Porous Structure Design of Polymeric Membranes for Gas Separation

Zhang, Jinshui; Schott, Jennifer Ann; Mahurin, Shannon Mark; Dai, Sheng

doi:10.1002/smtd.201600051

Title: Porous Structure Design of Polymeric Membranes for Gas Separation

Abstract

High-performance polymeric membranes for gas separation are of interest for molecular-level separations in industrial-scale chemical, energy and environmental processes. To overcome the inherent trade-off relationship between permeability and selectivity, the creation of permanent microporosity in polymeric matrices is highly desirable because the porous structures can provide a high fractional free volume to facilitate gas transport through the dense layer. In this feature article, recent developments in the formation of porous polymeric membranes and potential strategies for pore structure design are reviewed.

Authors:

^[1]; Schott, Jennifer Ann ^[2];

^[1];

^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Publication Date:: Tue Apr 04 00:00:00 EDT 2017

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1412064

Alternate Identifier(s):: OSTI ID: 1401297

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Small Methods

Additional Journal Information:: Journal Volume: 1; Journal Issue: 5; Journal ID: ISSN 2366-9608

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; gas separation; membrane technology; polymeric membranes; porous structures

Citation Formats


                    Zhang, Jinshui, Schott, Jennifer Ann, Mahurin, Shannon Mark, and Dai, Sheng. Porous Structure Design of Polymeric Membranes for Gas Separation.  United States: N. p., 2017. 
Web.  doi:10.1002/smtd.201600051.

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                    Zhang, Jinshui, Schott, Jennifer Ann, Mahurin, Shannon Mark, & Dai, Sheng. Porous Structure Design of Polymeric Membranes for Gas Separation.  United States.  https://doi.org/10.1002/smtd.201600051

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                    Zhang, Jinshui, Schott, Jennifer Ann, Mahurin, Shannon Mark, and Dai, Sheng. Tue .  
"Porous Structure Design of Polymeric Membranes for Gas Separation".  United States.  https://doi.org/10.1002/smtd.201600051.  https://www.osti.gov/servlets/purl/1412064.

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@article{osti_1412064,

  title        = {Porous Structure Design of Polymeric Membranes for Gas Separation},

  author       = {Zhang, Jinshui and Schott, Jennifer Ann and Mahurin, Shannon Mark and Dai, Sheng},

  abstractNote = {High-performance polymeric membranes for gas separation are of interest for molecular-level separations in industrial-scale chemical, energy and environmental processes. To overcome the inherent trade-off relationship between permeability and selectivity, the creation of permanent microporosity in polymeric matrices is highly desirable because the porous structures can provide a high fractional free volume to facilitate gas transport through the dense layer. In this feature article, recent developments in the formation of porous polymeric membranes and potential strategies for pore structure design are reviewed.},

  doi          = {10.1002/smtd.201600051},

  journal      = {Small Methods},

  number       = 5,

  volume       = 1,

  place        = {United States},

  year         = {Tue Apr 04 00:00:00 EDT 2017},

  month        = {Tue Apr 04 00:00:00 EDT 2017}

}

Copy to clipboard

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https://doi.org/10.1002/smtd.201600051

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Cited by: 42 works

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Works referenced in this record:

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Works referencing / citing this record:

Electrostatic-Assisted Liquefaction of Porous Carbons
journal, October 2017

Li, Peipei; Schott, Jennifer A.; Zhang, Jinshui
Angewandte Chemie International Edition, Vol. 56, Issue 47
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Recent Advances of Gas Transport Channels Constructed with Different Dimensional Nanomaterials in Mixed‐Matrix Membranes for CO ₂ Separation
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Wang, Bo; Sheng, Menglong; Xu, Jiayou
Small Methods, Vol. 4, Issue 3
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Electrostatic-Assisted Liquefaction of Porous Carbons
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Li, Peipei; Schott, Jennifer A.; Zhang, Jinshui
Angewandte Chemie, Vol. 129, Issue 47
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Membranes with Intrinsic Micro-Porosity: Structure, Solubility, and Applications
journal, December 2018

Zhou, Haoli; Jin, Wanqin
Membranes, Vol. 9, Issue 1
DOI: 10.3390/membranes9010003

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Similar Records

Title: Porous Structure Design of Polymeric Membranes for Gas Separation

Abstract

Citation Formats

Polymer of Intrinsic Microporosity Incorporating Thioamide Functionality: Preparation and Gas Transport Properties journal, August 2011

Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage journal, January 2006

Phthalocyanine-based nanoporous network polymers journal, October 2002

High-Performance Thermally Self-Cross-Linked Polymer of Intrinsic Microporosity (PIM-1) Membranes for Energy Development journal, January 2012

Design and Preparation of Porous Polymers journal, April 2012

A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals journal, November 2010

Poly(ionic liquid)/Ionic Liquid Ion-Gels with High “Free” Ionic Liquid Content: Platform Membrane Materials for CO 2 /Light Gas Separations journal, April 2016

Nanoporous Organic Polymer/Cage Composite Membranes journal, December 2012

Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation journal, January 2012

Porous Materials and Supercritical Fluids journal, July 2003

Polymer nanosieve membranes for CO2-capture applications journal, April 2011

Membrane separation processes: Current relevance and future opportunities journal, May 2001

Photo-oxidative enhancement of polymeric molecular sieve membranes journal, May 2013

Challenges and opportunities for mixed-matrix membranes for gas separation journal, January 2013

Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis journal, April 2008

Membrane-based gas separation journal, August 1993

Pushing the limits on possibilities for large scale gas separation: which strategies? journal, August 2000

Controlled thermal oxidative crosslinking of polymers of intrinsic microporosity towards tunable molecular sieve membranes journal, September 2014

Recent advances of inorganic fillers in mixed matrix membrane for gas separation journal, October 2011

Polymers of Intrinsic Microporosity (PIMs): High Free Volume Polymers for Membrane Applications journal, December 2006

Recent Development of Hypercrosslinked Microporous Organic Polymers journal, January 2013

Guest-Induced Breathing Effect in a Flexible Molecular Crystal journal, February 2016

Star-shaped two-dimensional covalent organic frameworks journal, January 2013

Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation journal, December 2014

Hierarchically Structured Nanoporous Poly(Ionic Liquid) Membranes: Facile Preparation and Application in Fiber-Optic pH Sensing journal, April 2013

Rigid and microporous polymers for gas separation membranes journal, April 2015

Linear High Molecular Weight Ladder Polymers by Optimized Polycondensation of Tetrahydroxytetramethylspirobisindane and 1,4-Dicyanotetrafluorobenzene † journal, October 2008

Gas separation using polymer membranes: an overview journal, November 1994

Membrane Technology and Applications book, July 2012

Metal–organic framework nanosheets in polymer composite materials for gas separation journal, November 2014

Mixed matrix membranes using carbon molecular sieves journal, January 2003

Membrane-Based Gas Separation Accelerated by Hollow Nanosphere Architectures journal, November 2016

Super absorbent conjugated microporous polymers: a synergistic structural effect on the exceptional uptake of amines journal, January 2013

Polymeric Gas Separation Membranes journal, March 2012

Porous Nanosized Particles: Preparation, Properties, and Applications journal, May 2013

Gas Separation with Polymer Membranes journal, November 1998

Future Directions of Membrane Gas Separation Technology journal, March 2002

Porous Organic Cage Thin Films and Molecular-Sieving Membranes journal, January 2016

Porous, Fluorescent, Covalent Triazine-Based Frameworks Via Room-Temperature and Microwave-Assisted Synthesis journal, April 2012

Recent Progress in the Synthesis of Porous Carbon Materials journal, August 2006

The upper bound revisited journal, July 2008

A Superacid-Catalyzed Synthesis of Porous Membranes Based on Triazine Frameworks for CO2 Separation journal, June 2012

Designing the Next Generation of Chemical Separation Membranes journal, May 2011

Membrane Gas Separation: A Review/State of the Art journal, May 2009

Polymeric molecular sieve membranes via in situ cross-linking of non-porous polymer membrane templates journal, April 2014

Electrostatic-Assisted Liquefaction of Porous Carbons journal, October 2017

Recent Advances of Gas Transport Channels Constructed with Different Dimensional Nanomaterials in Mixed‐Matrix Membranes for CO 2 Separation journal, January 2020

Electrostatic-Assisted Liquefaction of Porous Carbons journal, October 2017

Membranes with Intrinsic Micro-Porosity: Structure, Solubility, and Applications journal, December 2018

Polymer of Intrinsic Microporosity Incorporating Thioamide Functionality: Preparation and Gas Transport Properties
journal, August 2011

Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage
journal, January 2006

Phthalocyanine-based nanoporous network polymers
journal, October 2002

High-Performance Thermally Self-Cross-Linked Polymer of Intrinsic Microporosity (PIM-1) Membranes for Energy Development
journal, January 2012

Design and Preparation of Porous Polymers
journal, April 2012

A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals
journal, November 2010

Poly(ionic liquid)/Ionic Liquid Ion-Gels with High “Free” Ionic Liquid Content: Platform Membrane Materials for CO ₂ /Light Gas Separations
journal, April 2016

Nanoporous Organic Polymer/Cage Composite Membranes
journal, December 2012

Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation
journal, January 2012

Porous Materials and Supercritical Fluids
journal, July 2003

Polymer nanosieve membranes for CO₂-capture applications
journal, April 2011

Membrane separation processes: Current relevance and future opportunities
journal, May 2001

Photo-oxidative enhancement of polymeric molecular sieve membranes
journal, May 2013

Challenges and opportunities for mixed-matrix membranes for gas separation
journal, January 2013

Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis
journal, April 2008

Membrane-based gas separation
journal, August 1993

Pushing the limits on possibilities for large scale gas separation: which strategies?
journal, August 2000

Controlled thermal oxidative crosslinking of polymers of intrinsic microporosity towards tunable molecular sieve membranes
journal, September 2014

Recent advances of inorganic fillers in mixed matrix membrane for gas separation
journal, October 2011

Polymers of Intrinsic Microporosity (PIMs): High Free Volume Polymers for Membrane Applications
journal, December 2006

Recent Development of Hypercrosslinked Microporous Organic Polymers
journal, January 2013

Guest-Induced Breathing Effect in a Flexible Molecular Crystal
journal, February 2016

Star-shaped two-dimensional covalent organic frameworks
journal, January 2013

Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation
journal, December 2014

Hierarchically Structured Nanoporous Poly(Ionic Liquid) Membranes: Facile Preparation and Application in Fiber-Optic pH Sensing
journal, April 2013

Rigid and microporous polymers for gas separation membranes
journal, April 2015

Linear High Molecular Weight Ladder Polymers by Optimized Polycondensation of Tetrahydroxytetramethylspirobisindane and 1,4-Dicyanotetrafluorobenzene ^†
journal, October 2008

Gas separation using polymer membranes: an overview
journal, November 1994

Membrane Technology and Applications
book, July 2012

Metal–organic framework nanosheets in polymer composite materials for gas separation
journal, November 2014

Mixed matrix membranes using carbon molecular sieves
journal, January 2003

Membrane-Based Gas Separation Accelerated by Hollow Nanosphere Architectures
journal, November 2016

Super absorbent conjugated microporous polymers: a synergistic structural effect on the exceptional uptake of amines
journal, January 2013

Polymeric Gas Separation Membranes
journal, March 2012

Porous Nanosized Particles: Preparation, Properties, and Applications
journal, May 2013

Gas Separation with Polymer Membranes
journal, November 1998

Future Directions of Membrane Gas Separation Technology
journal, March 2002

Porous Organic Cage Thin Films and Molecular-Sieving Membranes
journal, January 2016

Porous, Fluorescent, Covalent Triazine-Based Frameworks Via Room-Temperature and Microwave-Assisted Synthesis
journal, April 2012

Recent Progress in the Synthesis of Porous Carbon Materials
journal, August 2006

The upper bound revisited
journal, July 2008

A Superacid-Catalyzed Synthesis of Porous Membranes Based on Triazine Frameworks for CO₂ Separation
journal, June 2012

Designing the Next Generation of Chemical Separation Membranes
journal, May 2011

Membrane Gas Separation: A Review/State of the Art
journal, May 2009

Polymeric molecular sieve membranes via in situ cross-linking of non-porous polymer membrane templates
journal, April 2014

Electrostatic-Assisted Liquefaction of Porous Carbons
journal, October 2017

Recent Advances of Gas Transport Channels Constructed with Different Dimensional Nanomaterials in Mixed‐Matrix Membranes for CO ₂ Separation
journal, January 2020

Electrostatic-Assisted Liquefaction of Porous Carbons
journal, October 2017

Membranes with Intrinsic Micro-Porosity: Structure, Solubility, and Applications
journal, December 2018