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Title: New Paradigms on the Nature of Solid Electrolyte Interphase Formation and Capacity Fading of Hard Carbon Anodes in Na-Ion Batteries

Authors:
 [1];  [1];  [1];  [2];  [3];  [1]
  1. Department of Chemistry, Oregon State University, Corvallis OR 97331 USA
  2. Hewlett-Packard Co, 1000 NE Circle Blvd Corvallis OR 97330 USA
  3. Bourns College of Engineering, University of California, Riverside CA 92521 USA
Publication Date:
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1401231
Grant/Contract Number:  
AR0000297TDD
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials Interfaces
Additional Journal Information:
Journal Name: Advanced Materials Interfaces Journal Volume: 3 Journal Issue: 19; Journal ID: ISSN 2196-7350
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Bommier, Clement, Leonard, Daniel, Jian, Zelang, Stickle, William F., Greaney, P. Alex, and Ji, Xiulei. New Paradigms on the Nature of Solid Electrolyte Interphase Formation and Capacity Fading of Hard Carbon Anodes in Na-Ion Batteries. Germany: N. p., 2016. Web. doi:10.1002/admi.201600449.
Bommier, Clement, Leonard, Daniel, Jian, Zelang, Stickle, William F., Greaney, P. Alex, & Ji, Xiulei. New Paradigms on the Nature of Solid Electrolyte Interphase Formation and Capacity Fading of Hard Carbon Anodes in Na-Ion Batteries. Germany. doi:10.1002/admi.201600449.
Bommier, Clement, Leonard, Daniel, Jian, Zelang, Stickle, William F., Greaney, P. Alex, and Ji, Xiulei. Thu . "New Paradigms on the Nature of Solid Electrolyte Interphase Formation and Capacity Fading of Hard Carbon Anodes in Na-Ion Batteries". Germany. doi:10.1002/admi.201600449.
@article{osti_1401231,
title = {New Paradigms on the Nature of Solid Electrolyte Interphase Formation and Capacity Fading of Hard Carbon Anodes in Na-Ion Batteries},
author = {Bommier, Clement and Leonard, Daniel and Jian, Zelang and Stickle, William F. and Greaney, P. Alex and Ji, Xiulei},
abstractNote = {},
doi = {10.1002/admi.201600449},
journal = {Advanced Materials Interfaces},
number = 19,
volume = 3,
place = {Germany},
year = {2016},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/admi.201600449

Citation Metrics:
Cited by: 42 works
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Works referenced in this record:

Self-cleaning and handle properties of TiO2-modified textiles
journal, August 2009

  • Veronovski, Nika; Rudolf, Andreja; Smole, Majda Sfiligoj
  • Fibers and Polymers, Vol. 10, Issue 4
  • DOI: 10.1007/s12221-009-0551-5

Hard Carbon Microtubes Made from Renewable Cotton as High-Performance Anode Material for Sodium-Ion Batteries
journal, June 2016

  • Li, Yunming; Hu, Yong-Sheng; Titirici, Maria-Magdalena
  • Advanced Energy Materials, Vol. 6, Issue 18
  • DOI: 10.1002/aenm.201600659

Synergistic Na-Storage Reactions in Sn 4 P 3 as a High-Capacity, Cycle-stable Anode of Na-Ion Batteries
journal, March 2014

  • Qian, Jiangfeng; Xiong, Ya; Cao, Yuliang
  • Nano Letters, Vol. 14, Issue 4
  • DOI: 10.1021/nl404637q

Formation of TiO x films produced by high-power pulsed magnetron sputtering
journal, February 2008


Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors
journal, September 2012

  • Choi, Nam-Soon; Chen, Zonghai; Freunberger, Stefan A.
  • Angewandte Chemie International Edition, Vol. 51, Issue 40
  • DOI: 10.1002/anie.201201429

Predicting capacity of hard carbon anodes in sodium-ion batteries using porosity measurements
journal, September 2014


Tin and graphite based nanocomposites: Potential anode for sodium ion batteries
journal, March 2013


Monodisperse Antimony Nanocrystals for High-Rate Li-ion and Na-ion Battery Anodes: Nano versus Bulk
journal, February 2014

  • He, Meng; Kravchyk, Kostiantyn; Walter, Marc
  • Nano Letters, Vol. 14, Issue 3
  • DOI: 10.1021/nl404165c

Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000


Graphene oxide wrapped croconic acid disodium salt for sodium ion battery electrodes
journal, March 2014


Challenges for Na-ion Negative Electrodes
journal, January 2011

  • Chevrier, V. L.; Ceder, G.
  • Journal of The Electrochemical Society, Vol. 158, Issue 9
  • DOI: 10.1149/1.3607983

High Capacity Anode Materials for Rechargeable Sodium-Ion Batteries
journal, January 2000

  • Stevens, D. A.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 147, Issue 4
  • DOI: 10.1149/1.1393348

A superior low-cost amorphous carbon anode made from pitch and lignin for sodium-ion batteries
journal, January 2016

  • Li, Yunming; Hu, Yong-Sheng; Li, Hong
  • Journal of Materials Chemistry A, Vol. 4, Issue 1
  • DOI: 10.1039/C5TA08601A

Conductivity and Solvation of Li + Ions of LiPF 6 in Propylene Carbonate Solutions
journal, May 2000

  • Kondo, Kazutaka; Sano, Mitsuru; Hiwara, Akio
  • The Journal of Physical Chemistry B, Vol. 104, Issue 20
  • DOI: 10.1021/jp000142f

Amorphous Phosphorus/Nitrogen-Doped Graphene Paper for Ultrastable Sodium-Ion Batteries
journal, February 2016


Low-Potential Sodium Insertion in a NASICON-Type Structure through the Ti(III)/Ti(II) Redox Couple
journal, March 2013

  • Senguttuvan, P.; Rousse, G.; Arroyo y. de Dompablo, M. E.
  • Journal of the American Chemical Society, Vol. 135, Issue 10
  • DOI: 10.1021/ja311044t

Tin and Tin Compounds for Sodium Ion Battery Anodes: Phase Transformations and Performance
journal, May 2015


The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries
journal, January 1995

  • Aurbach, Doron
  • Journal of The Electrochemical Society, Vol. 142, Issue 9
  • DOI: 10.1149/1.2048658

Biomass carbon & its prospects in electrochemical energy systems
journal, April 2013


Low-Surface-Area Hard Carbon Anode for Na-Ion Batteries via Graphene Oxide as a Dehydration Agent
journal, January 2015

  • Luo, Wei; Bommier, Clement; Jian, Zelang
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 4
  • DOI: 10.1021/am507679x

On the Comparative Stability of Li and Na Metal Anode Interfaces in Conventional Alkyl Carbonate Electrolytes
journal, January 2015

  • Iermakova, D. I.; Dugas, R.; Palacín, M. R.
  • Journal of The Electrochemical Society, Vol. 162, Issue 13
  • DOI: 10.1149/2.0091513jes

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


The behaviour of lithium electrodes in propylene and ethylene carbonate: Te major factors that influence Li cycling efficiency
journal, November 1992

  • Aurbach, Doron; Gofer, Yosef; Ben-Zion, Moshe
  • Journal of Electroanalytical Chemistry, Vol. 339, Issue 1-2
  • DOI: 10.1016/0022-0728(92)80467-I

Raman spectroscopy as a versatile tool for studying the properties of graphene
journal, April 2013


Lyocell fibers as the precursor of carbon fibers
journal, September 2003

  • Peng, Shunjin; Shao, Huili; Hu, Xuechao
  • Journal of Applied Polymer Science, Vol. 90, Issue 7
  • DOI: 10.1002/app.12879

Nanocrystalline anatase TiO2: a new anode material for rechargeable sodium ion batteries
journal, January 2013

  • Xu, Yang; Memarzadeh Lotfabad, Elmira; Wang, Huanlei
  • Chemical Communications, Vol. 49, Issue 79
  • DOI: 10.1039/c3cc45254a

Defective Graphene as a High-Capacity Anode Material for Na- and Ca-Ion Batteries
journal, January 2014

  • Datta, Dibakar; Li, Junwen; Shenoy, Vivek B.
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 3
  • DOI: 10.1021/am404788e

Advanced Sodium Ion Battery Anode Constructed via Chemical Bonding between Phosphorus, Carbon Nanotube, and Cross-Linked Polymer Binder
journal, October 2015


Na 2 Ti 3 O 7 : Lowest Voltage Ever Reported Oxide Insertion Electrode for Sodium Ion Batteries
journal, September 2011

  • Senguttuvan, Premkumar; Rousse, Gwenaëlle; Seznec, Vincent
  • Chemistry of Materials, Vol. 23, Issue 18
  • DOI: 10.1021/cm202076g

A sodium-ion battery exploiting layered oxide cathode, graphite anode and glyme-based electrolyte
journal, April 2016


Engraving Copper Foil to Give Large-Scale Binder-Free Porous CuO Arrays for a High-Performance Sodium-Ion Battery Anode
journal, January 2014

  • Yuan, Shuang; Huang, Xiao-lei; Ma, De-long
  • Advanced Materials, Vol. 26, Issue 14
  • DOI: 10.1002/adma.201304469

Density Functional Theory Calculations of Alkali Metal (Li, Na, and K) Graphite Intercalation Compounds
journal, December 2013

  • Okamoto, Yasuharu
  • The Journal of Physical Chemistry C, Vol. 118, Issue 1
  • DOI: 10.1021/jp4063753

SnO2@MWCNT nanocomposite as a high capacity anode material for sodium-ion batteries
journal, April 2013


Few-Layered SnS 2 on Few-Layered Reduced Graphene Oxide as Na-Ion Battery Anode with Ultralong Cycle Life and Superior Rate Capability
journal, November 2014

  • Zhang, Yandong; Zhu, Peiyi; Huang, Liliang
  • Advanced Functional Materials, Vol. 25, Issue 3
  • DOI: 10.1002/adfm.201402833

A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries
journal, January 2015

  • Han, Man Huon; Gonzalo, Elena; Singh, Gurpreet
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE03192J

High-Density Sodium and Lithium Ion Battery Anodes from Banana Peels
journal, June 2014

  • Lotfabad, Elmira Memarzadeh; Ding, Jia; Cui, Kai
  • ACS Nano, Vol. 8, Issue 7, p. 7115-7129
  • DOI: 10.1021/nn502045y

Ageing mechanisms in lithium-ion batteries
journal, September 2005


Composition analysis of the passive film on the carbon electrode of a lithium-ion battery with an EC-based electrolyte
journal, March 1998


Sodium Storage and Transport Properties in Layered Na 2 Ti 3 O 7 for Room-Temperature Sodium-Ion Batteries
journal, May 2013


Green and Facile Fabrication of MWNTs@Sb 2 S 3 @PPy Coaxial Nanocables for High-Performance Na-Ion Batteries
journal, March 2016

  • Wang, Sai; Yuan, Shuang; Yin, Yan-Bin
  • Particle & Particle Systems Characterization, Vol. 33, Issue 8
  • DOI: 10.1002/ppsc.201500227

Towards high energy density sodium ion batteries through electrolyte optimization
journal, January 2013

  • Ponrouch, Alexandre; Dedryvère, Rémi; Monti, Damien
  • Energy & Environmental Science, Vol. 6, Issue 8
  • DOI: 10.1039/c3ee41379a

Anodes for Sodium Ion Batteries Based on Tin–Germanium–Antimony Alloys
journal, April 2014

  • Farbod, Behdokht; Cui, Kai; Kalisvaart, W. Peter
  • ACS Nano, Vol. 8, Issue 5
  • DOI: 10.1021/nn4063598

Pure Single-Crystalline Na 1.1 V 3 O 7.9 Nanobelts as Superior Cathode Materials for Rechargeable Sodium-Ion Batteries
journal, February 2015


Tin Nanodots Encapsulated in Porous Nitrogen-Doped Carbon Nanofibers as a Free-Standing Anode for Advanced Sodium-Ion Batteries
journal, September 2015


Recent Development on Anodes for Na-Ion Batteries
journal, January 2015


Carbon Nanosheet Frameworks Derived from Peat Moss as High Performance Sodium Ion Battery Anodes
journal, November 2013

  • Ding, Jia; Wang, Huanlei; Li, Zhi
  • ACS Nano, Vol. 7, Issue 12
  • DOI: 10.1021/nn404640c

Electrochemical Insertion of Sodium into Carbon
journal, January 1993

  • Doeff, Marca M.
  • Journal of The Electrochemical Society, Vol. 140, Issue 12
  • DOI: 10.1149/1.2221153

Ultrafast Solvent-Assisted Sodium Ion Intercalation into Highly Crystalline Few-Layered Graphene
journal, December 2015


Carbon nanofibers derived from cellulose nanofibers as a long-life anode material for rechargeable sodium-ion batteries
journal, January 2013

  • Luo, Wei; Schardt, Jenna; Bommier, Clement
  • Journal of Materials Chemistry A, Vol. 1, Issue 36
  • DOI: 10.1039/c3ta12389h

Antimony/Graphitic Carbon Composite Anode for High-Performance Sodium-Ion Batteries
journal, May 2016

  • Zhao, Xin; Vail, Sean A.; Lu, Yuhao
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 22
  • DOI: 10.1021/acsami.6b01761

MoS 2 /Graphene Composite Paper for Sodium-Ion Battery Electrodes
journal, January 2014

  • David, Lamuel; Bhandavat, Romil; Singh, Gurpreet
  • ACS Nano, Vol. 8, Issue 2
  • DOI: 10.1021/nn406156b

Graphene nanosheets, carbon nanotubes, graphite, and activated carbon as anode materials for sodium-ion batteries
journal, January 2015

  • Luo, Xu-Feng; Yang, Cheng-Hsien; Peng, You-Yu
  • Journal of Materials Chemistry A, Vol. 3, Issue 19
  • DOI: 10.1039/C5TA00727E

In search of an optimized electrolyte for Na-ion batteries
journal, January 2012

  • Ponrouch, Alexandre; Marchante, Elena; Courty, Matthieu
  • Energy & Environmental Science, Vol. 5, Issue 9
  • DOI: 10.1039/c2ee22258b

Structure formation of regenerated cellulose materials from NMMO-solutions
journal, November 2001


Sodium Terephthalate as an Organic Anode Material for Sodium Ion Batteries
journal, June 2012

  • Park, Yuwon; Shin, Dong-Seon; Woo, Seung Hee
  • Advanced Materials, Vol. 24, Issue 26
  • DOI: 10.1002/adma.201201205

Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

An Amorphous Red Phosphorus/Carbon Composite as a Promising Anode Material for Sodium Ion Batteries
journal, March 2013


Ultrafine SnO 2 nanoparticle loading onto reduced graphene oxide as anodes for sodium-ion batteries with superior rate and cycling performances
journal, January 2014

  • Wang, Yun-Xiao; Lim, Young-Geun; Park, Min-Sik
  • J. Mater. Chem. A, Vol. 2, Issue 2
  • DOI: 10.1039/C3TA13592F

Integrating 3D Flower-Like Hierarchical Cu 2 NiSnS 4 with Reduced Graphene Oxide as Advanced Anode Materials for Na-Ion Batteries
journal, March 2016

  • Yuan, Shuang; Wang, Sai; Li, Lin
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 14
  • DOI: 10.1021/acsami.6b01725

In Situ Fabrication of Porous Graphene Electrodes for High-Performance Energy Storage
journal, February 2013

  • Wang, Zhong-Li; Xu, Dan; Wang, Heng-Guo
  • ACS Nano, Vol. 7, Issue 3
  • DOI: 10.1021/nn3057388

Vine-like MoS 2 anode materials self-assembled from 1-D nanofibers for high capacity sodium rechargeable batteries
journal, January 2014

  • Ryu, Won-Hee; Jung, Ji-Won; Park, Kyusung
  • Nanoscale, Vol. 6, Issue 19
  • DOI: 10.1039/C4NR02044H

A computational study of Na behavior on graphene
journal, April 2015


High Capacity and Rate Capability of Amorphous Phosphorus for Sodium Ion Batteries
journal, March 2013

  • Qian, Jiangfeng; Wu, Xianyong; Cao, Yuliang
  • Angewandte Chemie International Edition, Vol. 52, Issue 17
  • DOI: 10.1002/anie.201209689

A Raman spectroscopic study of organic electrolyte solutions based on binary solvent systems of ethylene carbonate with low viscosity solvents which dissolve different lithium salts
journal, January 1998

  • Morita, Masayuki; Asai, Yoshiko; Yoshimoto, Nobuko
  • Journal of the Chemical Society, Faraday Transactions, Vol. 94, Issue 23
  • DOI: 10.1039/a806278a

Van der Waals density functional study of the energetics of alkali metal intercalation in graphite
journal, January 2014

  • Wang, Zhaohui; Selbach, Sverre M.; Grande, Tor
  • RSC Adv., Vol. 4, Issue 8
  • DOI: 10.1039/C3RA47187J

Electrochemical impedance study on the low temperature of Li-ion batteries
journal, March 2004


New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon
journal, August 2015


Controlling SEI Formation on SnSb-Porous Carbon Nanofibers for Improved Na Ion Storage
journal, February 2014


Ab initio study of sodium intercalation into disordered carbon
journal, January 2015

  • Tsai, Ping-chun; Chung, Sai-Cheong; Lin, Shih-kang
  • Journal of Materials Chemistry A, Vol. 3, Issue 18
  • DOI: 10.1039/C5TA01443C

SnO2@graphene nanocomposites as anode materials for Na-ion batteries with superior electrochemical performance
journal, January 2013

  • Su, Dawei; Ahn, Hyo-Jun; Wang, Guoxiu
  • Chemical Communications, Vol. 49, Issue 30
  • DOI: 10.1039/c3cc40448j

Crystallography and defect chemistry of solid solutions of vanadium and titanium oxides
journal, June 1969

  • Loehman, R. E.; Rao, C. N. Ramachandra; Honig, Jurgen M.
  • The Journal of Physical Chemistry, Vol. 73, Issue 6
  • DOI: 10.1021/j100726a025

Disodium Terephthalate (Na2C8H4O4) as High Performance Anode Material for Low-Cost Room-Temperature Sodium-Ion Battery
journal, May 2012

  • Zhao, Liang; Zhao, Junmei; Hu, Yong-Sheng
  • Advanced Energy Materials, Vol. 2, Issue 8
  • DOI: 10.1002/aenm.201200166

Expanded graphite as superior anode for sodium-ion batteries
journal, June 2014

  • Wen, Yang; He, Kai; Zhu, Yujie
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5033