An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes
Abstract
Here, an artificial solid electrolyte interphase (SEI) is demonstrated for the efficient and safe operation of a lithium metal anode. Composed of lithium-ion-conducting inorganic nanoparticles within a flexible polymer binder matrix, the rationally designed artificial SEI not only mechanically suppresses lithium dendrite formation but also promotes homogeneous lithium-ion flux, significantly enhancing the efficiency and cycle life of the lithium metal anode.
- Authors:
-
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
- Stanford Univ., CA (United States). Dept. of Mechanical Engineering
- Department of Materials Science and Engineering, Stanford University, Stanford CA 94305 USA
- Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
- OSTI Identifier:
- 1352611
- Alternate Identifier(s):
- OSTI ID: 1401036
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 29; Journal Issue: 10; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; artificial solid electrolyte interphase; electrochemistry; lithium metal anodes; nanotechnology; porous lithium
Citation Formats
Liu, Yayuan, Lin, Dingchang, Yuen, Pak Yan, Liu, Kai, Xie, Jin, Dauskardt, Reinhold H., and Cui, Yi. An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes. United States: N. p., 2016.
Web. doi:10.1002/adma.201605531.
Liu, Yayuan, Lin, Dingchang, Yuen, Pak Yan, Liu, Kai, Xie, Jin, Dauskardt, Reinhold H., & Cui, Yi. An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes. United States. https://doi.org/10.1002/adma.201605531
Liu, Yayuan, Lin, Dingchang, Yuen, Pak Yan, Liu, Kai, Xie, Jin, Dauskardt, Reinhold H., and Cui, Yi. Thu .
"An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes". United States. https://doi.org/10.1002/adma.201605531. https://www.osti.gov/servlets/purl/1352611.
@article{osti_1352611,
title = {An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes},
author = {Liu, Yayuan and Lin, Dingchang and Yuen, Pak Yan and Liu, Kai and Xie, Jin and Dauskardt, Reinhold H. and Cui, Yi},
abstractNote = {Here, an artificial solid electrolyte interphase (SEI) is demonstrated for the efficient and safe operation of a lithium metal anode. Composed of lithium-ion-conducting inorganic nanoparticles within a flexible polymer binder matrix, the rationally designed artificial SEI not only mechanically suppresses lithium dendrite formation but also promotes homogeneous lithium-ion flux, significantly enhancing the efficiency and cycle life of the lithium metal anode.},
doi = {10.1002/adma.201605531},
journal = {Advanced Materials},
number = 10,
volume = 29,
place = {United States},
year = {Thu Dec 29 00:00:00 EST 2016},
month = {Thu Dec 29 00:00:00 EST 2016}
}
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Figures / Tables:
Figure 1: (a) Schematic illustration of the fabrication of the Cu3N+SBR composite artificial SEI. (b) Schematic illustration of the Li plating/stripping behavior of bare Li (upper figure), where the cracking of SEI results in the formation of Li-ion flux “hot spots” and Li dendrites; and the artificial SEI protected Limore »
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