Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering
Abstract
We present that despite the vast number of publication dealing with ZIF-8, the performance of this zeolitic MOF upon adsorption is still a matter of debate. The understanding of its adsorption properties its of great importance to define its potential in aplications such as gas separation, sensing and catalytic processes. Using inelastic neutron scattering (INS) upon exposure to different probe molecules we get further insight about the adsortion performance at cryogenic temperatures, including the possible swinging of the imidazolate linkers.
- Authors:
-
[2];
[2];
[1]
- Universidad de Alicante, San Vicente del Raspeig (Spain)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1488727
- Alternate Identifier(s):
- OSTI ID: 1401315
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemistry Select
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 9; Journal ID: ISSN 2365-6549
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; breathing; flexibility; Inelastic Neutron Scattering; swinging; ZIF-8
Citation Formats
Casco, Mirian E., Fernández-Catalá, Javier, Cheng, Yongqiang, Daemen, Luke L., Ramirez-Cuesta, Anibal J., Cuadrado-Collados, Carlos, Silvestre-Albero, Joaquin, and Ramos-Fernandez, Enrique V. Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering. United States: N. p., 2017.
Web. doi:10.1002/slct.201700250.
Casco, Mirian E., Fernández-Catalá, Javier, Cheng, Yongqiang, Daemen, Luke L., Ramirez-Cuesta, Anibal J., Cuadrado-Collados, Carlos, Silvestre-Albero, Joaquin, & Ramos-Fernandez, Enrique V. Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering. United States. https://doi.org/10.1002/slct.201700250
Casco, Mirian E., Fernández-Catalá, Javier, Cheng, Yongqiang, Daemen, Luke L., Ramirez-Cuesta, Anibal J., Cuadrado-Collados, Carlos, Silvestre-Albero, Joaquin, and Ramos-Fernandez, Enrique V. Thu .
"Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering". United States. https://doi.org/10.1002/slct.201700250. https://www.osti.gov/servlets/purl/1488727.
@article{osti_1488727,
title = {Understanding ZIF-8 Performance upon Gas Adsorption by Means of Inelastic Neutron Scattering},
author = {Casco, Mirian E. and Fernández-Catalá, Javier and Cheng, Yongqiang and Daemen, Luke L. and Ramirez-Cuesta, Anibal J. and Cuadrado-Collados, Carlos and Silvestre-Albero, Joaquin and Ramos-Fernandez, Enrique V.},
abstractNote = {We present that despite the vast number of publication dealing with ZIF-8, the performance of this zeolitic MOF upon adsorption is still a matter of debate. The understanding of its adsorption properties its of great importance to define its potential in aplications such as gas separation, sensing and catalytic processes. Using inelastic neutron scattering (INS) upon exposure to different probe molecules we get further insight about the adsortion performance at cryogenic temperatures, including the possible swinging of the imidazolate linkers.},
doi = {10.1002/slct.201700250},
journal = {Chemistry Select},
number = 9,
volume = 2,
place = {United States},
year = {Thu Mar 23 00:00:00 EDT 2017},
month = {Thu Mar 23 00:00:00 EDT 2017}
}
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Cited by: 21 works
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Figures / Tables:
Figure 1.: Adsorption isotherms of different gases at 77K in ZIF-8.
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Works referencing / citing this record:
Neutron Instruments for Research in Coordination Chemistry: Neutron Instruments for Research in Coordination Chemistry
journal, January 2019
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New insights into the breathing phenomenon in ZIF-4
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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.