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Title: Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization

Authors:
 [1];  [2];  [2];  [3];  [1];  [3];  [2];  [1]
  1. Energy and Environmental DirectoratePacific Northwest National Laboratory 902 Battelle Boulevard Richland WA 99354 USA
  2. School of Energy and Chemical EngineeringGreen Energy Materials Development CenterUlsan National Institute of Science and Technology (UNIST) Korea 689–798
  3. Environmental Molecular Sciences LaboratoryPacific Northwest National Laboratory 902 Battelle Boulevard Richland WA 99354 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1401043
Grant/Contract Number:  
DE‐AC02‐05CH11231; 18769
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 7 Journal Issue: 6; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zheng, Jianming, Myeong, Seungjun, Cho, Woongrae, Yan, Pengfei, Xiao, Jie, Wang, Chongmin, Cho, Jaephil, and Zhang, Ji‐Guang. Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization. Germany: N. p., 2016. Web. doi:10.1002/aenm.201601284.
Zheng, Jianming, Myeong, Seungjun, Cho, Woongrae, Yan, Pengfei, Xiao, Jie, Wang, Chongmin, Cho, Jaephil, & Zhang, Ji‐Guang. Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization. Germany. doi:10.1002/aenm.201601284.
Zheng, Jianming, Myeong, Seungjun, Cho, Woongrae, Yan, Pengfei, Xiao, Jie, Wang, Chongmin, Cho, Jaephil, and Zhang, Ji‐Guang. Wed . "Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization". Germany. doi:10.1002/aenm.201601284.
@article{osti_1401043,
title = {Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization},
author = {Zheng, Jianming and Myeong, Seungjun and Cho, Woongrae and Yan, Pengfei and Xiao, Jie and Wang, Chongmin and Cho, Jaephil and Zhang, Ji‐Guang},
abstractNote = {},
doi = {10.1002/aenm.201601284},
journal = {Advanced Energy Materials},
number = 6,
volume = 7,
place = {Germany},
year = {2016},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/aenm.201601284

Citation Metrics:
Cited by: 21 works
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Electrochemical Kinetics and Performance of Layered Composite Cathode Material Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2
journal, January 2013

  • Zheng, Jianming; Shi, Wei; Gu, Meng
  • Journal of The Electrochemical Society, Vol. 160, Issue 11
  • DOI: 10.1149/2.090311jes

Synthesis–Structure–Property Relations in Layered, “Li-excess” Oxides Electrode Materials Li[Li[sub 1/3−2x/3]Ni[sub x]Mn[sub 2/3−x/3]]O[sub 2] (x=1/3, 1/4, and 1/5)
journal, January 2010

  • Fell, Christopher R.; Carroll, Kyler J.; Chi, Miaofang
  • Journal of The Electrochemical Society, Vol. 157, Issue 11
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Unravelling structural ambiguities in lithium- and manganese-rich transition metal oxides
journal, October 2015

  • Shukla, Alpesh Khushalchand; Ramasse, Quentin M.; Ophus, Colin
  • Nature Communications, Vol. 6, Issue 1
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Exploring Electrochemistry and Interface Characteristics of Lithium-Ion Cells with Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 Positive and Li 4 Ti 5 O 12 Negative Electrodes
journal, January 2015

  • Li, Yan; Bettge, Martin; Bareño, Javier
  • Journal of The Electrochemical Society, Vol. 162, Issue 13
  • DOI: 10.1149/2.0071513jes

Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li 2 MnO 3 −LiCo 1/3 Ni 1/3 Mn 1/3 O 2
journal, March 2011

  • Yabuuchi, Naoaki; Yoshii, Kazuhiro; Myung, Seung-Taek
  • Journal of the American Chemical Society, Vol. 133, Issue 12
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Tris(hexafluoro-iso-propyl)phosphate as an SEI-Forming Additive on Improving the Electrochemical Performance of the Li[Li 0.2 Mn 0.56 Ni 0.16 Co 0.08 ]O 2 Cathode Material
journal, December 2012

  • Tan, Shi; Zhang, Zhongru; Li, Yixiao
  • Journal of The Electrochemical Society, Vol. 160, Issue 2
  • DOI: 10.1149/2.066302jes

Electrochemical performance of 0.5Li2MnO3–0.5Li(Mn0.375Ni0.375Co0.25)O2 composite cathode in pyrrolidinium-based ionic liquid electrolytes
journal, October 2015


Multifunctional AlPO 4 Coating for Improving Electrochemical Properties of Low-Cost Li[Li 0.2 Fe 0.1 Ni 0.15 Mn 0.55 ]O 2 Cathode Materials for Lithium-Ion Batteries
journal, February 2015

  • Wu, Feng; Zhang, Xiaoxiao; Zhao, Taolin
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 6
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Reinvestigation on the state-of-the-art nonaqueous carbonate electrolytes for 5 V Li-ion battery applications
journal, September 2012


Electrochemical Behavior of Layered Solid Solution Li2MnO3−LiMO2 (M = Ni, Mn, Co) Li-Ion Cathodes with and without Alumina Coatings
journal, January 2011

  • West, W. C.; Soler, J.; Smart, M. C.
  • Journal of The Electrochemical Society, Vol. 158, Issue 8
  • DOI: 10.1149/1.3597319

Direct Atomic-Resolution Observation of Two Phases in the Li 1.2 Mn 0.567 Ni 0.166 Co 0.067 O 2 Cathode Material for Lithium-Ion Batteries
journal, April 2013

  • Yu, Haijun; Ishikawa, Ryo; So, Yeong-Gi
  • Angewandte Chemie International Edition, Vol. 52, Issue 23
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Understanding the stepwise capacity increase of high energy low-Co Li-rich cathode materials for lithium ion batteries
journal, January 2014

  • Ye, Delai; Wang, Bei; Chen, Yu
  • J. Mater. Chem. A, Vol. 2, Issue 44
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Layered Li(Li0.2Ni0.15+0.5zCo0.10Mn0.55−0.5z)O2−zFz cathode materials for Li-ion secondary batteries
journal, August 2005


Effect of Lithium Bis(oxalato)borate Additive on Electrochemical Performance of Li 1.17 Ni 0.17 Mn 0.5 Co 0.17 O 2 Cathodes for Lithium-Ion Batteries
journal, January 2014

  • Lee, Sung Jun; Han, Jung-Gu; Park, Inbok
  • Journal of The Electrochemical Society, Vol. 161, Issue 14
  • DOI: 10.1149/2.0211414jes

Enhancing the rate capability of high capacity xLi2MnO3 · (1−x)LiMO2 (M=Mn, Ni, Co) electrodes by Li–Ni–PO4 treatment
journal, April 2009


First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries
journal, July 2013

  • Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François
  • Nano Letters, Vol. 13, Issue 8
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Conflicting Roles of Nickel in Controlling Cathode Performance in Lithium Ion Batteries
journal, September 2012

  • Gu, Meng; Belharouak, Ilias; Genc, Arda
  • Nano Letters, Vol. 12, Issue 10
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Probing the electrode/electrolyte interface in the lithium excess layered oxide Li1.2Ni0.2Mn0.6O2
journal, January 2013

  • Carroll, Kyler J.; Qian, Danna; Fell, Chris
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 26
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A New Spinel-Layered Li-Rich Microsphere as a High-Rate Cathode Material for Li-Ion Batteries
journal, April 2014

  • Luo, Dong; Li, Guangshe; Fu, Chaochao
  • Advanced Energy Materials, Vol. 4, Issue 11
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Influence of Ru substitution on Li-rich 0.55Li2MnO3·0.45LiNi1/3Co1/3Mn1/3O2 cathode for Li-ion batteries
journal, October 2012


New electrolytes using Li2O or Li2O2 oxides and tris(pentafluorophenyl) borane as boron based anion receptor for lithium batteries
journal, August 2008


Suppressed capacity/voltage fading of high-capacity lithium-rich layered materials via the design of heterogeneous distribution in the composition
journal, January 2014

  • Yang, Xiukang; Wang, Di; Yu, Ruizhi
  • Journal of Materials Chemistry A, Vol. 2, Issue 11
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High-Energy Cathode Materials (Li 2 MnO 3 –LiMO 2 ) for Lithium-Ion Batteries
journal, March 2013

  • Yu, Haijun; Zhou, Haoshen
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 8
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Countering Voltage Decay and Capacity Fading of Lithium-Rich Cathode Material at 60 °C by Hybrid Surface Protection Layers
journal, April 2015


Synthesis and Electrochemical Performances of Y-Doped Lithium-Rich Layered Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2 Cathode Material
journal, January 2016

  • Sun, Lingna; Yi, Xianwen; Ren, Xiangzhong
  • Journal of The Electrochemical Society, Vol. 163, Issue 5
  • DOI: 10.1149/2.1071605jes

Quantifying Hysteresis and Voltage Fade in xLi 2 MnO 3 (1-x)LiMn 0.5 Ni 0.5 O 2 Electrodes as a Function of Li 2 MnO 3 Content
journal, December 2013

  • Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam
  • Journal of The Electrochemical Society, Vol. 161, Issue 3
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LixNi0.25Mn0.75Oy (0.5 ≤x≤ 2, 2 ≤y≤ 2.75) compounds for high-energy lithium-ion batteries
journal, January 2009

  • Deng, Haixia; Belharouak, Ilias; Sun, Yang-Kook
  • Journal of Materials Chemistry, Vol. 19, Issue 26
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Improved electrochemical performance of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode material by fluorine incorporation
journal, August 2013


A diisocyanate/sulfone binary electrolyte based on lithium difluoro(oxalate)borate for lithium batteries
journal, January 2013

  • Wu, Feng; Zhu, Qizhen; Li, Li
  • Journal of Materials Chemistry A, Vol. 1, Issue 11
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Fabrication and Performance of High Energy Li-Ion Battery Based on the Spherical Li[Li 0.2 Ni 0.16 Co 0.1 Mn 0.54 ]O 2 Cathode and Si Anode
journal, December 2015

  • Ye, Jing; Li, Yi-xuan; Zhang, Li
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 1
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Effect of MnO2 modification on electrochemical performance of LiNi0.2Li0.2Mn0.6O2 layered solid solution cathode
journal, January 2013


Anomalous capacity and cycling stability of xLi2MnO3·(1−x)LiMO2 electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C
journal, April 2007

  • Johnson, Christopher S.; Li, Naichao; Lefief, Christina
  • Electrochemistry Communications, Vol. 9, Issue 4, p. 787-795
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High capacity Li[Li0.2Ni0.2Mn0.6]O2 cathode materials via a carbonate co-precipitation method
journal, November 2006


Countering the Voltage Decay in High Capacity xLi 2 MnO 3 •(1–x)LiMO 2 Electrodes (M=Mn, Ni, Co) for Li + -Ion Batteries
journal, January 2012

  • Croy, Jason R.; Kim, Donghan; Balasubramanian, Mahalingam
  • Journal of The Electrochemical Society, Vol. 159, Issue 6
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Comments on stabilizing layered manganese oxide electrodes for Li batteries
journal, November 2013


Nanostructured Hybrid Layered-Spinel Cathode Material Synthesized by Hydrothermal Method for Lithium-Ion Batteries
journal, May 2014

  • Liu, Cong; Wang, Zhiyuan; Shi, Chunsheng
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 11
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The Configurational Space of Rocksalt-Type Oxides for High-Capacity Lithium Battery Electrodes
journal, May 2014

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  • Advanced Energy Materials, Vol. 4, Issue 13
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New Insights into Improving Rate Performance of Lithium-Rich Cathode Material
journal, May 2015

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  • Advanced Materials, Vol. 27, Issue 26
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Synthetic optimization of Li[Ni1/3Co1/3Mn1/3]O2 via co-precipitation
journal, December 2004


Retarded phase transition by fluorine doping in Li-rich layered Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 cathode material
journal, June 2015


Atomic Structure of a Lithium-Rich Layered Oxide Material for Lithium-Ion Batteries: Evidence of a Solid Solution
journal, August 2011

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  • Chemistry of Materials, Vol. 23, Issue 16
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Advances in Sustain Stable Voltage of Cr-Doped Li-Rich Layered Cathodes for Lithium Ion Batteries
journal, January 2014

  • Song, Bohang; Zhou, Cuifeng; Wang, Hailong
  • Journal of The Electrochemical Society, Vol. 161, Issue 10
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Improving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive electrode with alumina
journal, July 2013


A high energy density full lithium-ion cell based on specially matched coulombic efficiency
journal, January 2016

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  • Journal of Materials Chemistry A, Vol. 4, Issue 11
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History, Evolution, and Future Status of Energy Storage
journal, May 2012


An Advanced Lithium Ion Battery Based on Amorphous Silicon Film Anode and Integrated xLi2MnO3.(1-x)LiNiyMnzCo1-y-zO2 Cathode
journal, January 2013

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Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives
journal, October 2015

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Structural and electrochemical properties of (1−x) Li[Ni0.20Li0.20Mn0.60]O2–xLi[Co0.50Li0.167Mn0.333]O2 for lithium secondary batteries
journal, September 2005


Enhanced performance of sulfone-based electrolytes at lithium ion battery electrodes, including the LiNi0.5Mn1.5O4 high voltage cathode
journal, September 2014


Understanding the Effect of Lithium Bis(oxalato) Borate (LiBOB) on the Structural and Electrochemical Aging of Li and Mn Rich High Capacity Li 1.2 Ni 0.16 Mn 0.56 Co 0.08 O 2 Cathodes
journal, January 2015

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Improving High Voltage Interfacial and Structural Stability of Layered Lithium-Rich Oxide Cathode by Using a Boracic Electrolyte Additive
journal, January 2016

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Mechanisms Associated with the “Plateau” Observed at High Voltage for the Overlithiated Li 1.12 (Ni 0.425 Mn 0.425 Co 0.15 ) 0.88 O 2 System
journal, August 2008

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  • Chemistry of Materials, Vol. 20, Issue 15
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