Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS 2 Nanosheets: The Dual Interfacial Effect
Abstract
Abstract Hydrogen generation via electrocatalytic water splitting holds great promise for future energy revolution. It is desirable to design abundant and efficient catalysts and achieve mechanistic understanding of hydrogen evolution reaction (HER). Here, this paper reports a strategy for improving HER performance of molybdenum disulfide (MoS 2 ) via introducing gold nanoclusters as a cocatalyst. Compared to plain MoS 2 nanosheets, the Au 25 (SR) 18 /MoS 2 nanocomposite exhibits enhanced HER activity with a small onset potential of −0.20 V (vs reversible hydrogen electrode) and a higher current density of 59.3 mA cm −2 at the potential of −0.4 V. In addition to the interfacial interaction between nanoclusters and MoS 2 , the interface between the Au 25 core and the surface ligands (thiolate vs selenolate) is also discovered to distinctly affect the catalytic performance. This work highlights the promise of metal nanoclusters in boosting the HER performance via tailoring the interfacial electronic interactions between gold nanoclusters and MoS 2 nanosheets, as well as the interface between metal core and surface ligands.
- Authors:
-
- Department of Chemistry Carnegie Mellon University Pittsburgh PA 15213 USA
- Chemical and Petroleum Engineering, and Physics University of Pittsburgh Pittsburgh PA 15261 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1401309
- Grant/Contract Number:
- DE FG02‐03ER15476
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Small
- Additional Journal Information:
- Journal Name: Small Journal Volume: 13 Journal Issue: 43; Journal ID: ISSN 1613-6810
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Zhao, Shuo, Jin, Renxi, Song, Yongbo, Zhang, Hui, House, Stephen D., Yang, Judith C., and Jin, Rongchao. Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS 2 Nanosheets: The Dual Interfacial Effect. Germany: N. p., 2017.
Web. doi:10.1002/smll.201701519.
Zhao, Shuo, Jin, Renxi, Song, Yongbo, Zhang, Hui, House, Stephen D., Yang, Judith C., & Jin, Rongchao. Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS 2 Nanosheets: The Dual Interfacial Effect. Germany. https://doi.org/10.1002/smll.201701519
Zhao, Shuo, Jin, Renxi, Song, Yongbo, Zhang, Hui, House, Stephen D., Yang, Judith C., and Jin, Rongchao. Mon .
"Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS 2 Nanosheets: The Dual Interfacial Effect". Germany. https://doi.org/10.1002/smll.201701519.
@article{osti_1401309,
title = {Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS 2 Nanosheets: The Dual Interfacial Effect},
author = {Zhao, Shuo and Jin, Renxi and Song, Yongbo and Zhang, Hui and House, Stephen D. and Yang, Judith C. and Jin, Rongchao},
abstractNote = {Abstract Hydrogen generation via electrocatalytic water splitting holds great promise for future energy revolution. It is desirable to design abundant and efficient catalysts and achieve mechanistic understanding of hydrogen evolution reaction (HER). Here, this paper reports a strategy for improving HER performance of molybdenum disulfide (MoS 2 ) via introducing gold nanoclusters as a cocatalyst. Compared to plain MoS 2 nanosheets, the Au 25 (SR) 18 /MoS 2 nanocomposite exhibits enhanced HER activity with a small onset potential of −0.20 V (vs reversible hydrogen electrode) and a higher current density of 59.3 mA cm −2 at the potential of −0.4 V. In addition to the interfacial interaction between nanoclusters and MoS 2 , the interface between the Au 25 core and the surface ligands (thiolate vs selenolate) is also discovered to distinctly affect the catalytic performance. This work highlights the promise of metal nanoclusters in boosting the HER performance via tailoring the interfacial electronic interactions between gold nanoclusters and MoS 2 nanosheets, as well as the interface between metal core and surface ligands.},
doi = {10.1002/smll.201701519},
journal = {Small},
number = 43,
volume = 13,
place = {Germany},
year = {Mon Jul 24 00:00:00 EDT 2017},
month = {Mon Jul 24 00:00:00 EDT 2017}
}
https://doi.org/10.1002/smll.201701519
Web of Science
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