High-Performance Near-IR Photodetector Using Low-Bandgap MA0.5FA0.5Pb0.5Sn0.5I3 Perovskite

Xu, Xiaobao; Chueh, Chu-Chen; Jing, Peifeng; Yang, Zhibin; Shi, Xueliang; Zhao, Ting; Lin, Lih Y.; Jen, Alex K. -Y.

doi:10.1002/adfm.201701053

Title: High-Performance Near-IR Photodetector Using Low-Bandgap MA_0.5FA_0.5Pb_0.5Sn_0.5I₃ Perovskite

Abstract

Photodetectors with ultrafast response are explored using inorganic/organic hybrid perovskites. High responsivity and fast optoelectronic response are achieved due to the exceptional semiconducting properties of perovskite materials. However, most of the perovskite-based photodetectors exploited to date are centered on Pb-based perovskites, which only afford spectral response across the visible spectrum. This study demonstrates a high-performance near-IR (NIR) photodetector using a stable low-bandgap Sn-containing perovskite, (CH₃NH₃)_0.5(NH₂CHNH₂)_0.5Pb_0.5Sn_0.5I₃ (MA_0.5FA_0.5Pb_0.5Sn_0.5I₃), which is processed with an antioxidant additive, ascorbic acid (AA). The addition of AA effectively strengthens the stability of Sn-containing perovskite against oxygen, thereby significantly inhibiting the leakage current. Consequently, the derived photodetector shows high responsivity with a detectivity of over 10¹² Jones ranging from 800 to 970 nm. Such low-cost, solution processable NIR photodetectors with high performance show promising potential for future optoelectronic applications.

Authors:

Xu, Xiaobao ^[1]; Chueh, Chu-Chen ^[2]; Jing, Peifeng ^[1]; Yang, Zhibin ^[1]; Shi, Xueliang ^[1]; Zhao, Ting ^[1]; Lin, Lih Y. ^[1]; Jen, Alex K. -Y. ^[3]

Univ. of Washington, Seattle, WA (United States)
Department of Chemical Engineering, National Taiwan University
Univ. of Washington, Seattle, WA (United States) ; Hong Kong Univ. (Hong Kong)

Publication Date:: Tue May 16 00:00:00 EDT 2017

Research Org.:: Univ. of Washington, Seattle, WA (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1533020

Alternate Identifier(s):: OSTI ID: 1400855

Grant/Contract Number:: EE0006710

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Volume: 27; Journal Issue: 28; Journal ID: ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; chemistry; science & technology; materials science; Physics; low bandgap; near‐IR; perovskites; photodetectors

Citation Formats


                    Xu, Xiaobao, Chueh, Chu-Chen, Jing, Peifeng, Yang, Zhibin, Shi, Xueliang, Zhao, Ting, Lin, Lih Y., and Jen, Alex K. -Y. High-Performance Near-IR Photodetector Using Low-Bandgap MA0.5FA0.5Pb0.5Sn0.5I3 Perovskite.  United States: N. p., 2017. 
Web.  doi:10.1002/adfm.201701053.

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                    Xu, Xiaobao, Chueh, Chu-Chen, Jing, Peifeng, Yang, Zhibin, Shi, Xueliang, Zhao, Ting, Lin, Lih Y., & Jen, Alex K. -Y. High-Performance Near-IR Photodetector Using Low-Bandgap MA0.5FA0.5Pb0.5Sn0.5I3 Perovskite.  United States.  https://doi.org/10.1002/adfm.201701053

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                    Xu, Xiaobao, Chueh, Chu-Chen, Jing, Peifeng, Yang, Zhibin, Shi, Xueliang, Zhao, Ting, Lin, Lih Y., and Jen, Alex K. -Y. Tue .  
"High-Performance Near-IR Photodetector Using Low-Bandgap MA0.5FA0.5Pb0.5Sn0.5I3 Perovskite".  United States.  https://doi.org/10.1002/adfm.201701053.  https://www.osti.gov/servlets/purl/1533020.

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@article{osti_1533020,

  title        = {High-Performance Near-IR Photodetector Using Low-Bandgap MA0.5FA0.5Pb0.5Sn0.5I3 Perovskite},

  author       = {Xu, Xiaobao and Chueh, Chu-Chen and Jing, Peifeng and Yang, Zhibin and Shi, Xueliang and Zhao, Ting and Lin, Lih Y. and Jen, Alex K. -Y.},

  abstractNote = {Photodetectors with ultrafast response are explored using inorganic/organic hybrid perovskites. High responsivity and fast optoelectronic response are achieved due to the exceptional semiconducting properties of perovskite materials. However, most of the perovskite-based photodetectors exploited to date are centered on Pb-based perovskites, which only afford spectral response across the visible spectrum. This study demonstrates a high-performance near-IR (NIR) photodetector using a stable low-bandgap Sn-containing perovskite, (CH3NH3)0.5(NH2CHNH2)0.5Pb0.5Sn0.5I3 (MA0.5FA0.5Pb0.5Sn0.5I3), which is processed with an antioxidant additive, ascorbic acid (AA). The addition of AA effectively strengthens the stability of Sn-containing perovskite against oxygen, thereby significantly inhibiting the leakage current. Consequently, the derived photodetector shows high responsivity with a detectivity of over 1012 Jones ranging from 800 to 970 nm. Such low-cost, solution processable NIR photodetectors with high performance show promising potential for future optoelectronic applications.},

  doi          = {10.1002/adfm.201701053},

  journal      = {Advanced Functional Materials},

  number       = 28,

  volume       = 27,

  place        = {United States},

  year         = {Tue May 16 00:00:00 EDT 2017},

  month        = {Tue May 16 00:00:00 EDT 2017}

}

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Title: High-Performance Near-IR Photodetector Using Low-Bandgap MA0.5FA0.5Pb0.5Sn0.5I3 Perovskite

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Third-generation infrared photodetector arrays journal, May 2009

Ultrasensitive solution-cast quantum dot photodetectors journal, July 2006

Lead-Free Inverted Planar Formamidinium Tin Triiodide Perovskite Solar Cells Achieving Power Conversion Efficiencies up to 6.22% journal, August 2016

Stable Low-Bandgap Pb-Sn Binary Perovskites for Tandem Solar Cells journal, August 2016

High performance organic-inorganic perovskite-optocoupler based on low-voltage and fast response perovskite compound photodetector journal, January 2015

A filterless, visible-blind, narrow-band, and near-infrared photodetector with a gain journal, January 2016

Lead-Free Halide Perovskite Solar Cells with High Photocurrents Realized Through Vacancy Modulation journal, September 2014

Highly responsive organic near-infrared photodetectors based on a porphyrin small molecule journal, January 2014

CH 3 NH 3 Sn x Pb (1– x ) I 3 Perovskite Solar Cells Covering up to 1060 nm journal, March 2014

Single-band upconversion nanoprobes for multiplexed simultaneous in situ molecular mapping of cancer biomarkers journal, April 2015

On-Site Quantitative Elemental Analysis of Metal Ions in Aqueous Solutions by Underwater Laser-Induced Breakdown Spectroscopy Combined with Electrodeposition under Controlled Potential journal, January 2015

Working Mechanism for Flexible Perovskite Solar Cells with Simplified Architecture journal, September 2015

A Highly Sensitive Narrowband Nanocomposite Photodetector with Gain journal, January 2016

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells journal, May 2009

Solution-processed hybrid perovskite photodetectors with high detectivity journal, November 2014

Advancing the speed, sensitivity and accuracy of biomolecular detection using multi-length-scale engineering journal, December 2014

Ascorbic acid as an effective antioxidant additive to enhance the efficiency and stability of Pb/Sn-based binary perovskite solar cells journal, April 2017

Hole Selective NiO Contact for Efficient Perovskite Solar Cells with Carbon Electrode journal, March 2015

High-Detectivity Polymer Photodetectors with Spectral Response from 300 nm to 1450 nm journal, August 2009

Atomically thin two-dimensional organic-inorganic hybrid perovskites journal, September 2015

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber journal, October 2013

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3 journal, October 2013

Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide journal, September 2016

Room-Temperature Near-Infrared Photodetectors Based on Single Heterojunction Nanowires journal, January 2014

A Self-Powered, Sub-nanosecond-Response Solution-Processed Hybrid Perovskite Photodetector for Time-Resolved Photoluminescence-Lifetime Detection journal, October 2016

Ascorbic acid-assisted synthesis of cobalt ferrite (CoFe2O4) hierarchical flower-like microspheres with enhanced lithium storage properties journal, June 2014

Organic Cation-Dependent Degradation Mechanism of Organotin Halide Perovskites journal, March 2016

Disulfide/Thiolate Based Redox Shuttle for Dye-Sensitized Solar Cells: An Impedance Spectroscopy Study journal, November 2012

50% Sn-Based Planar Perovskite Solar Cell with Power Conversion Efficiency up to 13.6% journal, August 2016

Binary-Metal Perovskites Toward High-Performance Planar-Heterojunction Hybrid Solar Cells journal, August 2014

Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals journal, March 2016

One-Pot Reaction to Synthesize Water-Soluble Magnetite Nanocrystals journal, April 2004

Filterless narrowband visible photodetectors journal, September 2015

Perovskite-perovskite tandem photovoltaics with optimized band gaps journal, October 2016

Near-Infrared Photodetector Based on MoS 2 /Black Phosphorus Heterojunction journal, March 2016

Anomalous Band Gap Behavior in Mixed Sn and Pb Perovskites Enables Broadening of Absorption Spectrum in Solar Cells journal, May 2014

Interfacial Degradation of Planar Lead Halide Perovskite Solar Cells journal, December 2015

Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes journal, February 2015

Highly narrowband perovskite single-crystal photodetectors enabled by surface-charge recombination journal, August 2015

Sensitive, Fast, and Stable Perovskite Photodetectors Exploiting Interface Engineering journal, July 2015

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells journal, October 2013

A nanocomposite ultraviolet photodetector based on interfacial trap-controlled charge injection journal, November 2012

A nanocomposite ultraviolet photodetector based on interfacial trap-controlled charge injection text, January 2012

Perovskite-perovskite tandem photovoltaics with optimized bandgaps text, January 2016

Highly Sensitive Low-Bandgap Perovskite Photodetectors with Response from Ultraviolet to the Near-Infrared Region journal, September 2017

Low-Bandgap Methylammonium-Rubidium Cation Sn-Rich Perovskites for Efficient Ultraviolet-Visible-Near Infrared Photodetectors journal, January 2018

Highly Efficient Sn/Pb Binary Perovskite Solar Cell via Precursor Engineering: A Two-Step Fabrication Process journal, December 2018

Spin‐On‐Patterning of Sn–Pb Perovskite Photodiodes on IGZO Transistor Arrays for Fast Active‐Matrix Near‐Infrared Imaging journal, December 2019

Plasmonic-Functionalized Broadband Perovskite Photodetector journal, February 2018

A Sensitive Broadband (UV–vis–NIR) Perovskite Photodetector Using Topological Insulator as Electrodes journal, December 2018

Enhanced UV‐C Detection of Perovskite Photodetector Arrays via Inorganic CsPbBr 3 Quantum Dot Down‐Conversion Layer journal, March 2019

Solution‐Processed Visible‐Blind Ultraviolet Photodetectors with Nanosecond Response Time and High Detectivity journal, June 2019

Multilayered PdSe 2 /Perovskite Schottky Junction for Fast, Self‐Powered, Polarization‐Sensitive, Broadband Photodetectors, and Image Sensor Application journal, August 2019

Stability enhancement of lead‐free CsSnI 3 perovskite photodetector with reductive ascorbic acid additive journal, January 2020

Phase Stabilized α-CsPbI 3 Perovskite Nanocrystals for Photodiode Applications journal, November 2017

Perovskite/Organic Bulk-Heterojunction Integrated Ultrasensitive Broadband Photodetectors with High Near-Infrared External Quantum Efficiency over 70% journal, August 2018

Crystallization, Properties, and Challenges of Low-Bandgap Sn-Pb Binary Perovskites journal, July 2018

High-Performance Photodiode-Type Photodetectors Based on Polycrystalline Formamidinium Lead Iodide Perovskite Thin Films journal, July 2018

Incorporating deep electron traps into perovskite devices: towards high efficiency solar cells and fast photodetectors journal, January 2018

Prospects of colour selective organic photodiodes journal, January 2018

Triple cation perovskite doped with the small molecule F4TCNQ for highly efficient stable photodetectors journal, January 2020

Mixed Two-Dimensional Organic-Inorganic Halide Perovskites for Highly Efficient and Stable Photovoltaic Application journal, June 2019

Title: High-Performance Near-IR Photodetector Using Low-Bandgap MA_0.5FA_0.5Pb_0.5Sn_0.5I₃ Perovskite

Fabrication of Efficient Formamidinium Tin Iodide Perovskite Solar Cells through SnF ₂ –Pyrazine Complex
journal, March 2016

Third-generation infrared photodetector arrays
journal, May 2009

Ultrasensitive solution-cast quantum dot photodetectors
journal, July 2006

Lead-Free Inverted Planar Formamidinium Tin Triiodide Perovskite Solar Cells Achieving Power Conversion Efficiencies up to 6.22%
journal, August 2016

Stable Low-Bandgap Pb-Sn Binary Perovskites for Tandem Solar Cells
journal, August 2016

High performance organic-inorganic perovskite-optocoupler based on low-voltage and fast response perovskite compound photodetector
journal, January 2015

A filterless, visible-blind, narrow-band, and near-infrared photodetector with a gain
journal, January 2016

Lead-Free Halide Perovskite Solar Cells with High Photocurrents Realized Through Vacancy Modulation
journal, September 2014

Highly responsive organic near-infrared photodetectors based on a porphyrin small molecule
journal, January 2014

CH ₃ NH ₃ Sn _x Pb _{(1– x )} I ₃ Perovskite Solar Cells Covering up to 1060 nm
journal, March 2014

Single-band upconversion nanoprobes for multiplexed simultaneous in situ molecular mapping of cancer biomarkers
journal, April 2015

On-Site Quantitative Elemental Analysis of Metal Ions in Aqueous Solutions by Underwater Laser-Induced Breakdown Spectroscopy Combined with Electrodeposition under Controlled Potential
journal, January 2015

Working Mechanism for Flexible Perovskite Solar Cells with Simplified Architecture
journal, September 2015

A Highly Sensitive Narrowband Nanocomposite Photodetector with Gain
journal, January 2016

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

Solution-processed hybrid perovskite photodetectors with high detectivity
journal, November 2014

Advancing the speed, sensitivity and accuracy of biomolecular detection using multi-length-scale engineering
journal, December 2014

Ascorbic acid as an effective antioxidant additive to enhance the efficiency and stability of Pb/Sn-based binary perovskite solar cells
journal, April 2017

Hole Selective NiO Contact for Efficient Perovskite Solar Cells with Carbon Electrode
journal, March 2015

High-Detectivity Polymer Photodetectors with Spectral Response from 300 nm to 1450 nm
journal, August 2009

Atomically thin two-dimensional organic-inorganic hybrid perovskites
journal, September 2015

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃
journal, October 2013

Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide
journal, September 2016

Room-Temperature Near-Infrared Photodetectors Based on Single Heterojunction Nanowires
journal, January 2014

A Self-Powered, Sub-nanosecond-Response Solution-Processed Hybrid Perovskite Photodetector for Time-Resolved Photoluminescence-Lifetime Detection
journal, October 2016

Ascorbic acid-assisted synthesis of cobalt ferrite (CoFe2O4) hierarchical flower-like microspheres with enhanced lithium storage properties
journal, June 2014

Organic Cation-Dependent Degradation Mechanism of Organotin Halide Perovskites
journal, March 2016

Disulfide/Thiolate Based Redox Shuttle for Dye-Sensitized Solar Cells: An Impedance Spectroscopy Study
journal, November 2012

50% Sn-Based Planar Perovskite Solar Cell with Power Conversion Efficiency up to 13.6%
journal, August 2016

Binary-Metal Perovskites Toward High-Performance Planar-Heterojunction Hybrid Solar Cells
journal, August 2014

Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals
journal, March 2016

One-Pot Reaction to Synthesize Water-Soluble Magnetite Nanocrystals
journal, April 2004

Filterless narrowband visible photodetectors
journal, September 2015

Perovskite-perovskite tandem photovoltaics with optimized band gaps
journal, October 2016

Near-Infrared Photodetector Based on MoS ₂ /Black Phosphorus Heterojunction
journal, March 2016

Anomalous Band Gap Behavior in Mixed Sn and Pb Perovskites Enables Broadening of Absorption Spectrum in Solar Cells
journal, May 2014

Interfacial Degradation of Planar Lead Halide Perovskite Solar Cells
journal, December 2015

Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
journal, February 2015

Highly narrowband perovskite single-crystal photodetectors enabled by surface-charge recombination
journal, August 2015

Sensitive, Fast, and Stable Perovskite Photodetectors Exploiting Interface Engineering
journal, July 2015

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
journal, October 2013

A nanocomposite ultraviolet photodetector based on interfacial trap-controlled charge injection
journal, November 2012

A nanocomposite ultraviolet photodetector based on interfacial trap-controlled charge injection
text, January 2012

Perovskite-perovskite tandem photovoltaics with optimized bandgaps
text, January 2016

Highly Sensitive Low-Bandgap Perovskite Photodetectors with Response from Ultraviolet to the Near-Infrared Region
journal, September 2017

Low-Bandgap Methylammonium-Rubidium Cation Sn-Rich Perovskites for Efficient Ultraviolet-Visible-Near Infrared Photodetectors
journal, January 2018

Highly Efficient Sn/Pb Binary Perovskite Solar Cell via Precursor Engineering: A Two-Step Fabrication Process
journal, December 2018

Spin‐On‐Patterning of Sn–Pb Perovskite Photodiodes on IGZO Transistor Arrays for Fast Active‐Matrix Near‐Infrared Imaging
journal, December 2019

Plasmonic-Functionalized Broadband Perovskite Photodetector
journal, February 2018

A Sensitive Broadband (UV–vis–NIR) Perovskite Photodetector Using Topological Insulator as Electrodes
journal, December 2018

Enhanced UV‐C Detection of Perovskite Photodetector Arrays via Inorganic CsPbBr ₃ Quantum Dot Down‐Conversion Layer
journal, March 2019

Solution‐Processed Visible‐Blind Ultraviolet Photodetectors with Nanosecond Response Time and High Detectivity
journal, June 2019

Multilayered PdSe ₂ /Perovskite Schottky Junction for Fast, Self‐Powered, Polarization‐Sensitive, Broadband Photodetectors, and Image Sensor Application
journal, August 2019

Stability enhancement of lead‐free CsSnI ₃ perovskite photodetector with reductive ascorbic acid additive
journal, January 2020

Phase Stabilized α-CsPbI ₃ Perovskite Nanocrystals for Photodiode Applications
journal, November 2017

Perovskite/Organic Bulk-Heterojunction Integrated Ultrasensitive Broadband Photodetectors with High Near-Infrared External Quantum Efficiency over 70%
journal, August 2018

Crystallization, Properties, and Challenges of Low-Bandgap Sn-Pb Binary Perovskites
journal, July 2018

High-Performance Photodiode-Type Photodetectors Based on Polycrystalline Formamidinium Lead Iodide Perovskite Thin Films
journal, July 2018

Incorporating deep electron traps into perovskite devices: towards high efficiency solar cells and fast photodetectors
journal, January 2018

Prospects of colour selective organic photodiodes
journal, January 2018

Triple cation perovskite doped with the small molecule F4TCNQ for highly efficient stable photodetectors
journal, January 2020

Mixed Two-Dimensional Organic-Inorganic Halide Perovskites for Highly Efficient and Stable Photovoltaic Application
journal, June 2019