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Title: Effects of macromolecular configuration of thermally sensitive binder in lithium‐ion battery

Abstract

ABSTRACT In order to suppress heat generation of nail‐penetrated lithium‐ion battery (LIB) cell, thermally sensitive binders (TSB) based on poly(vinylidene fluoride) (PVDF) and poly(vinylidene fluoride‐ co ‐hexafluoropropylene) (PVDF‐HFP) were investigated. The testing data showed that with appropriate treatment, TSB could efficiently reduce the peak temperature associated with internal shorting, and did not influence the cycling performance of LIB. The molecular weight of TSB was not a vital factor, while crosslinking was critical. This technology can be used to mitigate thermal runaway of LIB, enabling safe and robust large‐scale energy storage. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45078.

Authors:
 [1];  [1];  [2];  [2];  [3];  [3];  [3];  [4]
+ Show Author Affiliations
  1. Department of Structural Engineering University of California—San Diego La Jolla California 92093‐0085
  2. Program of Materials Science and Engineering University of California—San Diego La Jolla California 92093
  3. Department of Nanoengineering University of California—San Diego La Jolla California 92093
  4. Department of Structural Engineering University of California—San Diego La Jolla California 92093‐0085, Program of Materials Science and Engineering University of California—San Diego La Jolla California 92093
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401312
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Applied Polymer Science
Additional Journal Information:
Journal Name: Journal of Applied Polymer Science Journal Volume: 134 Journal Issue: 31; Journal ID: ISSN 0021-8995
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States
Language:
English

Citation Formats

Le, Anh V., Wang, Meng, Noelle, Daniel J., Shi, Yang, Yoon, Hyojung, Zhang, Minghao, Meng, Y. Shirley, and Qiao, Yu. Effects of macromolecular configuration of thermally sensitive binder in lithium‐ion battery. United States: N. p., 2017. Web. doi:10.1002/app.45078.
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Le, Anh V., Wang, Meng, Noelle, Daniel J., Shi, Yang, Yoon, Hyojung, Zhang, Minghao, Meng, Y. Shirley, & Qiao, Yu. Effects of macromolecular configuration of thermally sensitive binder in lithium‐ion battery. United States. https://doi.org/10.1002/app.45078
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Le, Anh V., Wang, Meng, Noelle, Daniel J., Shi, Yang, Yoon, Hyojung, Zhang, Minghao, Meng, Y. Shirley, and Qiao, Yu. Wed . "Effects of macromolecular configuration of thermally sensitive binder in lithium‐ion battery". United States. https://doi.org/10.1002/app.45078.
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@article{osti_1401312,
title = {Effects of macromolecular configuration of thermally sensitive binder in lithium‐ion battery},
author = {Le, Anh V. and Wang, Meng and Noelle, Daniel J. and Shi, Yang and Yoon, Hyojung and Zhang, Minghao and Meng, Y. Shirley and Qiao, Yu},
abstractNote = {ABSTRACT In order to suppress heat generation of nail‐penetrated lithium‐ion battery (LIB) cell, thermally sensitive binders (TSB) based on poly(vinylidene fluoride) (PVDF) and poly(vinylidene fluoride‐ co ‐hexafluoropropylene) (PVDF‐HFP) were investigated. The testing data showed that with appropriate treatment, TSB could efficiently reduce the peak temperature associated with internal shorting, and did not influence the cycling performance of LIB. The molecular weight of TSB was not a vital factor, while crosslinking was critical. This technology can be used to mitigate thermal runaway of LIB, enabling safe and robust large‐scale energy storage. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45078.},
doi = {10.1002/app.45078},
journal = {Journal of Applied Polymer Science},
number = 31,
volume = 134,
place = {United States},
year = {Wed Apr 19 00:00:00 EDT 2017},
month = {Wed Apr 19 00:00:00 EDT 2017}
}
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Journal Article:
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Accepted Manuscript (Publisher)
Publisher's Version of Record
https://doi.org/10.1002/app.45078
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