Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis

doi:10.1002/ente.201600636

Title: Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis

Authors:

; Chen, Qingmei ^[1] ; ; ; ;

Dioxide Materials, 3998, FAU Blvd. #300 Boca Raton FL 33433 USA

Publication Date:: 2017-03-09

Grant/Contract Number:: AR0000345

Type:: Publisher's Accepted Manuscript

Journal Name:: Energy Technology

Additional Journal Information:: Journal Name: Energy Technology Journal Volume: 5 Journal Issue: 6; Journal ID: ISSN 2194-4288

Publisher:: Wiley Blackwell (John Wiley & Sons)

Sponsoring Org:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Country of Publication:: Germany

Language:: English

OSTI Identifier:: 1400805


                    Kutz, Robert B., Chen, Qingmei, Yang, Hongzhou, Sajjad, Syed D., Liu, Zengcai, and Masel, I. Richard. Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis.  Germany: N. p.,  
        Web.  doi:10.1002/ente.201600636.

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                    Kutz, Robert B., Chen, Qingmei, Yang, Hongzhou, Sajjad, Syed D., Liu, Zengcai, & Masel, I. Richard. Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis.  Germany.  doi:10.1002/ente.201600636.

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                    Kutz, Robert B., Chen, Qingmei, Yang, Hongzhou, Sajjad, Syed D., Liu, Zengcai, and Masel, I. Richard. 2017.  
        "Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis".  Germany.  
        doi:10.1002/ente.201600636.

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@article{osti_1400805,

  title        = {Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis},

  author       = {Kutz, Robert B. and Chen, Qingmei and Yang, Hongzhou and Sajjad, Syed D. and Liu, Zengcai and Masel, I. Richard},

  abstractNote = {},

  doi          = {10.1002/ente.201600636},

  journal      = {Energy Technology},

  number       = 6,

  volume       = 5,

  place        = {Germany},

  year         = {2017},

  month        = {3}

}

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Free Publicly Accessible Full Text
Accepted Manuscript (Publisher)
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10.1002/ente.201600636
https://doi.org/10.1002/ente.201600636

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Works referenced in this record:

A review of the aqueous electrochemical reduction of CO₂ to hydrocarbons at copper
journal, August 2006

Gattrell, M.; Gupta, N.; Co, A.
Journal of Electroanalytical Chemistry, Vol. 594, Issue 1, p. 1-19
DOI: 10.1016/j.jelechem.2006.05.013

Effect of solid polymer electrolyte on electrochemical reduction of CO₂
journal, June 2012

Aeshala, L. M.; Rahman, S. U.; Verma, A.
Separation and Purification Technology, Vol. 94, p. 131-137
DOI: 10.1016/j.seppur.2011.12.030

Electrochemical CO₂ Reduction on Metal Electrodes
book, January 2008

Hori, Y.; Vayenas, Constantinos G.; White, Ralph E.
Modern Aspects of Electrochemistry, p. 89-189
DOI: 10.1007/978-0-387-49489-0_3

Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials
journal, September 2011

Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.
Science, Vol. 334, Issue 6056, p. 643-644
DOI: 10.1126/science.1209786

In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide
journal, July 2012

Rosen, Brian A.; Haan, John L.; Mukherjee, Prabuddha
The Journal of Physical Chemistry C, Vol. 116, Issue 29, p. 15307-15312
DOI: 10.1021/jp210542v

Electrochemical conversion of CO₂ to fuels: tuning of the reaction zone using suitable functional groups in a solid polymer electrolyte
journal, January 2014

Aeshala, Leela Manohar; Uppaluri, Ramagopal; Verma, Anil
Physical Chemistry Chemical Physics, Vol. 16, Issue 33, p. 17588-17594
DOI: 10.1039/C4CP02389G

Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction
journal, December 2010

Whipple, Devin T.; Kenis, Paul J. A.
The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458
DOI: 10.1021/jz1012627

Water Enhancement of CO₂ Conversion on Silver in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate
journal, November 2012

Rosen, B. A.; Zhu, W.; Kaul, G.
Journal of the Electrochemical Society, Vol. 160, Issue 2, p. H138-H141
DOI: 10.1149/2.004303jes

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Title: Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis

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