An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes

doi:10.1002/adma.201605531

Title: An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes

Authors:

Liu, Yayuan ^[1]; Lin, Dingchang ^[1]; Yuen, Pak Yan ^[2]; Liu, Kai ^[1]; Xie, Jin ^[1]; Dauskardt, Reinhold H. ^[1]; Cui, Yi ^[3]

Department of Materials Science and Engineering, Stanford University, Stanford CA 94305 USA
Department of Mechanical Engineering, Stanford University, Stanford CA 94305 USA
Department of Materials Science and Engineering, Stanford University, Stanford CA 94305 USA, Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road Menlo Park CA 94025 USA

Publication Date:: 2016-12-29

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1401036

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Advanced Materials

Additional Journal Information:: Journal Name: Advanced Materials Journal Volume: 29 Journal Issue: 10; Journal ID: ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Liu, Yayuan, Lin, Dingchang, Yuen, Pak Yan, Liu, Kai, Xie, Jin, Dauskardt, Reinhold H., and Cui, Yi. An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes.  Germany: N. p., 2016. 
        Web.  doi:10.1002/adma.201605531.

Copy to clipboard


                    Liu, Yayuan, Lin, Dingchang, Yuen, Pak Yan, Liu, Kai, Xie, Jin, Dauskardt, Reinhold H., & Cui, Yi. An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes.  Germany.  doi:10.1002/adma.201605531.

Copy to clipboard


                    Liu, Yayuan, Lin, Dingchang, Yuen, Pak Yan, Liu, Kai, Xie, Jin, Dauskardt, Reinhold H., and Cui, Yi. Thu .  
        "An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes".  Germany.  doi:10.1002/adma.201605531.

Copy to clipboard


                    
@article{osti_1401036,

  title        = {An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes},

  author       = {Liu, Yayuan and Lin, Dingchang and Yuen, Pak Yan and Liu, Kai and Xie, Jin and Dauskardt, Reinhold H. and Cui, Yi},

  abstractNote = {},

  doi          = {10.1002/adma.201605531},

  journal      = {Advanced Materials},

  number       = 10,

  volume       = 29,

  place        = {Germany},

  year         = {2016},

  month        = {12}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1002/adma.201605531

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 32 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Addition of a thin-film inorganic solid electrolyte (Lipon) as a protective film in lithium batteries with a liquid electrolyte
journal, August 2000

Dudney, Nancy J.
Journal of Power Sources, Vol. 89, Issue 2, p. 176-179
DOI: 10.1016/S0378-7753(00)00427-4

Li�O₂ and Li�S batteries with high energy storage
journal, January 2012

Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
Nature Materials, Vol. 11, Issue 1, p. 19-29
DOI: 10.1038/nmat3191

Similar Records in DOE PAGES and OSTI.GOV collections:

Effect of electrolyte on the nanostructure of the solid electrolyte interphase (SEI) and performance of lithium metal anodes

Journal Article Jurng, Sunhyung ; Brown, Zachary L. ; Kim, Jiyeon ; ... - Energy & Environmental Science

Nanostructure of the SEI may be as important as the molecular composition of the SEI for good cycling performance of lithium metal anodes.
Cited by 8
DOI: 10.1039/C8EE00364E
Artificial Solid Electrolyte Interphase-Protected Li _x Si Nanoparticles: An Efficient and Stable Prelithiation Reagent for Lithium-Ion Batteries

Journal Article Zhao, Jie ; Lu, Zhenda ; Wang, Haotian ; ... - Journal of the American Chemical Society
DOI: 10.1021/jacs.5b04526
Enhanced Stability of Li Metal Anodes by Synergetic Control of Nucleation and the Solid Electrolyte Interphase

Journal Article Peng, Zhe ; Song, Junhua ; Huai, Liyuan ; ... - Advanced Energy Materials
DOI: 10.1002/aenm.201901764
Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries

Journal Article Li, Guoxing ; Gao, Yue ; He, Xin ; ... - Nature Communications

Lithium metal is a promising anode candidate for the next-generation rechargeable battery due to its highest specific capacity (3860 mA h g ^-1) and lowest potential, but low Coulombic efficiency and formation of lithium dendrites hinder its practical application. Here, we report a self-formed flexible hybrid solid-electrolyte interphase layer through co-deposition of organosulfides/organopolysulfides and inorganic lithium salts using sulfur-containing polymers as an additive in the electrolyte. The organosulfides/organopolysulfides serve as “plasticizer” in the solid-electrolyte interphase layer to improve its mechanical flexibility and toughness. The as-formed robust solid-electrolyte interphase layers enable dendrite-free lithium deposition and significantly improve Coulombic efficiency (99% overmore »« less
Cited by 13
DOI: 10.1038/s41467-017-00974-x

Full Text Available
Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries

Journal Article Li, Guoxing ; Gao, Yue ; He, Xin ; ... - Nature Communications

Lithium metal is a promising anode candidate for the next-generation rechargeable battery due to its highest specific capacity (3860 mA h g-1) and lowest potential, but low Coulombic efficiency and formation of lithium dendrites hinder its practical application. Here, we report a self-formed flexible hybrid solid-electrolyte interphase layer through co-deposition of organosulfides/organopolysulfides and inorganic lithium salts using sulfur-containing polymers as an additive in the electrolyte. The organosulfides/organopolysulfides serve as “plasticizer” in the solid-electrolyte interphase layer to improve its mechanical flexibility and toughness. The as-formed robust solid-electrolyte interphase layers enable dendrite-free lithium deposition and significantly improve Coulombic efficiency (99% over 400more »« less
Cited by 13
DOI: 10.1038/s41467-017-00974-x

Full Text Available

Similar Records

Title: An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes

Citation Formats

Addition of a thin-film inorganic solid electrolyte (Lipon) as a protective film in lithium batteries with a liquid electrolyte journal, August 2000

Li�O2 and Li�S batteries with high energy storage journal, January 2012

Addition of a thin-film inorganic solid electrolyte (Lipon) as a protective film in lithium batteries with a liquid electrolyte
journal, August 2000

Li�O₂ and Li�S batteries with high energy storage
journal, January 2012