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Title: Random poly(3-hexylthiophene- co -3-cyanothiophene- co -3-(2-ethylhexyl)thiophene) copolymers with high open-circuit voltage in polymer solar cells

Authors:
 [1];  [1];  [1]
  1. Department of Chemistry and Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles California 90089-1661
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401412
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Polymer Science. Part A, Polymer Chemistry
Additional Journal Information:
Journal Name: Journal of Polymer Science. Part A, Polymer Chemistry Journal Volume: 54 Journal Issue: 11; Journal ID: ISSN 0887-624X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States
Language:
English

Citation Formats

Rudenko, Andrey E., Khlyabich, Petr P., and Thompson, Barry C. Random poly(3-hexylthiophene- co -3-cyanothiophene- co -3-(2-ethylhexyl)thiophene) copolymers with high open-circuit voltage in polymer solar cells. United States: N. p., 2015. Web. doi:10.1002/pola.28007.
Rudenko, Andrey E., Khlyabich, Petr P., & Thompson, Barry C. Random poly(3-hexylthiophene- co -3-cyanothiophene- co -3-(2-ethylhexyl)thiophene) copolymers with high open-circuit voltage in polymer solar cells. United States. doi:10.1002/pola.28007.
Rudenko, Andrey E., Khlyabich, Petr P., and Thompson, Barry C. Thu . "Random poly(3-hexylthiophene- co -3-cyanothiophene- co -3-(2-ethylhexyl)thiophene) copolymers with high open-circuit voltage in polymer solar cells". United States. doi:10.1002/pola.28007.
@article{osti_1401412,
title = {Random poly(3-hexylthiophene- co -3-cyanothiophene- co -3-(2-ethylhexyl)thiophene) copolymers with high open-circuit voltage in polymer solar cells},
author = {Rudenko, Andrey E. and Khlyabich, Petr P. and Thompson, Barry C.},
abstractNote = {},
doi = {10.1002/pola.28007},
journal = {Journal of Polymer Science. Part A, Polymer Chemistry},
number = 11,
volume = 54,
place = {United States},
year = {2015},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/pola.28007

Citation Metrics:
Cited by: 6 works
Citation information provided by
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Works referenced in this record:

Ternary blend polymer solar cells with enhanced power conversion efficiency
journal, August 2014


Single-Junction Organic Solar Cells Based on a Novel Wide-Bandgap Polymer with Efficiency of 9.7%
journal, April 2015


High band gap poly(9,9-dihexylfluorene-alt-bithiophene) blended with [6,6]-phenyl C61 butyric acid methyl ester for use in efficient photovoltaic devices
journal, January 2009

  • Schulz, Gisela L.; Chen, Xiwen; Holdcroft, Steven
  • Applied Physics Letters, Vol. 94, Issue 2
  • DOI: 10.1063/1.3070574

High-Efficiency Polymer Solar Cells via the Incorporation of an Amino-Functionalized Conjugated Metallopolymer as a Cathode Interlayer
journal, October 2013

  • Liu, Shengjian; Zhang, Kai; Lu, Junming
  • Journal of the American Chemical Society, Vol. 135, Issue 41
  • DOI: 10.1021/ja408363c

Single-Junction Polymer Solar Cells with Over 10% Efficiency by a Novel Two-Dimensional Donor–Acceptor Conjugated Copolymer
journal, February 2015

  • Liu, Chang; Yi, Chao; Wang, Kai
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 8
  • DOI: 10.1021/am509047g

Polymer-Based Solar Cells: State-of-the-Art Principles for the Design of Active Layer Components
journal, January 2011


Effect of Polymer Aggregation on the Open Circuit Voltage in Organic Photovoltaic Cells: Aggregation-Induced Conjugated Polymer Gel and its Application for Preventing Open Circuit Voltage Drop
journal, February 2011

  • Kim, Bong-Gi; Jeong, Eun Jeong; Park, Hui Joon
  • ACS Applied Materials & Interfaces, Vol. 3, Issue 3, p. 674-680
  • DOI: 10.1021/am101067x

Relation between absorption and crystallinity of poly(3-hexylthiophene)/fullerene films for plastic solar cells
journal, February 2006


Random poly(3-hexylthiophene- co -3-cyanothiophene) copolymers with high open-circuit voltage in organic solar cells
journal, January 2014

  • Khlyabich, Petr P.; Rudenko, Andrey E.; Thompson, Barry C.
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 52, Issue 8
  • DOI: 10.1002/pola.27095

Single-junction polymer solar cells with high efficiency and photovoltage
journal, February 2015


Conjugated Polymers with Switchable Carrier Polarity
journal, August 2015


Random Poly(3-hexylthiophene- co -3-cyanothiophene) Copolymers via Direct Arylation Polymerization (DArP) for Organic Solar Cells with High Open-Circuit Voltage
journal, March 2014

  • Rudenko, Andrey E.; Khlyabich, Petr P.; Thompson, Barry C.
  • ACS Macro Letters, Vol. 3, Issue 4
  • DOI: 10.1021/mz5001652

Influence of the Ethylhexyl Side-Chain Content on the Open-Circuit Voltage in rr-Poly(3-hexylthiophene- co -3-(2-ethylhexyl)thiophene) Copolymers
journal, April 2012

  • Burkhart, Beate; Khlyabich, Petr P.; Thompson, Barry C.
  • Macromolecules, Vol. 45, Issue 9
  • DOI: 10.1021/ma300263a

Theoretical Study on the Rational Design of Cyano-Substituted P3HT Materials for OSCs: Substitution Effect on the Improvement of Photovoltaic Performance
journal, April 2015

  • Qiu, Meng; Brandt, Rasmus G.; Niu, Yingli
  • The Journal of Physical Chemistry C, Vol. 119, Issue 16
  • DOI: 10.1021/acs.jpcc.5b01071

Effect of Molecular Weight and Annealing of Poly(3-hexylthiophene)s on the Performance of Organic Field-Effect Transistors
journal, August 2004

  • Zen, A.; Pflaum, J.; Hirschmann, S.
  • Advanced Functional Materials, Vol. 14, Issue 8, p. 757-764
  • DOI: 10.1002/adfm.200400017

Fill factor in organic solar cells
journal, January 2013

  • Qi, Boyuan; Wang, Jizheng
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 23
  • DOI: 10.1039/c3cp51383a

Efficient Ternary Blend Bulk Heterojunction Solar Cells with Tunable Open-Circuit Voltage
journal, September 2011

  • Khlyabich, Petr P.; Burkhart, Beate; Thompson, Barry C.
  • Journal of the American Chemical Society, Vol. 133, Issue 37
  • DOI: 10.1021/ja205977z

Ultimate performance of polymer:fullerene bulk heterojunction tandem solar cells
journal, January 2011

  • Kotlarski, J. D.; Blom, P. W. M.
  • Applied Physics Letters, Vol. 98, Issue 5
  • DOI: 10.1063/1.3549693

Spectral Engineering in π-Conjugated Polymers with Intramolecular Donor−Acceptor Interactions
journal, November 2010

  • Beaujuge, Pierre M.; Amb, Chad M.; Reynolds, John R.
  • Accounts of Chemical Research, Vol. 43, Issue 11
  • DOI: 10.1021/ar100043u

The Spectral Signatures of Frenkel Polarons in H- and J-Aggregates
journal, March 2010

  • Spano, Frank C.
  • Accounts of Chemical Research, Vol. 43, Issue 3
  • DOI: 10.1021/ar900233v

25th Anniversary Article: A Decade of Organic/Polymeric Photovoltaic Research
journal, September 2013


How the structural deviations on the backbone of conjugated polymers influence their optoelectronic properties and photovoltaic performance
journal, October 2011


Recent trends in polymer tandem solar cells research
journal, December 2013


Optimization and simplification of polymer–fullerene solar cells through polymer and active layer design
journal, September 2013


Recent progress in the morphology of bulk heterojunction photovoltaics
journal, January 2011

  • Brady, Michael A.; Su, Gregory M.; Chabinyc, Michael L.
  • Soft Matter, Vol. 7, Issue 23
  • DOI: 10.1039/c1sm06147j

P3HT:PCBM, Best Seller in Polymer Photovoltaic Research
journal, July 2011

  • Dang, Minh Trung; Hirsch, Lionel; Wantz, Guillaume
  • Advanced Materials, Vol. 23, Issue 31
  • DOI: 10.1002/adma.201100792

n-Type Naphthalene Diimide–Biselenophene Copolymer for All-Polymer Bulk Heterojunction Solar Cells
journal, November 2012

  • Hwang, Ye-Jin; Ren, Guoqiang; Murari, Nishit M.
  • Macromolecules, Vol. 45, Issue 22
  • DOI: 10.1021/ma3020239

Measuring Molecular Order in Poly(3-alkylthiophene) Thin Films with Polarizing Spectroscopies
journal, January 2007

  • Gurau, Marc C.; Delongchamp, Dean M.; Vogel, Brandon M.
  • Langmuir, Vol. 23, Issue 2
  • DOI: 10.1021/la0618972

High-performance multiple-donor bulk heterojunction solar cells
journal, February 2015


J-Aggregate Behavior in Poly-3-hexylthiophene Nanofibers
journal, January 2012

  • Niles, Edwards T.; Roehling, John D.; Yamagata, Hajime
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 2
  • DOI: 10.1021/jz201509h

“Semi-Random” Multichromophoric rr-P3HT Analogues for Solar Photon Harvesting
journal, March 2011

  • Burkhart, Beate; Khlyabich, Petr P.; Cakir Canak, Tuba
  • Macromolecules, Vol. 44, Issue 6
  • DOI: 10.1021/ma102747e

Efficient Solar Cells from Semi-random P3HT Analogues Incorporating Diketopyrrolopyrrole
journal, July 2011

  • Khlyabich, Petr P.; Burkhart, Beate; Ng, Christi F.
  • Macromolecules, Vol. 44, Issue 13
  • DOI: 10.1021/ma2009386

Factors Limiting Device Efficiency in Organic Photovoltaics
journal, December 2012


Soluble Narrow Band Gap and Blue Propylenedioxythiophene-Cyanovinylene Polymers as Multifunctional Materials for Photovoltaic and Electrochromic Applications
journal, October 2006

  • Thompson, Barry C.; Kim, Young-Gi; McCarley, Tracy D.
  • Journal of the American Chemical Society, Vol. 128, Issue 39
  • DOI: 10.1021/ja061274a

Small Bandgap Polymers for Organic Solar Cells (Polymer Material Development in the Last 5 Years)
journal, August 2008


A polymer tandem solar cell with 10.6% power conversion efficiency
journal, February 2013

  • You, Jingbi; Dou, Letian; Yoshimura, Ken
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2411

Charge Generation and Recombination Dynamics in Poly(3-hexylthiophene)/Fullerene Blend Films with Different Regioregularities and Morphologies
journal, May 2010

  • Guo, Jiamo; Ohkita, Hideo; Benten, Hiroaki
  • Journal of the American Chemical Society, Vol. 132, Issue 17
  • DOI: 10.1021/ja100302p

Organic Ternary Solar Cells: A Review
journal, May 2013


Influence of the Acceptor Composition on Physical Properties and Solar Cell Performance in Semi-Random Two-Acceptor Copolymers
journal, May 2012

  • Burkhart, Beate; Khlyabich, Petr P.; Thompson, Barry C.
  • ACS Macro Letters, Vol. 1, Issue 6
  • DOI: 10.1021/mz300197c

Influence of Backbone Fluorination in Regioregular Poly(3-alkyl-4-fluoro)thiophenes
journal, May 2015

  • Fei, Zhuping; Boufflet, Pierre; Wood, Sebastian
  • Journal of the American Chemical Society, Vol. 137, Issue 21
  • DOI: 10.1021/jacs.5b02785

A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells
journal, February 2006

  • Kim, Youngkyoo; Cook, Steffan; Tuladhar, Sachetan M.
  • Nature Materials, Vol. 5, Issue 3
  • DOI: 10.1038/nmat1574

Low band gap polymers for organic photovoltaics
journal, July 2007

  • Bundgaard, Eva; Krebs, Frederik C.
  • Solar Energy Materials and Solar Cells, Vol. 91, Issue 11, p. 954-985
  • DOI: 10.1016/j.solmat.2007.01.015

Quantitatively Analyzing the Influence of Side Chains on Photovoltaic Properties of Polymer−Fullerene Solar Cells
journal, September 2010

  • Yang, Liqiang; Zhou, Huaxing; You, Wei
  • The Journal of Physical Chemistry C, Vol. 114, Issue 39
  • DOI: 10.1021/jp106640r

Influence of molecular weight on the spectroscopic properties of a series of well-defined poly(3-hexylthiophene) polymers
journal, January 2011

  • Peng, Qiliang; Wyman, Ian W.; Han, Dehui
  • Canadian Journal of Chemistry, Vol. 89, Issue 1
  • DOI: 10.1139/V10-151

Compositional Dependence of the Open-Circuit Voltage in Ternary Blend Bulk Heterojunction Solar Cells Based on Two Donor Polymers
journal, May 2012

  • Khlyabich, Petr P.; Burkhart, Beate; Thompson, Barry C.
  • Journal of the American Chemical Society, Vol. 134, Issue 22
  • DOI: 10.1021/ja302935n

Efficiency exceeding 10% for inverted polymer solar cells with a ZnO/ionic liquid combined cathode interfacial layer
journal, January 2015

  • Yu, W.; Huang, L.; Yang, D.
  • Journal of Materials Chemistry A, Vol. 3, Issue 20
  • DOI: 10.1039/C5TA00930H

Efficiency of bulk-heterojunction organic solar cells
journal, December 2013


Stille Polycondensation for Synthesis of Functional Materials
journal, March 2011

  • Carsten, Bridget; He, Feng; Son, Hae Jung
  • Chemical Reviews, Vol. 111, Issue 3
  • DOI: 10.1021/cr100320w

Open-circuit voltage in organic solar cells
journal, January 2012

  • Qi, Boyuan; Wang, Jizheng
  • Journal of Materials Chemistry, Vol. 22, Issue 46
  • DOI: 10.1039/c2jm33719c

Influence of Fluorination and Molecular Weight on the Morphology and Performance of PTB7:PC 71 BM Solar Cells
journal, May 2014

  • He, Xiaoxi; Mukherjee, Subhrangsu; Watkins, Scott
  • The Journal of Physical Chemistry C, Vol. 118, Issue 19
  • DOI: 10.1021/jp501222w

Effect of chemical modifications on the electronic structure of poly(3-hexylthiophene)
journal, February 2013

  • Oliveira, Eliézer Fernando de; Camilo-Jr, Alexandre; Silva-Filho, Luiz Carlos da
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 10
  • DOI: 10.1002/polb.23274

Towards 15% energy conversion efficiency: a systematic study of the solution-processed organic tandem solar cells based on commercially available materials
journal, January 2013

  • Li, Ning; Baran, Derya; Forberich, Karen
  • Energy & Environmental Science, Vol. 6, Issue 12
  • DOI: 10.1039/c3ee42307g

Influence of blend microstructure on bulk heterojunction organic photovoltaic performance
journal, January 2011

  • Brabec, Christoph J.; Heeney, Martin; McCulloch, Iain
  • Chem. Soc. Rev., Vol. 40, Issue 3
  • DOI: 10.1039/C0CS00045K

3-Fluoro-4-hexylthiophene as a Building Block for Tuning the Electronic Properties of Conjugated Polythiophenes
journal, February 2013

  • Gohier, Frédéric; Frère, Pierre; Roncali, Jean
  • The Journal of Organic Chemistry, Vol. 78, Issue 4
  • DOI: 10.1021/jo302571u

Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications
journal, April 2011

  • Cardona, Claudia M.; Li, Wei; Kaifer, Angel E.
  • Advanced Materials, Vol. 23, Issue 20
  • DOI: 10.1002/adma.201004554

Thienothiophenes, Dithienothiophenes, and Thienoacenes: Syntheses, Oligomers, Polymers, and Properties
journal, April 2015

  • Cinar, Mehmet Emin; Ozturk, Turan
  • Chemical Reviews, Vol. 115, Issue 9
  • DOI: 10.1021/cr500271a

Isostructural, Deeper Highest Occupied Molecular Orbital Analogues of Poly(3-hexylthiophene) for High-Open Circuit Voltage Organic Solar Cells
journal, October 2013

  • Bronstein, Hugo; Hurhangee, Michael; Fregoso, Elisa Collado
  • Chemistry of Materials, Vol. 25, Issue 21
  • DOI: 10.1021/cm4022563

Molecular and Morphological Influences on the Open Circuit Voltages of Organic Photovoltaic Devices
journal, July 2009

  • Perez, M. Dolores; Borek, Carsten; Forrest, Stephen R.
  • Journal of the American Chemical Society, Vol. 131, Issue 26
  • DOI: 10.1021/ja9007722

The Next Breakthrough for Organic Photovoltaics?
journal, December 2014

  • Jackson, Nicholas E.; Savoie, Brett M.; Marks, Tobin J.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 1
  • DOI: 10.1021/jz502223t

New conjugated polymers for plastic solar cells
journal, January 2011

  • Gendron, David; Leclerc, Mario
  • Energy & Environmental Science, Vol. 4, Issue 4
  • DOI: 10.1039/c1ee01072g

The future of organic photovoltaics
journal, January 2015

  • Mazzio, Katherine A.; Luscombe, Christine K.
  • Chemical Society Reviews, Vol. 44, Issue 1
  • DOI: 10.1039/C4CS00227J

Highly efficient organic tandem solar cells: a follow up review
journal, January 2013

  • Ameri, Tayebeh; Li, Ning; Brabec, Christoph J.
  • Energy & Environmental Science, Vol. 6, Issue 8
  • DOI: 10.1039/c3ee40388b

Influence of Molecular Weight Distribution on the Gelation of P3HT and Its Impact on the Photovoltaic Performance
journal, July 2009

  • Koppe, Markus; Brabec, Christoph J.; Heiml, Sabrina
  • Macromolecules, Vol. 42, Issue 13, p. 4661-4666
  • DOI: 10.1021/ma9005445

Recent progress in the design of narrow bandgap conjugated polymers for high-efficiency organic solar cells
journal, September 2012


An Easy and Effective Method To Modulate Molecular Energy Level of Poly(3-alkylthiophene) for High- V oc Polymer Solar Cells
journal, December 2009

  • Hou, Jianhui; Chen, Teresa L.; Zhang, Shaoqing
  • Macromolecules, Vol. 42, Issue 23
  • DOI: 10.1021/ma902197a

Space-Charge Limited Photocurrent
journal, April 2005


Ultrafast Hole-Transfer Dynamics in Polymer/PCBM Bulk Heterojunctions
journal, May 2010

  • Bakulin, Artem A.; Hummelen, Jan C.; Pshenichnikov, Maxim S.
  • Advanced Functional Materials, Vol. 20, Issue 10
  • DOI: 10.1002/adfm.200902099

The impact of molecular weight on microstructure and charge transport in semicrystalline polymer semiconductors–poly(3-hexylthiophene), a model study
journal, December 2013


Techniques for characterization of charge carrier mobility in organic semiconductors
journal, June 2012

  • Kokil, Akshay; Yang, Ke; Kumar, Jayant
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 50, Issue 15
  • DOI: 10.1002/polb.23103

Charge carrier recombination in organic solar cells
journal, December 2013


Regiocontrolled Synthesis of Poly(3-alkylthiophenes) Mediated by Rieke Zinc: Their Characterization and Solid-State Properties
journal, January 1995

  • Chen, Tian-An; Wu, Xiaoming; Rieke, Reuben D.
  • Journal of the American Chemical Society, Vol. 117, Issue 1, p. 233-244
  • DOI: 10.1021/ja00106a027

Dual Functional Zwitterionic Fullerene Interlayer for Efficient Inverted Polymer Solar Cells
journal, May 2015

  • Liu, Yao; Page, Zachariah; Ferdous, Sunzida
  • Advanced Energy Materials, Vol. 5, Issue 14
  • DOI: 10.1002/aenm.201500405

Polymer Solar Cells with Efficiency >10% Enabled via a Facile Solution-Processed Al-Doped ZnO Electron Transporting Layer
journal, April 2015

  • Jagadamma, Lethy Krishnan; Al-Senani, Mohammed; El-Labban, Abdulrahman
  • Advanced Energy Materials, Vol. 5, Issue 12
  • DOI: 10.1002/aenm.201500204