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Title: Open‐Pore Two‐Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon‐Isomer‐Selective Membranes on Porous Polymer Supports

Abstract

Abstract Two‐dimensional zeolite nanosheets that do not contain any organic structure‐directing agents were prepared from a multilamellar MFI (ML‐MFI) zeolite. ML‐MFI was first exfoliated by melt compounding and then detemplated by treatment with a mixture of H 2 SO 4 and H 2 O 2 (piranha solution). The obtained OSDA‐free MFI nanosheets disperse well in water and can be used for coating applications. Deposits made on porous polybenzimidazole (PBI) supports by simple filtration of these suspensions exhibit an n ‐butane/isobutane selectivity of 5.4, with an n ‐butane permeance of 3.5×10 −7  mol m −2  s −1  Pa −1 (ca. 1000 GPU).

Authors:
 [1];  [2];  [3];  [4];  [1];  [1];  [1];  [5];  [5];  [5];  [6];  [1];  [1];  [1]; ORCiD logo [1]
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  1. Department of Chemical Engineering and Materials Science University of Minnesota 421 Washington Ave SE Minneapolis MN 55455 USA
  2. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry Zhejiang Normal University, Jinhua Zhejiang 321004 China
  3. Key Laboratory of Systems Bioengineering, Ministry of Education Department of Pharmaceutical Engineering School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China
  4. College of Chemistry Chemical Engineering and Materials Science Collaborative Innovation Center of Suzhou Nano Science and Technology Soochow University, Suzhou Jiangsu 215123 China
  5. Department of Chemistry Faculty of Science King Abdulaziz University Jeddah 21589 Saudi Arabia
  6. Department of Chemical Engineering Ankara University Ankara 06100 Turkey
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1400963
Grant/Contract Number:  
AR0000338; D-003/433; SC0001004
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition) Journal Volume: 55 Journal Issue: 25; Journal ID: ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zhang, Han, Xiao, Qiang, Guo, Xianghai, Li, Najun, Kumar, Prashant, Rangnekar, Neel, Jeon, Mi Young, Al‐Thabaiti, Shaeel, Narasimharao, Katabathini, Basahel, Sulaiman Nasir, Topuz, Berna, Onorato, Frank J., Macosko, Christopher W., Mkhoyan, K. Andre, and Tsapatsis, Michael. Open‐Pore Two‐Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon‐Isomer‐Selective Membranes on Porous Polymer Supports. Germany: N. p., 2016. Web. doi:10.1002/anie.201601135.
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Zhang, Han, Xiao, Qiang, Guo, Xianghai, Li, Najun, Kumar, Prashant, Rangnekar, Neel, Jeon, Mi Young, Al‐Thabaiti, Shaeel, Narasimharao, Katabathini, Basahel, Sulaiman Nasir, Topuz, Berna, Onorato, Frank J., Macosko, Christopher W., Mkhoyan, K. Andre, & Tsapatsis, Michael. Open‐Pore Two‐Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon‐Isomer‐Selective Membranes on Porous Polymer Supports. Germany. https://doi.org/10.1002/anie.201601135
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Zhang, Han, Xiao, Qiang, Guo, Xianghai, Li, Najun, Kumar, Prashant, Rangnekar, Neel, Jeon, Mi Young, Al‐Thabaiti, Shaeel, Narasimharao, Katabathini, Basahel, Sulaiman Nasir, Topuz, Berna, Onorato, Frank J., Macosko, Christopher W., Mkhoyan, K. Andre, and Tsapatsis, Michael. Thu . "Open‐Pore Two‐Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon‐Isomer‐Selective Membranes on Porous Polymer Supports". Germany. https://doi.org/10.1002/anie.201601135.
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@article{osti_1400963,
title = {Open‐Pore Two‐Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon‐Isomer‐Selective Membranes on Porous Polymer Supports},
author = {Zhang, Han and Xiao, Qiang and Guo, Xianghai and Li, Najun and Kumar, Prashant and Rangnekar, Neel and Jeon, Mi Young and Al‐Thabaiti, Shaeel and Narasimharao, Katabathini and Basahel, Sulaiman Nasir and Topuz, Berna and Onorato, Frank J. and Macosko, Christopher W. and Mkhoyan, K. Andre and Tsapatsis, Michael},
abstractNote = {Abstract Two‐dimensional zeolite nanosheets that do not contain any organic structure‐directing agents were prepared from a multilamellar MFI (ML‐MFI) zeolite. ML‐MFI was first exfoliated by melt compounding and then detemplated by treatment with a mixture of H 2 SO 4 and H 2 O 2 (piranha solution). The obtained OSDA‐free MFI nanosheets disperse well in water and can be used for coating applications. Deposits made on porous polybenzimidazole (PBI) supports by simple filtration of these suspensions exhibit an n ‐butane/isobutane selectivity of 5.4, with an n ‐butane permeance of 3.5×10 −7  mol m −2  s −1  Pa −1 (ca. 1000 GPU).},
doi = {10.1002/anie.201601135},
journal = {Angewandte Chemie (International Edition)},
number = 25,
volume = 55,
place = {Germany},
year = {Thu Apr 21 00:00:00 EDT 2016},
month = {Thu Apr 21 00:00:00 EDT 2016}
}
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Journal Article:
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https://doi.org/10.1002/anie.201601135
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