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Title: Catalytically Active Silicon Oxide Nanoclusters Stabilized in a Metal-Organic Framework

Authors:
ORCiD logo [1];  [2];  [2];  [1];  [1];  [3]
  1. Department of Chemistry, Northwestern University, 2145 Sheridan Road Evanston Illinois 60208 USA
  2. X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Avenue Argonne Illinois 60439 USA
  3. Department of Chemistry, Northwestern University, 2145 Sheridan Road Evanston Illinois 60208 USA, Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21589 Saudi Arabia
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401064
Grant/Contract Number:  
SC0012702; AC02-06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Name: Chemistry - A European Journal Journal Volume: 23 Journal Issue: 35; Journal ID: ISSN 0947-6539
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Rimoldi, Martino, Gallington, Leighanne C., Chapman, Karena W., MacRenaris, Keith, Hupp, Joseph T., and Farha, Omar K. Catalytically Active Silicon Oxide Nanoclusters Stabilized in a Metal-Organic Framework. Germany: N. p., 2017. Web. doi:10.1002/chem.201701902.
Rimoldi, Martino, Gallington, Leighanne C., Chapman, Karena W., MacRenaris, Keith, Hupp, Joseph T., & Farha, Omar K. Catalytically Active Silicon Oxide Nanoclusters Stabilized in a Metal-Organic Framework. Germany. doi:10.1002/chem.201701902.
Rimoldi, Martino, Gallington, Leighanne C., Chapman, Karena W., MacRenaris, Keith, Hupp, Joseph T., and Farha, Omar K. Tue . "Catalytically Active Silicon Oxide Nanoclusters Stabilized in a Metal-Organic Framework". Germany. doi:10.1002/chem.201701902.
@article{osti_1401064,
title = {Catalytically Active Silicon Oxide Nanoclusters Stabilized in a Metal-Organic Framework},
author = {Rimoldi, Martino and Gallington, Leighanne C. and Chapman, Karena W. and MacRenaris, Keith and Hupp, Joseph T. and Farha, Omar K.},
abstractNote = {},
doi = {10.1002/chem.201701902},
journal = {Chemistry - A European Journal},
number = 35,
volume = 23,
place = {Germany},
year = {2017},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/chem.201701902

Citation Metrics:
Cited by: 4 works
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Works referenced in this record:

Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal–Organic Frameworks: The Unique Case of UiO-66(Zr)
journal, July 2013

  • Vermoortele, Frederik; Bueken, Bart; Le Bars, Gaëlle
  • Journal of the American Chemical Society, Vol. 135, Issue 31
  • DOI: 10.1021/ja405078u

Tailoring nanoporous materials by atomic layer deposition
journal, January 2011

  • Detavernier, Christophe; Dendooven, Jolien; Pulinthanathu Sree, Sreeprasanth
  • Chemical Society Reviews, Vol. 40, Issue 11
  • DOI: 10.1039/c1cs15091j

Atomic Layer Deposition of Pt Nanoparticles within the Cages of MIL-101: A Mild and Recyclable Hydrogenation Catalyst
journal, March 2016

  • Leus, Karen; Dendooven, Jolien; Tahir, Norini
  • Nanomaterials, Vol. 6, Issue 3
  • DOI: 10.3390/nano6030045

Mechanisms of xylene isomerization over acidic solid catalysts
journal, April 2000


Recent Advances in Catalytic Conversion of Ethanol to Chemicals
journal, March 2014


Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
journal, November 2013

  • Katz, Michael J.; Mondloch, Joseph E.; Totten, Ryan K.
  • Angewandte Chemie, Vol. 126, Issue 2
  • DOI: 10.1002/ange.201307520

In Situ Reaction Mechanism Studies on Atomic Layer Deposition of Al x Si y O z from Trimethylaluminium, Hexakis(ethylamino)disilane, and Water
journal, October 2012

  • Tomczak, Yoann; Knapas, Kjell; Haukka, Suvi
  • Chemistry of Materials, Vol. 24, Issue 20
  • DOI: 10.1021/cm301658m

Zr-based metal–organic frameworks: design, synthesis, structure, and applications
journal, January 2016

  • Bai, Yan; Dou, Yibo; Xie, Lin-Hua
  • Chemical Society Reviews, Vol. 45, Issue 8
  • DOI: 10.1039/C5CS00837A

State of the art and future challenges of zeolites as catalysts
journal, May 2003


Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks
journal, December 2016

  • Rimoldi, Martino; Howarth, Ashlee J.; DeStefano, Matthew R.
  • ACS Catalysis, Vol. 7, Issue 2
  • DOI: 10.1021/acscatal.6b02923

Tuning Acid–Base Properties Using Mg–Al Oxide Atomic Layer Deposition
journal, July 2015

  • Jackson, David H. K.; O’Neill, Brandon J.; Lee, Jechan
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 30
  • DOI: 10.1021/acsami.5b04107

Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

Electronic Effects of Linker Substitution on Lewis Acid Catalysis with Metal-Organic Frameworks
journal, April 2012

  • Vermoortele, Frederik; Vandichel, Matthias; Van de Voorde, Ben
  • Angewandte Chemie, Vol. 124, Issue 20
  • DOI: 10.1002/ange.201108565

An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation
journal, January 2011

  • Vermoortele, Frederik; Ameloot, Rob; Vimont, Alexandre
  • Chem. Commun., Vol. 47, Issue 5
  • DOI: 10.1039/C0CC03038D

Superacidity in Sulfated Metal–Organic Framework-808
journal, September 2014

  • Jiang, Juncong; Gándara, Felipe; Zhang, Yue-Biao
  • Journal of the American Chemical Society, Vol. 136, Issue 37
  • DOI: 10.1021/ja507119n

Atomic Layer Deposition in a Metal–Organic Framework: Synthesis, Characterization, and Performance of a Solid Acid
journal, January 2017


Catalyst Design with Atomic Layer Deposition
journal, February 2015

  • O’Neill, Brandon J.; Jackson, David H. K.; Lee, Jechan
  • ACS Catalysis, Vol. 5, Issue 3
  • DOI: 10.1021/cs501862h

ALD of SiO[sub 2] at Room Temperature Using TEOS and H[sub 2]O with NH[sub 3] as the Catalyst
journal, January 2004

  • Ferguson, J. D.; Smith, E. R.; Weimer, A. W.
  • Journal of The Electrochemical Society, Vol. 151, Issue 8
  • DOI: 10.1149/1.1768548

High-resolution 29Si solid-state NMR study of silicon functionality distribution on the surface of silicas
journal, January 1996


Stable Metal–Organic Framework-Supported Niobium Catalysts
journal, October 2016


Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions
journal, May 1995


Destruction of chemical warfare agents using metal–organic frameworks
journal, March 2015

  • Mondloch, Joseph E.; Katz, Michael J.; Isley III, William C.
  • Nature Materials, Vol. 14, Issue 5
  • DOI: 10.1038/nmat4238

SiO 2 Atomic Layer Deposition Using Tris(dimethylamino)silane and Hydrogen Peroxide Studied by in Situ Transmission FTIR Spectroscopy
journal, April 2009

  • Burton, B. B.; Kang, S. W.; Rhee, S. W.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 19
  • DOI: 10.1021/jp806638e

Atomic and molecular layer deposition: off the beaten track
journal, January 2017

  • Van Bui, H.; Grillo, F.; van Ommen, J. R.
  • Chemical Communications, Vol. 53, Issue 1
  • DOI: 10.1039/C6CC05568K

Regioselective Atomic Layer Deposition in Metal–Organic Frameworks Directed by Dispersion Interactions
journal, October 2016

  • Gallington, Leighanne C.; Kim, In Soo; Liu, Wei-Guang
  • Journal of the American Chemical Society, Vol. 138, Issue 41
  • DOI: 10.1021/jacs.6b08711

Engineering Metal Organic Frameworks for Heterogeneous Catalysis
journal, August 2010

  • Corma, A.; García, H.; Llabrés i Xamena, F. X.
  • Chemical Reviews, Vol. 110, Issue 8, p. 4606-4655
  • DOI: 10.1021/cr9003924

Simple and Compelling Biomimetic Metal-Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
journal, November 2013

  • Katz, Michael J.; Mondloch, Joseph E.; Totten, Ryan K.
  • Angewandte Chemie International Edition, Vol. 53, Issue 2, p. 497-501
  • DOI: 10.1002/anie.201307520

Atomic Layer Deposition: An Overview
journal, January 2010

  • George, Steven M.
  • Chemical Reviews, Vol. 110, Issue 1, p. 111-131
  • DOI: 10.1021/cr900056b

Electronic Effects of Linker Substitution on Lewis Acid Catalysis with Metal-Organic Frameworks
journal, April 2012

  • Vermoortele, Frederik; Vandichel, Matthias; Van de Voorde, Ben
  • Angewandte Chemie International Edition, Vol. 51, Issue 20
  • DOI: 10.1002/anie.201108565

Targeted Single-Site MOF Node Modification: Trivalent Metal Loading via Atomic Layer Deposition
journal, June 2015


X-Ray photoelectron spectroscopy on zeolites and related materials
journal, July 1996


Conformal Coating on Ultrahigh-Aspect-Ratio Nanopores of Anodic Alumina by Atomic Layer Deposition
journal, September 2003

  • Elam, J. W.; Routkevitch, D.; Mardilovich, P. P.
  • Chemistry of Materials, Vol. 15, Issue 18, p. 3507-3517
  • DOI: 10.1021/cm0303080

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013

  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
  • DOI: 10.1021/ja4050828

Brønsted Acidity in Metal–Organic Frameworks
journal, June 2015


Towards a molecular understanding of shape selectivity
journal, February 2008


Aluminium atomic layer deposition applied to mesoporous zeolites for acid catalytic activity enhancement
journal, January 2011

  • Sree, Sreeprasanth Pulinthanathu; Dendooven, Jolien; Korányi, Tamás I.
  • Catalysis Science & Technology, Vol. 1, Issue 2
  • DOI: 10.1039/c0cy00056f

The nature of the relative bonding chemistry in zeolites: An XPS study
journal, November 1990