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Title: CO 2 Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper

Authors:
 [1];  [2];  [3];  [4];  [3]
  1. Joint Center for Artificial Photosynthesis Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley 94720 CA USA
  2. Joint Center for Artificial Photosynthesis Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley 94720 CA USA, Department of Materials Science and Engineering University of California, Berkeley Berkeley 94720 CA USA
  3. Joint Center for Artificial Photosynthesis Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley 94720 CA USA, Department of Chemical &, Biomolecular Engineering University of California, Berkeley Berkeley 94720 CA USA
  4. Joint Center for Artificial Photosynthesis Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley 94720 CA USA, Department of Materials Science and Engineering University of California, Berkeley Berkeley 94720 CA USA, Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley 94720 CA USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401194
Grant/Contract Number:  
SC0004993
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemElectroChem
Additional Journal Information:
Journal Name: ChemElectroChem Journal Volume: 3 Journal Issue: 6; Journal ID: ISSN 2196-0216
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Kwon, Youngkook, Lum, Yanwei, Clark, Ezra L., Ager, Joel W., and Bell, Alexis T. CO 2 Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper. Germany: N. p., 2016. Web. doi:10.1002/celc.201600068.
Kwon, Youngkook, Lum, Yanwei, Clark, Ezra L., Ager, Joel W., & Bell, Alexis T. CO 2 Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper. Germany. https://doi.org/10.1002/celc.201600068
Kwon, Youngkook, Lum, Yanwei, Clark, Ezra L., Ager, Joel W., and Bell, Alexis T. Sat . "CO 2 Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper". Germany. https://doi.org/10.1002/celc.201600068.
@article{osti_1401194,
title = {CO 2 Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper},
author = {Kwon, Youngkook and Lum, Yanwei and Clark, Ezra L. and Ager, Joel W. and Bell, Alexis T.},
abstractNote = {},
doi = {10.1002/celc.201600068},
journal = {ChemElectroChem},
number = 6,
volume = 3,
place = {Germany},
year = {2016},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/celc.201600068

Citation Metrics:
Cited by: 21 works
Citation information provided by
Web of Science

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Works referenced in this record:

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films
journal, April 2012

  • Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234
  • DOI: 10.1021/ja3010978

The importance of surface morphology in controlling the selectivity of polycrystalline copper for CO2 electroreduction
journal, January 2012

  • Tang, Wei; Peterson, Andrew A.; Varela, Ana Sofia
  • Phys. Chem. Chem. Phys., Vol. 14, Issue 1
  • DOI: 10.1039/C1CP22700A

Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes
journal, June 2013

  • Calle-Vallejo, Federico; Koper, Marc T. M.
  • Angewandte Chemie International Edition, Vol. 52, Issue 28
  • DOI: 10.1002/anie.201301470

Thermodynamic and achievable efficiencies for solar-driven electrochemical reduction of carbon dioxide to transportation fuels
journal, October 2015

  • Singh, Meenesh R.; Clark, Ezra L.; Bell, Alexis T.
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 45
  • DOI: 10.1073/pnas.1519212112

Kinetics and Mechanisms of Cu Electrodissolution in Chloride Media
journal, October 1986

  • Lee, H. P.; Nobe, Ken
  • Journal of The Electrochemical Society, Vol. 133, Issue 10
  • DOI: 10.1149/1.2108335

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
journal, April 2014

  • Li, Christina W.; Ciston, Jim; Kanan, Matthew W.
  • Nature, Vol. 508, Issue 7497
  • DOI: 10.1038/nature13249

Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008


Review: An Economic Perspective on Liquid Solar Fuels
journal, January 2012

  • Newman, John; Hoertz, Paul G.; Bonino, Christopher A.
  • Journal of The Electrochemical Society, Vol. 159, Issue 10
  • DOI: 10.1149/2.046210jes

Grain-Boundary-Dependent CO 2 Electroreduction Activity
journal, April 2015

  • Feng, Xiaofeng; Jiang, Kaili; Fan, Shoushan
  • Journal of the American Chemical Society, Vol. 137, Issue 14
  • DOI: 10.1021/ja5130513

Galvanostatic Pulse Plating of Copper and Copper (I) Halides from Acid Copper (II) Halide Solutions
journal, April 1983

  • Yeow, C. W.; Hibbert, D. B.
  • Journal of The Electrochemical Society, Vol. 130, Issue 4
  • DOI: 10.1149/1.2119804

Electronic and optical properties of Cu, CuO and Cu 2 O studied by electron spectroscopy
journal, April 2012


An Investigation of Thin-Film Ni–Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen
journal, August 2013

  • Louie, Mary W.; Bell, Alexis T.
  • Journal of the American Chemical Society, Vol. 135, Issue 33
  • DOI: 10.1021/ja405351s

Scalable synthesis of hollow Cu 2 O nanocubes with unique optical properties via a simple hydrolysis-based approach
journal, January 2013

  • Liu, Hui; Zhou, Yue; Kulinich, Sergei A.
  • J. Mater. Chem. A, Vol. 1, Issue 2
  • DOI: 10.1039/C2TA00138A

X-ray diffraction and Raman spectroscopic study of nanocrystalline CuO under pressures
journal, February 2002


Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO 2 Electroreduction by Process Conditions
journal, December 2014


Electrochemical synthesis of hierarchical Cu2O stars with enhanced photoelectrochemical properties
journal, February 2012


Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts
journal, March 2015

  • Ren, Dan; Deng, Yilin; Handoko, Albertus Denny
  • ACS Catalysis, Vol. 5, Issue 5
  • DOI: 10.1021/cs502128q

Raman spectra of CuO nanocrystals
journal, May 1999


Stable and selective electrochemical reduction of carbon dioxide to ethylene on copper mesocrystals
journal, January 2015

  • Chen, Chung Shou; Handoko, Albertus D.; Wan, Jane Hui
  • Catalysis Science & Technology, Vol. 5, Issue 1
  • DOI: 10.1039/C4CY00906A

The Reaction of Fluorine with Copper and Some of its Compounds. Some Properties of Copper(II) Fluoride 1
journal, April 1954

  • Haendler, H. M.; Towle, L. H.; Bennett, E. F.
  • Journal of the American Chemical Society, Vol. 76, Issue 8
  • DOI: 10.1021/ja01637a039

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide
journal, January 2015

  • Singh, Meenesh R.; Clark, Ezra L.; Bell, Alexis T.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 29
  • DOI: 10.1039/C5CP03283K

Copper in sea-water, potential-pH diagrams
journal, January 1973


Nickel-based solid catalysts for ethylene oligomerization – a review
journal, January 2014

  • Finiels, Annie; Fajula, François; Hulea, Vasile
  • Catal. Sci. Technol., Vol. 4, Issue 8
  • DOI: 10.1039/C4CY00305E

Porous cuprite films: Facile solution deposition and their application for nitrite sensing
journal, January 2010

  • Ning, Wang; Xia, Cao; Xiaolan, Cai
  • The Analyst, Vol. 135, Issue 8
  • DOI: 10.1039/c000086h

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

  • Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N.
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21234j

Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
journal, November 2012

  • Chen, Yihong; Li, Christina W.; Kanan, Matthew W.
  • Journal of the American Chemical Society, Vol. 134, Issue 49
  • DOI: 10.1021/ja309317u

Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide
journal, September 2015

  • Kortlever, Ruud; Shen, Jing; Schouten, Klaas Jan P.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 20
  • DOI: 10.1021/acs.jpclett.5b01559

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
journal, February 2015

  • Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders
  • Angewandte Chemie International Edition, Vol. 54, Issue 17
  • DOI: 10.1002/anie.201412214

Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
journal, July 2015

  • Verdaguer-Casadevall, Arnau; Li, Christina W.; Johansson, Tobias P.
  • Journal of the American Chemical Society, Vol. 137, Issue 31
  • DOI: 10.1021/jacs.5b06227

Sustainable hydrocarbon fuels by recycling CO 2 and H 2 O with renewable or nuclear energy
journal, January 2011

  • Graves, Christopher; Ebbesen, Sune D.; Mogensen, Mogens
  • Renewable and Sustainable Energy Reviews, Vol. 15, Issue 1
  • DOI: 10.1016/j.rser.2010.07.014