Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis

doi:10.1002/ente.201600636

Title: Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis

Authors:

^[1]; Chen, Qingmei ^[1];

^[1];

^[1]

Dioxide Materials, 3998, FAU Blvd. #300 Boca Raton FL 33433 USA

Publication Date:: 2017-03-09

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1400805

Grant/Contract Number:: AR0000345

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Energy Technology

Additional Journal Information:: Journal Name: Energy Technology Journal Volume: 5 Journal Issue: 6; Journal ID: ISSN 2194-4288

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Kutz, Robert B., Chen, Qingmei, Yang, Hongzhou, Sajjad, Syed D., Liu, Zengcai, and Masel, I. Richard. Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis.  Germany: N. p., 2017. 
        Web.  doi:10.1002/ente.201600636.

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                    Kutz, Robert B., Chen, Qingmei, Yang, Hongzhou, Sajjad, Syed D., Liu, Zengcai, & Masel, I. Richard. Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis.  Germany.  doi:10.1002/ente.201600636.

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                    Kutz, Robert B., Chen, Qingmei, Yang, Hongzhou, Sajjad, Syed D., Liu, Zengcai, and Masel, I. Richard. Thu .  
        "Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis".  Germany.  doi:10.1002/ente.201600636.

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@article{osti_1400805,

  title        = {Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis},

  author       = {Kutz, Robert B. and Chen, Qingmei and Yang, Hongzhou and Sajjad, Syed D. and Liu, Zengcai and Masel, I. Richard},

  abstractNote = {},

  doi          = {10.1002/ente.201600636},

  journal      = {Energy Technology},

  number       = 6,

  volume       = 5,

  place        = {Germany},

  year         = {2017},

  month        = {3}

}

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DOI: 10.1002/ente.201600636

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Title: Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis

Citation Formats

Electrocatalytic conversion of CO2 to liquid fuels using nanocarbon-based electrodes journal, March 2013

A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts journal, September 2014

A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper journal, August 2006

Unlocking the Potential of CO2 Conversion to Fuels and Chemicals as an Economically Viable Route to CCR journal, January 2014

Effect of solid polymer electrolyte on electrochemical reduction of CO2 journal, June 2012

Highly ionic-conductive crosslinked cardo poly(arylene ether sulfone)s as anion exchange membranes for alkaline fuel cells journal, October 2015

Valorization of greenhouse carbon dioxide emissions into value-added products by catalytic processes journal, December 2013

Electrochemical CO 2 Reduction: Recent Advances and Current Trends journal, September 2014

Imidazolium functionalized anion exchange membrane blended with PVA for acid recovery via diffusion dialysis process journal, January 2016

Electrochemical CO2 Reduction on Metal Electrodes book, January 2008

Comparison of alkaline stability of benzyltrimethylammonium, benzylmethylimidazolium and benzyldimethylimidazolium functionalized poly(arylene ether ketone) anion exchange membranes journal, January 2016

Imidazolium-Functionalized Anion Exchange Polymer Electrolytes with High Tensile Strength and Stability for Alkaline Membrane Fuel Cells journal, September 2015

1,2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells journal, February 2015

Amines as Reaction Environment Regulator for CO 2 Electrochemical Reduction to CH 4 journal, November 2015

Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials journal, September 2011

Preparing alkaline anion exchange membrane with enhanced hydroxide conductivity via blending imidazolium-functionalized and sulfonated poly(ether ether ketone) journal, August 2015

Catalysis for the Valorization of Exhaust Carbon: from CO 2 to Chemicals, Materials, and Fuels. Technological Use of CO 2 journal, November 2013

Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes journal, January 2013

A facile functionalized routine for the synthesis of imidazolium-based anion-exchange membrane with excellent alkaline stability journal, May 2016

A stable anion exchange membrane based on imidazolium salt for alkaline fuel cell journal, October 2014

Hydroxide-ion induced degradation pathway for dimethylimidazolium groups in anion exchange membranes journal, July 2014

Imidazolium-based anion exchange membranes for alkaline anion fuel cells: elucidation of the morphology and the interplay between the morphology and properties journal, January 2016

Modification of poly(aryl ether ketone) using imidazolium groups as both pendants and bridging joints for anion exchange membranes journal, December 2015

Comb-shaped alkyl imidazolium-functionalized poly(arylene ether sulfone)s as high performance anion-exchange membranes journal, January 2015

Stable poly(arylene ether sulfone)s anion exchange membranes containing imidazolium cations on pendant phenyl rings journal, February 2016

Recycling of carbon dioxide to methanol and derived products – closing the loop journal, January 2014

Synthesis and Characterization of Imidazolium Linear Bisphenol Polycarbonate Hydroxides for Anion Exchange Membrane journal, November 2015

Synthesis and characterization of novel anion exchange membranes containing bi-imidazolium-based ionic liquid for alkaline fuel cells journal, October 2015

Enhancement of hydroxide conductivity by grafting flexible pendant imidazolium groups into poly(arylene ether sulfone) as anion exchange membranes journal, January 2015

Effects of Substituents and Substitution Positions on Alkaline Stability of Imidazolium Cations and Their Corresponding Anion-Exchange Membranes journal, March 2014

In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide journal, July 2012

Using carbon dioxide as a building block in organic synthesis journal, January 2015

Electrochemical conversion of CO2 to fuels: tuning of the reaction zone using suitable functional groups in a solid polymer electrolyte journal, January 2014

Prospects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction journal, December 2010

Electrocatalytic Reduction of Carbon Dioxide: Let the Molecules Do the Work journal, November 2014

Substituent Effects in the Pyridinium Catalyzed Reduction of CO2 to Methanol: Further Mechanistic Insights journal, November 2014

Renewable Power-to-Gas: A technological and economic review journal, January 2016

Use of carbon dioxide as feedstock for chemicals and fuels: homogeneous and heterogeneous catalysis: Use of carbon dioxide as feedstock for chemicals and fuels journal, November 2013

Emerging electrochemical energy conversion and storage technologies journal, September 2014

The effect of electrolyte composition on the electroreduction of CO 2 to CO on Ag based gas diffusion electrodes journal, January 2016

Water Enhancement of CO2 Conversion on Silver in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate journal, November 2012

Development of Molecular Electrocatalysts for Energy Storage journal, February 2014

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels journal, January 2014

Electrocatalytic conversion of CO2 to liquid fuels using nanocarbon-based electrodes
journal, March 2013

A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts
journal, September 2014

A review of the aqueous electrochemical reduction of CO₂ to hydrocarbons at copper
journal, August 2006

Unlocking the Potential of CO2 Conversion to Fuels and Chemicals as an Economically Viable Route to CCR
journal, January 2014

Effect of solid polymer electrolyte on electrochemical reduction of CO₂
journal, June 2012

Highly ionic-conductive crosslinked cardo poly(arylene ether sulfone)s as anion exchange membranes for alkaline fuel cells
journal, October 2015

Valorization of greenhouse carbon dioxide emissions into value-added products by catalytic processes
journal, December 2013

Electrochemical CO ₂ Reduction: Recent Advances and Current Trends
journal, September 2014

Imidazolium functionalized anion exchange membrane blended with PVA for acid recovery via diffusion dialysis process
journal, January 2016

Electrochemical CO₂ Reduction on Metal Electrodes
book, January 2008

Comparison of alkaline stability of benzyltrimethylammonium, benzylmethylimidazolium and benzyldimethylimidazolium functionalized poly(arylene ether ketone) anion exchange membranes
journal, January 2016

Imidazolium-Functionalized Anion Exchange Polymer Electrolytes with High Tensile Strength and Stability for Alkaline Membrane Fuel Cells
journal, September 2015

1,2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells
journal, February 2015

Amines as Reaction Environment Regulator for CO ₂ Electrochemical Reduction to CH ₄
journal, November 2015

Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials
journal, September 2011

Preparing alkaline anion exchange membrane with enhanced hydroxide conductivity via blending imidazolium-functionalized and sulfonated poly(ether ether ketone)
journal, August 2015

Catalysis for the Valorization of Exhaust Carbon: from CO ₂ to Chemicals, Materials, and Fuels. Technological Use of CO ₂
journal, November 2013

Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes
journal, January 2013

A facile functionalized routine for the synthesis of imidazolium-based anion-exchange membrane with excellent alkaline stability
journal, May 2016

A stable anion exchange membrane based on imidazolium salt for alkaline fuel cell
journal, October 2014

Hydroxide-ion induced degradation pathway for dimethylimidazolium groups in anion exchange membranes
journal, July 2014

Imidazolium-based anion exchange membranes for alkaline anion fuel cells: elucidation of the morphology and the interplay between the morphology and properties
journal, January 2016

Modification of poly(aryl ether ketone) using imidazolium groups as both pendants and bridging joints for anion exchange membranes
journal, December 2015

Comb-shaped alkyl imidazolium-functionalized poly(arylene ether sulfone)s as high performance anion-exchange membranes
journal, January 2015

Stable poly(arylene ether sulfone)s anion exchange membranes containing imidazolium cations on pendant phenyl rings
journal, February 2016

Recycling of carbon dioxide to methanol and derived products – closing the loop
journal, January 2014

Synthesis and Characterization of Imidazolium Linear Bisphenol Polycarbonate Hydroxides for Anion Exchange Membrane
journal, November 2015

Synthesis and characterization of novel anion exchange membranes containing bi-imidazolium-based ionic liquid for alkaline fuel cells
journal, October 2015

Enhancement of hydroxide conductivity by grafting flexible pendant imidazolium groups into poly(arylene ether sulfone) as anion exchange membranes
journal, January 2015

Effects of Substituents and Substitution Positions on Alkaline Stability of Imidazolium Cations and Their Corresponding Anion-Exchange Membranes
journal, March 2014

In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide
journal, July 2012

Using carbon dioxide as a building block in organic synthesis
journal, January 2015

Electrochemical conversion of CO₂ to fuels: tuning of the reaction zone using suitable functional groups in a solid polymer electrolyte
journal, January 2014

Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction
journal, December 2010

Electrocatalytic Reduction of Carbon Dioxide: Let the Molecules Do the Work
journal, November 2014

Substituent Effects in the Pyridinium Catalyzed Reduction of CO2 to Methanol: Further Mechanistic Insights
journal, November 2014

Renewable Power-to-Gas: A technological and economic review
journal, January 2016

Use of carbon dioxide as feedstock for chemicals and fuels: homogeneous and heterogeneous catalysis: Use of carbon dioxide as feedstock for chemicals and fuels
journal, November 2013

Emerging electrochemical energy conversion and storage technologies
journal, September 2014

The effect of electrolyte composition on the electroreduction of CO ₂ to CO on Ag based gas diffusion electrodes
journal, January 2016

Water Enhancement of CO₂ Conversion on Silver in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate
journal, November 2012

Development of Molecular Electrocatalysts for Energy Storage
journal, February 2014

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
journal, January 2014