Adding to the Arsenal of Zirconium‐Based Metal–Organic Frameworks: the Topology as a Platform for Solvent‐Assisted Metal Incorporation
Abstract
Gaining control over the assembly of mesoporous Zr‐based metal–organic frameworks (MOFs) with modifiable metal nodes remains a challenge. The the topology is intriguing, particularly if considering postsynthetic modification, as it presents large sodalite‐like cages surrounded by 12 interconnected 1D channels that allow for efficient diffusion of guest molecules throughout the structure. Herein, we demonstrate the first Zr MOF with the topology, NU‐1200, which was synthesized by controlling the geometry of the organic building unit. In addition, by using NU‐1200 as a platform, we perform solvent‐assisted metal incorporation to form single‐site metalated nodes, a process that is characterized by single‐crystal X‐ray diffraction.
- Authors:
-
- Department of Chemistry Northwestern University 2145 Sheridan Road 60208 Evanston IL USA
- Cambridge Crystallographic Data Centre Center for Integrative Proteomics Research 174 Frelinghuysen Road 08854 Piscataway NJ USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1400776
- Grant/Contract Number:
- DESC0012702.
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- European Journal of Inorganic Chemistry
- Additional Journal Information:
- Journal Name: European Journal of Inorganic Chemistry Journal Volume: 2016 Journal Issue: 27; Journal ID: ISSN 1434-1948
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Liu, Tian‐Fu, Vermeulen, Nicolaas A., Howarth, Ashlee J., Li, Peng, Sarjeant, Amy A., Hupp, Joseph T., and Farha, Omar K. Adding to the Arsenal of Zirconium‐Based Metal–Organic Frameworks: the Topology as a Platform for Solvent‐Assisted Metal Incorporation. Germany: N. p., 2016.
Web. doi:10.1002/ejic.201600627.
Liu, Tian‐Fu, Vermeulen, Nicolaas A., Howarth, Ashlee J., Li, Peng, Sarjeant, Amy A., Hupp, Joseph T., & Farha, Omar K. Adding to the Arsenal of Zirconium‐Based Metal–Organic Frameworks: the Topology as a Platform for Solvent‐Assisted Metal Incorporation. Germany. https://doi.org/10.1002/ejic.201600627
Liu, Tian‐Fu, Vermeulen, Nicolaas A., Howarth, Ashlee J., Li, Peng, Sarjeant, Amy A., Hupp, Joseph T., and Farha, Omar K. Fri .
"Adding to the Arsenal of Zirconium‐Based Metal–Organic Frameworks: the Topology as a Platform for Solvent‐Assisted Metal Incorporation". Germany. https://doi.org/10.1002/ejic.201600627.
@article{osti_1400776,
title = {Adding to the Arsenal of Zirconium‐Based Metal–Organic Frameworks: the Topology as a Platform for Solvent‐Assisted Metal Incorporation},
author = {Liu, Tian‐Fu and Vermeulen, Nicolaas A. and Howarth, Ashlee J. and Li, Peng and Sarjeant, Amy A. and Hupp, Joseph T. and Farha, Omar K.},
abstractNote = {Gaining control over the assembly of mesoporous Zr‐based metal–organic frameworks (MOFs) with modifiable metal nodes remains a challenge. The the topology is intriguing, particularly if considering postsynthetic modification, as it presents large sodalite‐like cages surrounded by 12 interconnected 1D channels that allow for efficient diffusion of guest molecules throughout the structure. Herein, we demonstrate the first Zr MOF with the topology, NU‐1200, which was synthesized by controlling the geometry of the organic building unit. In addition, by using NU‐1200 as a platform, we perform solvent‐assisted metal incorporation to form single‐site metalated nodes, a process that is characterized by single‐crystal X‐ray diffraction.},
doi = {10.1002/ejic.201600627},
journal = {European Journal of Inorganic Chemistry},
number = 27,
volume = 2016,
place = {Germany},
year = {Fri Jul 08 00:00:00 EDT 2016},
month = {Fri Jul 08 00:00:00 EDT 2016}
}
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