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Title: Role of the PbTiO 3 Seed Layer on the Crystallization Behavior of PZT Thin Films

Abstract

The role of a highly crystalline and oriented lead titanate ( PTO ) seed layer on the subsequent phase and texture evolution of lead zirconate titanate ( PZT ) thin films is investigated in situ using X‐ray diffraction ( XRD ) during crystallization. Crystalline PTO seed layers were first prepared via a 2‐methoxyethanol route. Amorphous PZT with a Zr/Ti ratio of 52/48 was then deposited on the seed layer using the same synthesis route and subsequently crystallized in situ during XRD . During heating, a tetragonal‐to‐cubic transformation of the seed layer occurs prior to the formation of perovskite PZT . Subsequent nucleation of the crystalline PZT occurs in the cubic phase. Simultaneous to nucleation of PZT , development of a dominant 100 texture component was observed in the PZT phase of the thin films. The results indicate that 100 textured PTO nucleates 100 texture of PZT thin films during crystallization.

Authors:
 [1];  [1];  [1];  [1];  [2];  [3];  [3];  [4];
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  1. Korea Institute of Industrial Technology Gaetbeol‐ro 156 Yeonsu‐gu Incheon 406‐840 Korea
  2. Advanced Photon Source Argonne National Laboratory Argonne Illinois 60439
  3. U.S. Army Research Laboratory PiezoMEMS Adelphi Maryland 20783
  4. Department of Materials Science and Engineering North Carolina State University Raleigh North Carolina 27695
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401373
Grant/Contract Number:  
DE‐AC02‐06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of the American Ceramic Society
Additional Journal Information:
Journal Name: Journal of the American Ceramic Society Journal Volume: 98 Journal Issue: 5; Journal ID: ISSN 0002-7820
Publisher:
Wiley-Blackwell
Country of Publication:
United States
Language:
English

Citation Formats

Mhin, Sungwook, Nittala, Krishna, Cozzan, Clayton, Kim, Kyeongwon, Robinson, Douglas S., Sanchez, Luz M., Polcawich, Ronald G., Jones, Jacob L., and Trolier‐McKins, ed., S. Role of the PbTiO 3 Seed Layer on the Crystallization Behavior of PZT Thin Films. United States: N. p., 2015. Web. doi:10.1111/jace.13468.
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Mhin, Sungwook, Nittala, Krishna, Cozzan, Clayton, Kim, Kyeongwon, Robinson, Douglas S., Sanchez, Luz M., Polcawich, Ronald G., Jones, Jacob L., & Trolier‐McKins, ed., S. Role of the PbTiO 3 Seed Layer on the Crystallization Behavior of PZT Thin Films. United States. https://doi.org/10.1111/jace.13468
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Mhin, Sungwook, Nittala, Krishna, Cozzan, Clayton, Kim, Kyeongwon, Robinson, Douglas S., Sanchez, Luz M., Polcawich, Ronald G., Jones, Jacob L., and Trolier‐McKins, ed., S. Fri . "Role of the PbTiO 3 Seed Layer on the Crystallization Behavior of PZT Thin Films". United States. https://doi.org/10.1111/jace.13468.
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@article{osti_1401373,
title = {Role of the PbTiO 3 Seed Layer on the Crystallization Behavior of PZT Thin Films},
author = {Mhin, Sungwook and Nittala, Krishna and Cozzan, Clayton and Kim, Kyeongwon and Robinson, Douglas S. and Sanchez, Luz M. and Polcawich, Ronald G. and Jones, Jacob L. and Trolier‐McKins, ed., S.},
abstractNote = {The role of a highly crystalline and oriented lead titanate ( PTO ) seed layer on the subsequent phase and texture evolution of lead zirconate titanate ( PZT ) thin films is investigated in situ using X‐ray diffraction ( XRD ) during crystallization. Crystalline PTO seed layers were first prepared via a 2‐methoxyethanol route. Amorphous PZT with a Zr/Ti ratio of 52/48 was then deposited on the seed layer using the same synthesis route and subsequently crystallized in situ during XRD . During heating, a tetragonal‐to‐cubic transformation of the seed layer occurs prior to the formation of perovskite PZT . Subsequent nucleation of the crystalline PZT occurs in the cubic phase. Simultaneous to nucleation of PZT , development of a dominant 100 texture component was observed in the PZT phase of the thin films. The results indicate that 100 textured PTO nucleates 100 texture of PZT thin films during crystallization.},
doi = {10.1111/jace.13468},
journal = {Journal of the American Ceramic Society},
number = 5,
volume = 98,
place = {United States},
year = {Fri Feb 06 00:00:00 EST 2015},
month = {Fri Feb 06 00:00:00 EST 2015}
}
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https://doi.org/10.1111/jace.13468
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