu; Kotobuki, Masashi; Munakata, Hirokazu
Physical Chemistry Chemical Physics, Vol. 14, Issue 28
DOI: 10.1039/c2cp40634a

Effects of Li source on microstructure and ionic conductivity of Al-contained Li6.75La3Zr1.75Ta0.25O12 ceramics
journal, February 2015

Ren, Yaoyu; Deng, Hui; Chen, Rujun
Journal of the European Ceramic Society, Vol. 35, Issue 2
DOI: 10.1016/j.jeurceramsoc.2014.09.007

Grain-Size Dependence of Fracture Energy in Ceramics: I, Experiment
journal, June 1981

Rice, R. W.; Freiman, S. W.; Becher, P. F.
Journal of the American Ceramic Society, Vol. 64, Issue 6
DOI: 10.1111/j.1151-2916.1981.tb10300.x

Brittle Fracture and Toughening Mechanisms in Ceramics
journal, August 1984

Wiederhorn, S. M.
Annual Review of Materials Science, Vol. 14, Issue 1
DOI: 10.1146/annurev.ms.14.080184.002105

Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet
journal, July 2012

Ni, Jennifer E.; Case, Eldon D.; Sakamoto, Jeffrey S.
Journal of Materials Science, Vol. 47, Issue 23, p. 7978-7985
DOI: 10.1007/s10853-012-6687-5

A Critical Evaluation of Indentation Techniques for Measuring Fracture Toughness: I, Direct Crack Measurements
journal, September 1981

Anstis, G. R.; Chantikul, P.; Lawn, B. R.
Journal of the American Ceramic Society, Vol. 64, Issue 9
DOI: 10.1111/j.1151-2916.1981.tb10320.x

Crack deflection processes—II. Experiment
journal, April 1983

Faber, K. T.; Evans, A. G.
Acta Metallurgica, Vol. 31, Issue 4
DOI: 10.1016/0001-6160(83)90047-0

Effect of calcining and Al doping on structure and conductivity of Li 7 La 3 Zr 2 O 12
journal, November 2014

Chen, Ru-Jun; Huang, Mian; Huang, Wen-Ze
Solid State Ionics, Vol. 265
DOI: 10.1016/j.ssi.2014.07.004

Hydrogen Softening in the Thin Plate of Microcrystalline 316L Stainless Steel
journal, June 2013

Kim, Yunsung; Shin, Dongjun; Kim, Youngsuk
steel research international, Vol. 84, Issue 8
DOI: 10.1002/srin.201300082

Crack Deflection as a Toughening Mechanism in SiC-Whisker-Reinforced MoSi2
journal, April 1987

Carter, David H.; Hurley, George F.
Journal of the American Ceramic Society, Vol. 70, Issue 4
DOI: 10.1111/j.1151-2916.1987.tb04992.x

Effect of substitution (Ta, Al, Ga) on the conductivity of Li₇La₃Zr₂O₁₂
journal, May 2012

Allen, J. L.; Wolfenstine, J.; Rangasamy, E.
Journal of Power Sources, Vol. 206, p. 315-319
DOI: 10.1016/j.jpowsour.2012.01.131

High lithium ionic conductivity in the garnet-type oxide Li_7−XLa₃(Zr_2−X, Nb_X)O₁₂ (X=0–2)
journal, March 2011

Ohta, Shingo; Kobayashi, Tetsuro; Asaoka, Takahiko
Journal of Power Sources, Vol. 196, Issue 6, p. 3342-3345
DOI: 10.1016/j.jpowsour.2010.11.089

An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments
journal, June 1992

Oliver, W. C.; Pharr, G. M.
Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583
DOI: 10.1557/JMR.1992.1564

Crack deflection processes—I. Theory
journal, April 1983

Faber, K. T.; Evans, A. G.
Acta Metallurgica, Vol. 31, Issue 4
DOI: 10.1016/0001-6160(83)90046-9

Ceramic and polymeric solid electrolytes for lithium-ion batteries
journal, August 2010

Fergus, Jeffrey W.
Journal of Power Sources, Vol. 195, Issue 15, p. 4554-4569
DOI: 10.1016/j.jpowsour.2010.01.076

Effect of Sintering Atmosphere on Densification of MgO-Doped Al2O3
journal, August 1988

Paek, Y. -K.; Eun, K. -Y.; Kang, S. -J. L.
Journal of the American Ceramic Society, Vol. 71, Issue 8
DOI: 10.1111/j.1151-2916.1988.tb06398.x

Inorganic solid Li ion conductors: An overview
journal, June 2009

Knauth, Philippe
Solid State Ionics, Vol. 180, Issue 14-16, p. 911-916
DOI: 10.1016/j.ssi.2009.03.022

Sintering Alumina: Effect of Atmospheres
journal, March 1962

Coble, R. L.
Journal of the American Ceramic Society, Vol. 45, Issue 3
DOI: 10.1111/j.1151-2916.1962.tb11099.x

Grain size and porosity dependence of ceramic fracture energy and toughness at 22 °C
journal, April 1996

Rice, R. W.
Journal of Materials Science, Vol. 31, Issue 8
DOI: 10.1007/BF00356616

NMR study of Li distribution in Li _7−x H _x La ₃ Zr ₂ O ₁₂ garnets
journal, January 2015

Larraz, G.; Orera, A.; Sanz, J.
Journal of Materials Chemistry A, Vol. 3, Issue 10
DOI: 10.1039/C4TA04570J

A preliminary investigation of fracture toughness of Li7La3Zr2O12 and its comparison to other solid Li-ionconductors
journal, April 2013

Wolfenstine, Jeff; Jo, Hyungyung; Cho, Yong-Hun
Materials Letters, Vol. 96
DOI: 10.1016/j.matlet.2013.01.021

Resolving the Grain Boundary and Lattice Impedance of Hot-Pressed Li ₇ La ₃ Zr ₂ O ₁₂ Garnet Electrolytes
journal, July 2013

Tenhaeff, Wyatt E.; Rangasamy, Ezhiyl; Wang, Yangyang
ChemElectroChem, Vol. 1, Issue 2
DOI: 10.1002/celc.201300022

Fabrication of all-solid-state lithium battery with lithium metal anode using Al2O3-added Li7La3Zr2O12 solid electrolyte
journal, September 2011

Kotobuki, Masashi; Kanamura, Kiyoshi; Sato, Yosuke
Journal of Power Sources, Vol. 196, Issue 18
DOI: 10.1016/j.jpowsour.2011.04.047

Transfomation toughening of ??-alumina by incorporation of zirconia
journal, January 1983

Viswanathan, L.; Ikuma, Y.; Virkar, A. V.
Journal of Materials Science, Vol. 18, Issue 1
DOI: 10.1007/BF00543815

Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries
journal, March 2014

Baek, Seung-Wook; Lee, Jae-Myung; Kim, Tae Young
Journal of Power Sources, Vol. 249
DOI: 10.1016/j.jpowsour.2013.10.089

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li₇La₃Zr₂O₁₂
journal, January 2012

Rangasamy, Ezhiyl; Wolfenstine, Jeff; Sakamoto, Jeffrey
Solid State Ionics, Vol. 206, p. 28-32
DOI: 10.1016/j.ssi.2011.10.022

Lithium metal anodes for rechargeable batteries
journal, January 2014

Xu, Wu; Wang, Jiulin; Ding, Fei
Energy Environ. Sci., Vol. 7, Issue 2
DOI: 10.1039/C3EE40795K

Densification and ionic-conduction improvement of lithium garnet solid electrolytes by flowing oxygen sintering
journal, February 2014

Li, Yiqiu; Wang, Zheng; Li, Chilin
Journal of Power Sources, Vol. 248
DOI: 10.1016/j.jpowsour.2013.09.140

Synthesis and properties of Al-free Li7−xLa3Zr2−xTaxO12 garnet related oxides
journal, September 2014

Inada, Ryoji; Kusakabe, Koji; Tanaka, Takayuki
Solid State Ionics, Vol. 262
DOI: 10.1016/j.ssi.2013.09.008

Microstructure and Li-Ion Conductivity of Hot-Pressed Cubic Li ₇ La ₃ Zr ₂ O ₁₂
journal, January 2015

David, Isabel N.; Thompson, Travis; Wolfenstine, Jeff
Journal of the American Ceramic Society, Vol. 98, Issue 4
DOI: 10.1111/jace.13455

Effect of microstructure and surface impurity segregation on the electrical and electrochemical properties of dense Al-substituted Li ₇ La ₃ Zr ₂ O ₁₂
journal, January 2014

Cheng, Lei; Park, Joong Sun; Hou, Huaming
J. Mater. Chem. A, Vol. 2, Issue 1
DOI: 10.1039/C3TA13999A

Review Lecture: Fast Ionic Conduction in Solids
journal, June 1984

Goodenough, J. B.
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 393, Issue 1805
DOI: 10.1098/rspa.1984.0055

Lithium Lanthanum Titanates: A Review
journal, October 2003

Stramare, S.; Thangadurai, V.; Weppner, W.
Chemistry of Materials, Vol. 15, Issue 21
DOI: 10.1021/cm0300516

Intergranular Crack-Deflection Toughening in Silicon Carbide
journal, June 1983

Faber, K. T.; Evans, Anthony G.
Journal of the American Ceramic Society, Vol. 66, Issue 6
DOI: 10.1111/j.1151-2916.1983.tb10084.x

Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂
journal, October 2007

Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781
DOI: 10.1002/anie.200701144

Similar Records in DOE PAGES and OSTI.GOV collections:

Characterizing the Li–Li₇La₃Zr₂O₁₂ interface stability and kinetics as a function of temperature and current density

Journal Article Sharafi, Asma ; Meyer, Harry M. ; Nanda, Jagjit ; ... - Journal of Power Sources

The stability and kinetics of the Li–Li₇La₃Zr₂O₁₂ (LLZO) interface were characterized as a function of temperature and current density. Polycrystalline LLZO was densified using a rapid hot-pressing technique achieving 97 ± 1% relative density, and <10% grain boundary resistance; effectively consisting of an ensemble of single LLZO crystals. It was determined that by heating to 175 °C, the room temperature Li-LLZO interface resistance decreases dramatically from 5822 (as-assembled) to 514 Ω cm²; a > 10-fold decrease. In characterizing the maximum sustainable current density (or critical current density – CCD) of the Li-LLZO interface, several signs of degradation were observed. Inmore »« less
Cited by 357
https://doi.org/10.1016/j.jpowsour.2015.10.053

Full Text Available
Resolving the grain boundary and lattice impedance of hot-pressed Li₇La₃Zr₂O₁₂ garnet electrolytes

Journal Article Tenhaeff, Wyatt E. ; Wang, Yangyang ; Sokolov, Alexei P. ; ... - ChemElectroChem

Here, the cubic-stabilized garnet solid electrolyte with a nominal composition of Li_6.28Al_0.24La₃Zr₂O₁₂ is thoroughly characterized by impedance spectroscopy. By varying the frequency of the applied AC signal over 11 orders of magnitude for characterizations from –100 to +60 °C, the relative contributions of grain and grain boundary conduction are unambiguously resolved.
Cited by 84
https://doi.org/10.1002/celc.201300022

Full Text Available
Competing Effects in the Hydration Mechanism of a Garnet-Type Li ₇ La ₃ Zr ₂ O ₁₂ Electrolyte

Journal Article Arinicheva, Yulia ; Guo, Xin ; Gerhards, Marie-Theres ; ... - Chemistry of Materials

Not provided.
https://doi.org/10.1021/acs.chemmater.1c02581
Structural and Computational Assessment of the Influence of Wet-Chemical Post-Processing of the Al-Substituted Cubic Li₇La₃Zr₂O₁₂

Journal Article Kun, Robert ; Langer, Frederieke ; Delle Piane, Massimo ; ... - ACS Applied Materials and Interfaces

Li₇La₃Zr₂O₁₂ (LLZO) and related compounds are considered as promising candidates for future all-solid-state Li-ion battery applications. Still, the processing of those materials into thin membranes with the right stoichiometry and crystal structure is difficult and laborious. The sensitivity of the Li-ion conductive garnets against moisture and the associated Li⁺/H⁺ cation exchange makes their processing even more difficult. Formulation of suitable polymer/ceramic hybrid solid state electrolytes could be a prosperous way to reach the future large scale production of solid state Li-ion batteries. In fact, solvent mediated and/or slurry based wet-processing of the LLZO, e.g., tape-casting, could result in irreversible Li-ionmore »« less
Cited by 22
https://doi.org/10.1021/acsami.8b09789

Full Text Available
Tetragonal vs. cubic phase stability in Al – free Ta doped Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO)

Journal Article Thompson, Travis ; Wolfenstine, Jeff ; Allen, Jan L. ; ... - Journal of Materials Chemistry. A

X-ray and neutron diffraction, Raman spectroscopy, complex impedance spectroscopy and electron microscopy were used to characterize the tetragonalvs.cubic phase stability in superionic conducting garnet-oxide electrolyte.
https://doi.org/10.1039/c4ta02099e

Similar Records

Title: The Effect of Relative Density on the Mechanical Properties of Hot‐Pressed Cubic Li 7 La 3 Zr 2 O 12

Citation Formats

A Critical Review of Li∕Air Batteries journal, January 2012

Optimizing Li+ conductivity in a garnet framework journal, January 2012

Effects of penta- and trivalent dopants on structure and conductivity of Li7La3Zr2O12 journal, June 2015

Li7La3Zr2O12 electrolyte stability in air and fabrication of a Li/Li7La3Zr2O12/Cu0.1V2O5 solid-state battery journal, October 2013

Systematic hardness measurements on some rare earth garnet crystal journal, October 2001

Effect of sintering temperature on structure and ionic conductivity of Li7−xLa3Zr2O12−0.5x (x=0.5~0.7) ceramics journal, December 2011

Nebulized spray pyrolysis of Al-doped Li7La3Zr2O12 solid electrolyte for battery applications journal, October 2014

Effect of Grain Size and Poling on the Fracture Mode of Lead Zirconate Titanate Ceramics journal, January 1990

First-principles density functional calculation of electrochemical stability of fast Li ion conducting garnet-type oxides journal, January 2012

Effects of Li source on microstructure and ionic conductivity of Al-contained Li6.75La3Zr1.75Ta0.25O12 ceramics journal, February 2015

Grain-Size Dependence of Fracture Energy in Ceramics: I, Experiment journal, June 1981

Brittle Fracture and Toughening Mechanisms in Ceramics journal, August 1984

Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet journal, July 2012

A Critical Evaluation of Indentation Techniques for Measuring Fracture Toughness: I, Direct Crack Measurements journal, September 1981

Crack deflection processes—II. Experiment journal, April 1983

Effect of calcining and Al doping on structure and conductivity of Li 7 La 3 Zr 2 O 12 journal, November 2014

Hydrogen Softening in the Thin Plate of Microcrystalline 316L Stainless Steel journal, June 2013

Crack Deflection as a Toughening Mechanism in SiC-Whisker-Reinforced MoSi2 journal, April 1987

Effect of substitution (Ta, Al, Ga) on the conductivity of Li7La3Zr2O12 journal, May 2012

High lithium ionic conductivity in the garnet-type oxide Li7−XLa3(Zr2−X, NbX)O12 (X=0–2) journal, March 2011

An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments journal, June 1992

Crack deflection processes—I. Theory journal, April 1983

Ceramic and polymeric solid electrolytes for lithium-ion batteries journal, August 2010

Effect of Sintering Atmosphere on Densification of MgO-Doped Al2O3 journal, August 1988

Inorganic solid Li ion conductors: An overview journal, June 2009

Sintering Alumina: Effect of Atmospheres journal, March 1962

Grain size and porosity dependence of ceramic fracture energy and toughness at 22 °C journal, April 1996

NMR study of Li distribution in Li 7−x H x La 3 Zr 2 O 12 garnets journal, January 2015

A preliminary investigation of fracture toughness of Li7La3Zr2O12 and its comparison to other solid Li-ionconductors journal, April 2013

Resolving the Grain Boundary and Lattice Impedance of Hot-Pressed Li 7 La 3 Zr 2 O 12 Garnet Electrolytes journal, July 2013

Fabrication of all-solid-state lithium battery with lithium metal anode using Al2O3-added Li7La3Zr2O12 solid electrolyte journal, September 2011

Transfomation toughening of ??-alumina by incorporation of zirconia journal, January 1983

Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries journal, March 2014

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li7La3Zr2O12 journal, January 2012

Lithium metal anodes for rechargeable batteries journal, January 2014

Densification and ionic-conduction improvement of lithium garnet solid electrolytes by flowing oxygen sintering journal, February 2014

Synthesis and properties of Al-free Li7−xLa3Zr2−xTaxO12 garnet related oxides journal, September 2014

Microstructure and Li-Ion Conductivity of Hot-Pressed Cubic Li 7 La 3 Zr 2 O 12 journal, January 2015

Effect of microstructure and surface impurity segregation on the electrical and electrochemical properties of dense Al-substituted Li 7 La 3 Zr 2 O 12 journal, January 2014

Review Lecture: Fast Ionic Conduction in Solids journal, June 1984

Lithium Lanthanum Titanates: A Review journal, October 2003

Intergranular Crack-Deflection Toughening in Silicon Carbide journal, June 1983

Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12 journal, October 2007

Title: The Effect of Relative Density on the Mechanical Properties of Hot‐Pressed Cubic Li ₇ La ₃ Zr ₂ O ₁₂

A Critical Review of Li∕Air Batteries
journal, January 2012

Optimizing Li+ conductivity in a garnet framework
journal, January 2012

Effects of penta- and trivalent dopants on structure and conductivity of Li7La3Zr2O12
journal, June 2015

Li7La3Zr2O12 electrolyte stability in air and fabrication of a Li/Li7La3Zr2O12/Cu0.1V2O5 solid-state battery
journal, October 2013

Systematic hardness measurements on some rare earth garnet crystal
journal, October 2001

Effect of sintering temperature on structure and ionic conductivity of Li7−xLa3Zr2O12−0.5x (x=0.5~0.7) ceramics
journal, December 2011

Nebulized spray pyrolysis of Al-doped Li7La3Zr2O12 solid electrolyte for battery applications
journal, October 2014

Effect of Grain Size and Poling on the Fracture Mode of Lead Zirconate Titanate Ceramics
journal, January 1990

First-principles density functional calculation of electrochemical stability of fast Li ion conducting garnet-type oxides
journal, January 2012

Effects of Li source on microstructure and ionic conductivity of Al-contained Li6.75La3Zr1.75Ta0.25O12 ceramics
journal, February 2015

Grain-Size Dependence of Fracture Energy in Ceramics: I, Experiment
journal, June 1981

Brittle Fracture and Toughening Mechanisms in Ceramics
journal, August 1984

Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet
journal, July 2012

A Critical Evaluation of Indentation Techniques for Measuring Fracture Toughness: I, Direct Crack Measurements
journal, September 1981

Crack deflection processes—II. Experiment
journal, April 1983

Effect of calcining and Al doping on structure and conductivity of Li 7 La 3 Zr 2 O 12
journal, November 2014

Hydrogen Softening in the Thin Plate of Microcrystalline 316L Stainless Steel
journal, June 2013

Crack Deflection as a Toughening Mechanism in SiC-Whisker-Reinforced MoSi2
journal, April 1987

Effect of substitution (Ta, Al, Ga) on the conductivity of Li₇La₃Zr₂O₁₂
journal, May 2012

High lithium ionic conductivity in the garnet-type oxide Li_7−XLa₃(Zr_2−X, Nb_X)O₁₂ (X=0–2)
journal, March 2011

An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments
journal, June 1992

Crack deflection processes—I. Theory
journal, April 1983

Ceramic and polymeric solid electrolytes for lithium-ion batteries
journal, August 2010

Effect of Sintering Atmosphere on Densification of MgO-Doped Al2O3
journal, August 1988

Inorganic solid Li ion conductors: An overview
journal, June 2009

Sintering Alumina: Effect of Atmospheres
journal, March 1962

Grain size and porosity dependence of ceramic fracture energy and toughness at 22 °C
journal, April 1996

NMR study of Li distribution in Li _7−x H _x La ₃ Zr ₂ O ₁₂ garnets
journal, January 2015

A preliminary investigation of fracture toughness of Li7La3Zr2O12 and its comparison to other solid Li-ionconductors
journal, April 2013

Resolving the Grain Boundary and Lattice Impedance of Hot-Pressed Li ₇ La ₃ Zr ₂ O ₁₂ Garnet Electrolytes
journal, July 2013

Fabrication of all-solid-state lithium battery with lithium metal anode using Al2O3-added Li7La3Zr2O12 solid electrolyte
journal, September 2011

Transfomation toughening of ??-alumina by incorporation of zirconia
journal, January 1983

Garnet related lithium ion conductor processed by spark plasma sintering for all solid state batteries
journal, March 2014

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li₇La₃Zr₂O₁₂
journal, January 2012

Lithium metal anodes for rechargeable batteries
journal, January 2014

Densification and ionic-conduction improvement of lithium garnet solid electrolytes by flowing oxygen sintering
journal, February 2014

Synthesis and properties of Al-free Li7−xLa3Zr2−xTaxO12 garnet related oxides
journal, September 2014

Microstructure and Li-Ion Conductivity of Hot-Pressed Cubic Li ₇ La ₃ Zr ₂ O ₁₂
journal, January 2015

Effect of microstructure and surface impurity segregation on the electrical and electrochemical properties of dense Al-substituted Li ₇ La ₃ Zr ₂ O ₁₂
journal, January 2014

Review Lecture: Fast Ionic Conduction in Solids
journal, June 1984

Lithium Lanthanum Titanates: A Review
journal, October 2003

Intergranular Crack-Deflection Toughening in Silicon Carbide
journal, June 1983

Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂
journal, October 2007