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Title: Single gold atoms stabilized on nanoscale metal oxide supports are catalytic active centers for various reactions

Authors:
 [1];  [1];  [1]
  1. Dept. of Chemical and Biological Engineering, Tufts University, Medford MA 02155
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401411
Grant/Contract Number:  
FG02-05ER15730
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
AIChE Journal
Additional Journal Information:
Journal Name: AIChE Journal Journal Volume: 62 Journal Issue: 2; Journal ID: ISSN 0001-1541
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States
Language:
English

Citation Formats

Wang, Chongyang, Yang, Ming, and Flytzani-Stephanopoulos, Maria. Single gold atoms stabilized on nanoscale metal oxide supports are catalytic active centers for various reactions. United States: N. p., 2015. Web. doi:10.1002/aic.15134.
Wang, Chongyang, Yang, Ming, & Flytzani-Stephanopoulos, Maria. Single gold atoms stabilized on nanoscale metal oxide supports are catalytic active centers for various reactions. United States. doi:10.1002/aic.15134.
Wang, Chongyang, Yang, Ming, and Flytzani-Stephanopoulos, Maria. Tue . "Single gold atoms stabilized on nanoscale metal oxide supports are catalytic active centers for various reactions". United States. doi:10.1002/aic.15134.
@article{osti_1401411,
title = {Single gold atoms stabilized on nanoscale metal oxide supports are catalytic active centers for various reactions},
author = {Wang, Chongyang and Yang, Ming and Flytzani-Stephanopoulos, Maria},
abstractNote = {},
doi = {10.1002/aic.15134},
journal = {AIChE Journal},
number = 2,
volume = 62,
place = {United States},
year = {2015},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/aic.15134

Citation Metrics:
Cited by: 29 works
Citation information provided by
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Works referenced in this record:

Chemicals from ethanol—The acetone one-pot synthesis
journal, May 2013


Recent Advances in Catalytic Conversion of Ethanol to Chemicals
journal, March 2014


The oxidation of methanol on a silver (110) catalyst
journal, September 1978


Oxygenate reaction pathways on transition metal surfaces
journal, May 1998


Steam reforming of methanol over ceria and gold-ceria nanoshapes
journal, March 2010


Theoretical Study of O-Assisted Selective Coupling of Methanol on Au(111)
journal, February 2011

  • Xu, Bingjun; Haubrich, Jan; Baker, Thomas A.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 9
  • DOI: 10.1021/jp110835w

Catalytically active Au-O(OH) x - species stabilized by alkali ions on zeolites and mesoporous oxides
journal, November 2014


Catalytic steam reforming of ethanol to produce hydrogen and acetone
journal, January 2005

  • Nishiguchi, Toshiya; Matsumoto, Tomoaki; Kanai, Hiroyoshi
  • Applied Catalysis A: General, Vol. 279, Issue 1-2
  • DOI: 10.1016/j.apcata.2004.10.035

Low-content gold-ceria catalysts for the water–gas shift and preferential CO oxidation reactions
journal, September 2005


High temperature steam reforming of methanol over Cu/ZnO/ZrO2 catalysts
journal, September 2009


Surface reactivity of supported gold I. Oxygen transfer between CO and CO2
journal, August 1970


Highly Dispersed Gold on Zirconia: Characterization and Activity in Low-Temperature Water Gas Shift Tests
journal, April 2008

  • Menegazzo, Federica; Pinna, Francesco; Signoretto, Michela
  • ChemSusChem, Vol. 1, Issue 4
  • DOI: 10.1002/cssc.200700152

Oxygen-assisted cross-coupling of methanol with alkyl alcohols on metallic gold
journal, January 2010

  • Xu, Bingjun; Haubrich, Jan; Freyschlag, Cassandra G.
  • Chemical Science, Vol. 1, Issue 3
  • DOI: 10.1039/c0sc00214c

Active gold species on cerium oxide nanoshapes for methanol steam reforming and the water gas shift reactions
journal, January 2010

  • Yi, Nan; Si, Rui; Saltsburg, Howard
  • Energy & Environmental Science, Vol. 3, Issue 6
  • DOI: 10.1039/b924051a

Controlled surface properties of Au/ZSM5 catalysts and their effects in the selective oxidation of ethanol
journal, November 2015


Gold Atoms Stabilized on Various Supports Catalyze the Water–Gas Shift Reaction
journal, November 2013

  • Flytzani-Stephanopoulos, Maria
  • Accounts of Chemical Research, Vol. 47, Issue 3
  • DOI: 10.1021/ar4001845

Enhanced Bonding of Gold Nanoparticles on Oxidized TiO2(110)
journal, March 2007


Shape and Crystal-Plane Effects of Nanoscale Ceria on the Activity of Au-CeO2 Catalysts for the Water–Gas Shift Reaction
journal, March 2008


A study of ZnxZryOz mixed oxides for direct conversion of ethanol to isobutene
journal, October 2013


A Common Single-Site Pt(II)–O(OH) x – Species Stabilized by Sodium on “Active” and “Inert” Supports Catalyzes the Water-Gas Shift Reaction
journal, March 2015

  • Yang, Ming; Liu, Jilei; Lee, Sungsik
  • Journal of the American Chemical Society, Vol. 137, Issue 10
  • DOI: 10.1021/ja513292k

Selectivity Control in Gold-Mediated Esterification of Methanol
journal, May 2009

  • Xu, Bingjun; Liu, Xiaoying; Haubrich, Jan
  • Angewandte Chemie International Edition, Vol. 48, Issue 23, p. 4206-4209
  • DOI: 10.1002/anie.200805404

Activation of carbon-supported platinum catalysts by sodium for the low-temperature water-gas shift reaction
journal, January 2014

  • Zugic, Branko; Bell, David C.; Flytzani-Stephanopoulos, Maria
  • Applied Catalysis B: Environmental, Vol. 144
  • DOI: 10.1016/j.apcatb.2013.07.013

Methanol Steam Reforming for Hydrogen Production
journal, October 2007

  • Palo, Daniel R.; Dagle, Robert A.; Holladay, Jamie D.
  • Chemical Reviews, Vol. 107, Issue 10
  • DOI: 10.1021/cr050198b

On the Issue of the Deactivation of Au–Ceria and Pt–Ceria Water–Gas Shift Catalysts in Practical Fuel-Cell Applications
journal, March 2006

  • Deng, Weiling; Flytzani-Stephanopoulos, Maria
  • Angewandte Chemie International Edition, Vol. 45, Issue 14
  • DOI: 10.1002/anie.200503220

Effect of Zn addition to supported Pd catalysts in the steam reforming of methanol
journal, August 2003


Selective production of isobutylene from acetone over alkali metal ion-exchanged BEA zeolites
journal, April 2011


Fuel Cell Systems Explained, Second Edition
book, February 2003


Probing the Low-Temperature Water–Gas Shift Activity of Alkali-Promoted Platinum Catalysts Stabilized on Carbon Supports
journal, February 2014

  • Zugic, Branko; Zhang, Shiran; Bell, David C.
  • Journal of the American Chemical Society, Vol. 136, Issue 8
  • DOI: 10.1021/ja4123889

Selective oxidation of ethanol to acetaldehyde by Au−Ir catalysts
journal, September 2013


Renewable Hydrogen from Ethanol by Autothermal Reforming
journal, February 2004


Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift Reactions
journal, September 2010


Comparison of the activity of Au/CeO2 and Au/Fe2O3 catalysts for the CO oxidation and the water-gas shift reactions
journal, June 2007


Vapour-phase gold-surface-mediated coupling of aldehydes with methanol
journal, November 2009

  • Xu, Bingjun; Liu, Xiaoying; Haubrich, Jan
  • Nature Chemistry, Vol. 2, Issue 1
  • DOI: 10.1038/nchem.467

Strong Metal–Support Interactions between Gold Nanoparticles and ZnO Nanorods in CO Oxidation
journal, June 2012

  • Liu, Xiaoyan; Liu, Ming-Han; Luo, Yi-Chia
  • Journal of the American Chemical Society, Vol. 134, Issue 24
  • DOI: 10.1021/ja3033235

Raney Ni-Sn Catalyst for H2 Production from Biomass-Derived Hydrocarbons
journal, June 2003


Direct Conversion of Bio-ethanol to Isobutene on Nanosized Zn x Zr y O z Mixed Oxides with Balanced Acid–Base Sites
journal, July 2011

  • Sun, Junming; Zhu, Kake; Gao, Feng
  • Journal of the American Chemical Society, Vol. 133, Issue 29
  • DOI: 10.1021/ja204235v

Atomically Dispersed Supported Metal Catalysts
journal, July 2012


Reaction-Relevant Gold Structures in the Low Temperature Water-Gas Shift Reaction on Au-CeO 2
journal, August 2008

  • Deng, Weiling; Frenkel, Anatoly I.; Si, Rui
  • The Journal of Physical Chemistry C, Vol. 112, Issue 33
  • DOI: 10.1021/jp800075y

ZnO-modified zirconia as gold catalyst support for the low-temperature methanol steam reforming reaction
journal, July 2014


STM study of the geometric and electronic structure of ZnO()-Zn, ()-O, (), and () surfaces
journal, November 2002


Low-Temperature Oxidation of CO over Gold Supported on TiO2, α-Fe2O3, and Co3O4
journal, November 1993


Total Oxidation of Carbon-Monoxide and Methane over Transition Metal Fluorite Oxide Composite Catalysts
journal, May 1995


Nanoporous Gold Catalysts for Selective Gas-Phase Oxidative Coupling of Methanol at Low Temperature
journal, January 2010


Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C
journal, February 1987

  • Haruta, Masatake; Kobayashi, Tetsuhiko; Sano, Hiroshi
  • Chemistry Letters, Vol. 16, Issue 2
  • DOI: 10.1246/cl.1987.405

Silica-encapsulated platinum catalysts for the low-temperature water-gas shift reaction
journal, October 2012


Selective synthesis for light olefins from acetone over ZSM-5 zeolites with nano- and macro-crystal sizes
journal, August 2011


Total Oxidation of Carbon Monoxide and Methane over Transition Metal Fluorite Oxide Composite Catalysts
journal, May 1995


Evolution of gold structure during thermal treatment of Au/FeOx catalysts revealed by aberration-corrected electron microscopy
journal, April 2009

  • Allard, L. F.; Borisevich, A.; Deng, W.
  • Journal of Electron Microscopy, Vol. 58, Issue 3
  • DOI: 10.1093/jmicro/dfp016

Atomically Dispersed Au–(OH) x Species Bound on Titania Catalyze the Low-Temperature Water-Gas Shift Reaction
journal, March 2013

  • Yang, Ming; Allard, Lawrence F.; Flytzani-Stephanopoulos, Maria
  • Journal of the American Chemical Society, Vol. 135, Issue 10
  • DOI: 10.1021/ja312646d

Electronic structures of Au on TiO 2 ( 110 ) by first-principles calculations
journal, June 2004


A highly active and highly selective oxide catalyst for the conversion of ethanol to acetone in the presence of water vapour
journal, January 1994

  • Nakajima, Tsuyoshi; Nameta, Hisashi; Mishima, Shozi
  • Journal of Materials Chemistry, Vol. 4, Issue 6
  • DOI: 10.1039/jm9940400853

Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003


Selective oxidation of ethanol to acetaldehyde over Au–Cu catalysts prepared by a redox method
journal, March 2015


‘Shape effects’ in metal oxide supported nanoscale gold catalysts
journal, January 2011

  • Boucher, Matthew B.; Goergen, Simone; Yi, Nan
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 7
  • DOI: 10.1039/c0cp02009e

Novel Au/La2O3 and Au/La2O2SO4 catalysts for the water–gas shift reaction prepared via an anion adsorption method
journal, January 2012

  • Lessard, Joseph D.; Valsamakis, Ioannis; Flytzani-Stephanopoulos, Maria
  • Chemical Communications, Vol. 48, Issue 40
  • DOI: 10.1039/c2cc31105d

Hydrogen Production by Dehydrogenation of Formic Acid on Atomically Dispersed Gold on Ceria
journal, March 2013

  • Yi, Nan; Saltsburg, Howard; Flytzani-Stephanopoulos, Maria
  • ChemSusChem, Vol. 6, Issue 5
  • DOI: 10.1002/cssc.201200957

Hydrogen Production from Methanol over Gold Supported on ZnO and CeO 2 Nanoshapes
journal, September 2010

  • Boucher, Matthew B.; Yi, Nan; Gittleson, Forrest
  • The Journal of Physical Chemistry C, Vol. 115, Issue 4
  • DOI: 10.1021/jp106589n

Catalysts for methanol steam reforming—A review
journal, August 2010


Conversion of ethanol to acetone over promoted iron oxide catalysis
journal, February 1988