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Title: Ultrafast Photoluminescence from the Core and the Shell in CdSe/CdS Dot-in-Rod Heterostructures

 [1];  [2];  [3];  [4];  [2]
  1. Department of Chemistry, University of Pennsylvania, USA
  2. Department of Physics, University of Pennsylvania, Philadelphia Pennsylvania 19104 USA
  3. Department of Materials Science and Engineering, University of Pennsylvania, USA
  4. Department of Chemistry, University of Pennsylvania, USA, Department of Materials Science and Engineering, University of Pennsylvania, USA
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Journal Name: ChemPhysChem Journal Volume: 17 Journal Issue: 5; Journal ID: ISSN 1439-4235
Wiley Blackwell (John Wiley & Sons)
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Diroll, Benjamin T., Turk, Michael E., Gogotsi, Natalie, Murray, Christopher B., and Kikkawa, James M. Ultrafast Photoluminescence from the Core and the Shell in CdSe/CdS Dot-in-Rod Heterostructures. Germany: N. p., 2015. Web. doi:10.1002/cphc.201500747.
Diroll, Benjamin T., Turk, Michael E., Gogotsi, Natalie, Murray, Christopher B., & Kikkawa, James M. Ultrafast Photoluminescence from the Core and the Shell in CdSe/CdS Dot-in-Rod Heterostructures. Germany. doi:
Diroll, Benjamin T., Turk, Michael E., Gogotsi, Natalie, Murray, Christopher B., and Kikkawa, James M. Wed . "Ultrafast Photoluminescence from the Core and the Shell in CdSe/CdS Dot-in-Rod Heterostructures". Germany. doi:
title = {Ultrafast Photoluminescence from the Core and the Shell in CdSe/CdS Dot-in-Rod Heterostructures},
author = {Diroll, Benjamin T. and Turk, Michael E. and Gogotsi, Natalie and Murray, Christopher B. and Kikkawa, James M.},
abstractNote = {},
doi = {10.1002/cphc.201500747},
journal = {ChemPhysChem},
number = 5,
volume = 17,
place = {Germany},
year = {2015},
month = {11}

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Works referenced in this record:

Exciton storage in CdSe/CdS tetrapod semiconductor nanocrystals: Electric field effects on exciton and multiexciton states
journal, July 2012

Synthesis of Highly Luminescent and Photo-Stable, Graded Shell CdSe/Cd x Zn 1– x S Nanoparticles by In Situ Alloying
journal, November 2013

  • Boldt, Klaus; Kirkwood, Nicholas; Beane, Gary A.
  • Chemistry of Materials, Vol. 25, Issue 23
  • DOI: 10.1021/cm402645r

Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility
journal, July 1997

  • Peng, Xiaogang; Schlamp, Michael C.; Kadavanich, Andreas V.
  • Journal of the American Chemical Society, Vol. 119, Issue 30, p. 7019-7029
  • DOI: 10.1021/ja970754m

Direct Determination of Polarity, Faceting, and Core Location in Colloidal Core/Shell Wurtzite Semiconductor Nanocrystals
journal, June 2012

  • Bertoni, Giovanni; Grillo, Vincenzo; Brescia, Rosaria
  • ACS Nano, Vol. 6, Issue 7
  • DOI: 10.1021/nn302085t

Seeded Growth of Highly Luminescent CdSe/CdS Nanoheterostructures with Rod and Tetrapod Morphologies
journal, October 2007

  • Talapin, Dmitri V.; Nelson, James H.; Shevchenko, Elena V.
  • Nano Letters, Vol. 7, Issue 10
  • DOI: 10.1021/nl072003g

Polarized Light Emitting Diode by Long-Range Nanorod Self-Assembling on a Water Surface
journal, May 2009

  • Rizzo, Aurora; Nobile, Concetta; Mazzeo, Marco
  • ACS Nano, Vol. 3, Issue 6
  • DOI: 10.1021/nn900063m

Dual Wavelength Electroluminescence from CdSe/CdS Tetrapods
journal, March 2014

  • Wong, Jen It; Mishra, Nimai; Xing, Guichuan
  • ACS Nano, Vol. 8, Issue 3
  • DOI: 10.1021/nn500030t

Tailoring hot-exciton emission and lifetimes in semiconducting nanowires via whispering-gallery nanocavity plasmons
journal, July 2011

  • Cho, Chang-Hee; Aspetti, Carlos O.; Turk, Michael E.
  • Nature Materials, Vol. 10, Issue 9
  • DOI: 10.1038/nmat3067

Indirect Exciton Formation due to Inhibited Carrier Thermalization in Single CdSe/CdS Nanocrystals
journal, February 2013

  • Shafran, Eyal; Borys, Nicholas J.; Huang, Jing
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 4
  • DOI: 10.1021/jz400070g

Red, green and blue lasing enabled by single-exciton gain in colloidal quantum dot films
journal, April 2012

  • Dang, Cuong; Lee, Joonhee; Breen, Craig
  • Nature Nanotechnology, Vol. 7, Issue 5
  • DOI: 10.1038/nnano.2012.61

Non-Blinking Single-Photon Generation with Anisotropic Colloidal Nanocrystals: Towards Room-Temperature, Efficient, Colloidal Quantum Sources
journal, January 2013

  • Pisanello, Ferruccio; Leménager, Godefroy; Martiradonna, Luigi
  • Advanced Materials, Vol. 25, Issue 14
  • DOI: 10.1002/adma.201203171

Ultrafast Electron Trapping in Ligand-Exchanged Quantum Dot Assemblies
journal, January 2015

  • Turk, Michael E.; Vora, Patrick M.; Fafarman, Aaron T.
  • ACS Nano, Vol. 9, Issue 2
  • DOI: 10.1021/nn505862g

Ultrafast Electron−Hole Dynamics in Core/Shell CdSe/CdS Dot/Rod Nanocrystals
journal, December 2008

  • Lupo, Maria Grazia; Della Sala, Fabio; Carbone, Luigi
  • Nano Letters, Vol. 8, Issue 12
  • DOI: 10.1021/nl8028366

Ultrafast Electronic Delocalization in CdSe/CdS Quantum Rod Heterostructures
journal, November 2011

  • Smith, E. Ryan; Luther, Joseph M.; Johnson, Justin C.
  • Nano Letters, Vol. 11, Issue 11
  • DOI: 10.1021/nl202869z

CdSe/CdS/ZnS and CdSe/ZnSe/ZnS Core−Shell−Shell Nanocrystals
journal, December 2004

  • Talapin, Dmitri V.; Mekis, Ivo; Götzinger, Stephan
  • The Journal of Physical Chemistry B, Vol. 108, Issue 49
  • DOI: 10.1021/jp046481g

Reduced Auger Recombination in Single CdSe/CdS Nanorods by One-Dimensional Electron Delocalization
journal, September 2013

  • Rabouw, Freddy T.; Lunnemann, Per; van Dijk-Moes, Relinde J. A.
  • Nano Letters, Vol. 13, Issue 10
  • DOI: 10.1021/nl4027567

Wave Function Engineering in Elongated Semiconductor Nanocrystals with Heterogeneous Carrier Confinement
journal, October 2005

  • Müller, J.; Lupton, J. M.; Lagoudakis, P. G.
  • Nano Letters, Vol. 5, Issue 10
  • DOI: 10.1021/nl051596x

Comprehensive data analysis of femtosecond transient absorption spectra: A review
journal, March 2012

The Electronic Structure of CdSe/CdS Core/Shell Seeded Nanorods: Type-I or Quasi-Type-II?
journal, November 2013

  • Eshet, Hagai; Grünwald, Michael; Rabani, Eran
  • Nano Letters, Vol. 13, Issue 12
  • DOI: 10.1021/nl402722n

“Flash” Synthesis of CdSe/CdS Core–Shell Quantum Dots
journal, December 2013

  • Cirillo, Marco; Aubert, Tangi; Gomes, Raquel
  • Chemistry of Materials, Vol. 26, Issue 2
  • DOI: 10.1021/cm403518a

Spontaneous Superlattice Formation in Nanorods Through Partial Cation Exchange
journal, July 2007

  • Robinson, R. D.; Sadtler, B.; Demchenko, D. O.
  • Science, Vol. 317, Issue 5836, p. 355-358
  • DOI: 10.1126/science.1142593

Multiexcitonic Dual Emission in CdSe/CdS Tetrapods and Nanorods
journal, November 2010

  • Lutich, Andrey A.; Mauser, Christian; Da Como, Enrico
  • Nano Letters, Vol. 10, Issue 11
  • DOI: 10.1021/nl1028057

Efficient Extraction of Trapped Holes from Colloidal CdS Nanorods
journal, August 2015

  • Wu, Kaifeng; Du, Yongling; Tang, Hua
  • Journal of the American Chemical Society, Vol. 137, Issue 32
  • DOI: 10.1021/jacs.5b04564

New synthesis of two-dimensional CdSe/CdS core@shell dot-in-hexagonal platelet nanoheterostructures with interesting optical properties
journal, January 2014

  • Chauhan, Himani; Kumar, Yogesh; Deka, Sasanka
  • Nanoscale, Vol. 6, Issue 17
  • DOI: 10.1039/C4NR01264J

Universal Length Dependence of Rod-to-Seed Exciton Localization Efficiency in Type I and Quasi-Type II CdSe@CdS Nanorods
journal, February 2015

Optical detection and spectroscopy of single molecules in a solid
journal, May 1989

Breaking the Diffraction Barrier: Optical Microscopy on a Nanometric Scale
journal, March 1991

Highly Emissive Colloidal CdSe/CdS Heterostructures of Mixed Dimensionality
journal, December 2003

  • Talapin, Dmitri V.; Koeppe, Robert; Götzinger, Stephan
  • Nano Letters, Vol. 3, Issue 12
  • DOI: 10.1021/nl034815s

Colloidal CdSe/CdS Dot-in-Plate Nanocrystals with 2D-Polarized Emission
journal, July 2012

  • Cassette, Elsa; Mahler, Benoît; Guigner, Jean-Michel
  • ACS Nano, Vol. 6, Issue 8
  • DOI: 10.1021/nn3024255

Probing the Wave Function Delocalization in CdSe/CdS Dot-in-Rod Nanocrystals by Time- and Temperature-Resolved Spectroscopy
journal, April 2011

  • Rainò, Gabriele; Stöferle, Thilo; Moreels, Iwan
  • ACS Nano, Vol. 5, Issue 5
  • DOI: 10.1021/nn2005969

Highly Emissive Nano Rod-in-Rod Heterostructures with Strong Linear Polarization
journal, May 2011

  • Sitt, Amit; Salant, Asaf; Menagen, Gabi
  • Nano Letters, Vol. 11, Issue 5
  • DOI: 10.1021/nl200519b

Nearly Temperature-Independent Threshold for Amplified Spontaneous Emission in Colloidal CdSe/CdS Quantum Dot-in-Rods
journal, July 2012

  • Moreels, Iwan; Rainò, Gabriele; Gomes, Raquel
  • Advanced Materials, Vol. 24, Issue 35
  • DOI: 10.1002/adma.201202067

CdSe/CdS/ZnS Double Shell Nanorods with High Photoluminescence Efficiency and Their Exploitation As Biolabeling Probes
journal, March 2009

  • Deka, Sasanka; Quarta, Alessandra; Lupo, Maria Grazia
  • Journal of the American Chemical Society, Vol. 131, Issue 8
  • DOI: 10.1021/ja808369e

Beyond Band Alignment: Hole Localization Driven Formation of Three Spatially Separated Long-Lived Exciton States in CdSe/CdS Nanorods
journal, July 2013

  • Wu, Kaifeng; Rodríguez-Córdoba, William E.; Liu, Zheng
  • ACS Nano, Vol. 7, Issue 8
  • DOI: 10.1021/nn402597p

Spatially Indirect Emission in a Luminescent Nanocrystal Molecule
journal, June 2011

  • Choi, Charina L.; Li, Hui; Olson, Andrew C. K.
  • Nano Letters, Vol. 11, Issue 6
  • DOI: 10.1021/nl2007032

Multiexciton Engineering in Seeded Core/Shell Nanorods: Transfer from Type-I to Quasi-type-II Regimes
journal, October 2009

  • Sitt, Amit; Sala, Fabio Della; Menagen, Gabi
  • Nano Letters, Vol. 9, Issue 10
  • DOI: 10.1021/nl901679q

Hierarchical self-assembly of suspended branched colloidal nanocrystals into superlattice structures
journal, September 2011

  • Miszta, Karol; de Graaf, Joost; Bertoni, Giovanni
  • Nature Materials, Vol. 10, Issue 11
  • DOI: 10.1038/nmat3121

Luminescent Solar Concentration with Semiconductor Nanorods and Transfer-Printed Micro-Silicon Solar Cells
journal, December 2013

  • Bronstein, Noah D.; Li, Lanfang; Xu, Lu
  • ACS Nano, Vol. 8, Issue 1
  • DOI: 10.1021/nn404418h

Semiconductor Nanocrystals as Fluorescent Biological Labels
patent, September 1998

Exciton Fine Structure of CdSe/CdS Nanocrystals Determined by Polarization Microscopy at Room Temperature
journal, July 2015

CdSe/CdS Nanorod Photocatalysts: Tuning the Interfacial Charge Transfer Process through Shell Length
journal, July 2015

Using Shape to Control Photoluminescence from CdSe/CdS Core/Shell Nanorods
journal, May 2011

  • She, Chunxing; Demortière, Arnaud; Shevchenko, Elena V.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 12
  • DOI: 10.1021/jz200510f

Far-Field Optical Nanoscopy
journal, May 2007

Suppression of Biexciton Auger Recombination in CdSe/CdS Dot/Rods: Role of the Electronic Structure in the Carrier Dynamics
journal, August 2010

  • Zavelani-Rossi, Margherita; Lupo, Maria Grazia; Tassone, Francesco
  • Nano Letters, Vol. 10, Issue 8
  • DOI: 10.1021/nl101930z

Ultrafast Spectral Migration of Photoluminescence in Graphene Oxide
journal, January 2013

  • Exarhos, Annemarie L.; Turk, Michael E.; Kikkawa, James M.
  • Nano Letters, Vol. 13, Issue 2
  • DOI: 10.1021/nl302624p

Synthesis and Micrometer-Scale Assembly of Colloidal CdSe/CdS Nanorods Prepared by a Seeded Growth Approach
journal, October 2007

  • Carbone, Luigi; Nobile, Concetta; De Giorgi, Milena
  • Nano Letters, Vol. 7, Issue 10
  • DOI: 10.1021/nl0717661

Tunable Optical Anisotropy of Seeded CdSe/CdS Nanorods
journal, December 2013

  • Diroll, Benjamin T.; Koschitzky, Adriel; Murray, Christopher B.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 1
  • DOI: 10.1021/jz402426f

Synthesis and Characterization of Strongly Luminescing ZnS-Capped CdSe Nanocrystals
journal, January 1996

  • Hines, Margaret A.; Guyot-Sionnest, Philippe
  • The Journal of Physical Chemistry, Vol. 100, Issue 2, p. 468-471
  • DOI: 10.1021/jp9530562

Polarized-Light-Emitting Quantum-Rod Diodes
journal, June 2005

  • Hikmet, R. A. M.; Chin, P. T. K.; Talapin, D. V.
  • Advanced Materials, Vol. 17, Issue 11
  • DOI: 10.1002/adma.200401763

Ultralow-Threshold Two-Photon Pumped Amplified Spontaneous Emission and Lasing from Seeded CdSe/CdS Nanorod Heterostructures
journal, November 2012

  • Xing, Guichuan; Liao, Yile; Wu, Xiangyang
  • ACS Nano, Vol. 6, Issue 12
  • DOI: 10.1021/nn304200a

Band-like transport, high electron mobility and high photoconductivity in all-inorganic nanocrystal arrays
journal, April 2011

  • Lee, Jong-Soo; Kovalenko, Maksym V.; Huang, Jing
  • Nature Nanotechnology, Vol. 6, Issue 6
  • DOI: 10.1038/nnano.2011.46

Octapod-Shaped Colloidal Nanocrystals of Cadmium Chalcogenides via “One-Pot” Cation Exchange and Seeded Growth
journal, September 2010

  • Deka, Sasanka; Miszta, Karol; Dorfs, Dirk
  • Nano Letters, Vol. 10, Issue 9
  • DOI: 10.1021/nl102539a

Controlling the spatial location of photoexcited electrons in semiconductor CdSe/CdS core/shell nanorods
journal, April 2013

High-Temperature Photoluminescence of CdSe/CdS Core/Shell Nanoheterostructures
journal, May 2014

  • Diroll, Benjamin T.; Murray, Christopher B.
  • ACS Nano, Vol. 8, Issue 6
  • DOI: 10.1021/nn5021314

Photocatalytic Hydrogen Production with Tunable Nanorod Heterostructures
journal, March 2010

  • Amirav, Lilac; Alivisatos, A. Paul
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 7
  • DOI: 10.1021/jz100075c

Mobility and Spatial Distribution of Photoexcited Electrons in CdSe/CdS Nanorods
journal, February 2013

  • Kunneman, Lucas T.; Zanella, Marco; Manna, Liberato
  • The Journal of Physical Chemistry C, Vol. 117, Issue 6
  • DOI: 10.1021/jp3117984