Modulated Synthesis of Metal‐Organic Frameworks through Tuning of the Initial Oxidation State of the Metal
Abstract
Modulated solvothermal synthesis and other alterations of synthetic conditions have been used to control metal‐organic framework (MOF) crystallinity, porosity, and other properties. However, so far these changes have mostly been limited to changes in solvent, pH, or modulating acid type or concentration. In this work, we introduce a new method for the tuning of MOF synthesis: modulation through alteration of the metal source's initial oxidation state. By choosing a metal source that should be reduced or oxidized at high temperature in the solvent, metal concentration can be started at zero for initially insoluble starting materials and then increased as the metal reacts with the solvent, slowing and altering crystallization compared to standard MOF solvothermal synthesis. This concept is demonstrated through the synthesis of PCN‐47, PCN‐48, and PCN‐49, MOFs with distinct structures and porosities synthesized from the same metal and ligand with the metal initially in different oxidation states.
- Authors:
-
[1];
[3]
- Department of Chemistry Texas A&,M University 77842‐3012 College Station Texas USA
- Department of Material Science and Engineering Texas A&,M University 77842‐3012 College Station Texas USA
- Department of Chemistry Texas A&,M University 77842‐3012 College Station Texas USA, Department of Material Science and Engineering Texas A&,M University 77842‐3012 College Station Texas USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1400769
- Grant/Contract Number:
- DE‐SC0001015; DE‐AR0000249; DE‐EE‐0007049; DE‐AC02‐06CH11357
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- European Journal of Inorganic Chemistry
- Additional Journal Information:
- Journal Name: European Journal of Inorganic Chemistry Journal Volume: 2016 Journal Issue: 27; Journal ID: ISSN 1434-1948
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Bosch, Mathieu, Sun, Xing, Yuan, Shuai, Chen, Ying‐Pin, Wang, Qi, Wang, Xuan, and Zhou, Hong‐Cai. Modulated Synthesis of Metal‐Organic Frameworks through Tuning of the Initial Oxidation State of the Metal. Germany: N. p., 2016.
Web. doi:10.1002/ejic.201600211.
Bosch, Mathieu, Sun, Xing, Yuan, Shuai, Chen, Ying‐Pin, Wang, Qi, Wang, Xuan, & Zhou, Hong‐Cai. Modulated Synthesis of Metal‐Organic Frameworks through Tuning of the Initial Oxidation State of the Metal. Germany. https://doi.org/10.1002/ejic.201600211
Bosch, Mathieu, Sun, Xing, Yuan, Shuai, Chen, Ying‐Pin, Wang, Qi, Wang, Xuan, and Zhou, Hong‐Cai. Fri .
"Modulated Synthesis of Metal‐Organic Frameworks through Tuning of the Initial Oxidation State of the Metal". Germany. https://doi.org/10.1002/ejic.201600211.
@article{osti_1400769,
title = {Modulated Synthesis of Metal‐Organic Frameworks through Tuning of the Initial Oxidation State of the Metal},
author = {Bosch, Mathieu and Sun, Xing and Yuan, Shuai and Chen, Ying‐Pin and Wang, Qi and Wang, Xuan and Zhou, Hong‐Cai},
abstractNote = {Modulated solvothermal synthesis and other alterations of synthetic conditions have been used to control metal‐organic framework (MOF) crystallinity, porosity, and other properties. However, so far these changes have mostly been limited to changes in solvent, pH, or modulating acid type or concentration. In this work, we introduce a new method for the tuning of MOF synthesis: modulation through alteration of the metal source's initial oxidation state. By choosing a metal source that should be reduced or oxidized at high temperature in the solvent, metal concentration can be started at zero for initially insoluble starting materials and then increased as the metal reacts with the solvent, slowing and altering crystallization compared to standard MOF solvothermal synthesis. This concept is demonstrated through the synthesis of PCN‐47, PCN‐48, and PCN‐49, MOFs with distinct structures and porosities synthesized from the same metal and ligand with the metal initially in different oxidation states.},
doi = {10.1002/ejic.201600211},
journal = {European Journal of Inorganic Chemistry},
number = 27,
volume = 2016,
place = {Germany},
year = {Fri Jun 10 00:00:00 EDT 2016},
month = {Fri Jun 10 00:00:00 EDT 2016}
}
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https://doi.org/10.1002/ejic.201600211
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